catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P]
The title compound, [Cu2(CF3SO3)2(C3H9PS3)2]n, crystallizes as infinite chains in which two trimethyl trithiophosphite ligands and two trifluoromethanesulfonate anions bridge the essentially tetrahedrally coordinated CuI ions in an alternating fashion. The P and one S atom of each trimethyl trithiop...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808041809 |
| _version_ | 1818974331805368320 |
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| author | Christoph E. Strasser Stephanie Cronje Helgard G. Raubenheimer |
| author_facet | Christoph E. Strasser Stephanie Cronje Helgard G. Raubenheimer |
| author_sort | Christoph E. Strasser |
| collection | DOAJ |
| description | The title compound, [Cu2(CF3SO3)2(C3H9PS3)2]n, crystallizes as infinite chains in which two trimethyl trithiophosphite ligands and two trifluoromethanesulfonate anions bridge the essentially tetrahedrally coordinated CuI ions in an alternating fashion. The P and one S atom of each trimethyl trithiophosphite ligand are employed for coordination. The molecular structure exhibits the rare motif of copper(I) bridged by two trifluoromethanesulfonate anions generating eight-membered rings. |
| first_indexed | 2024-12-20T15:38:22Z |
| format | Article |
| id | doaj.art-4738c7e79024445d8b789ee3914b9e19 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:38:22Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4738c7e79024445d8b789ee3914b9e192022-12-21T19:35:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m86m8610.1107/S1600536808041809catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P]Christoph E. StrasserStephanie CronjeHelgard G. RaubenheimerThe title compound, [Cu2(CF3SO3)2(C3H9PS3)2]n, crystallizes as infinite chains in which two trimethyl trithiophosphite ligands and two trifluoromethanesulfonate anions bridge the essentially tetrahedrally coordinated CuI ions in an alternating fashion. The P and one S atom of each trimethyl trithiophosphite ligand are employed for coordination. The molecular structure exhibits the rare motif of copper(I) bridged by two trifluoromethanesulfonate anions generating eight-membered rings.http://scripts.iucr.org/cgi-bin/paper?S1600536808041809 |
| spellingShingle | Christoph E. Strasser Stephanie Cronje Helgard G. Raubenheimer catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P] Acta Crystallographica Section E |
| title | catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P] |
| title_full | catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P] |
| title_fullStr | catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P] |
| title_full_unstemmed | catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P] |
| title_short | catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2P:S;κ2S:P] |
| title_sort | catena poly copper i bis 956 trifluoromethanesulfonato 954 2o o 8242 copper i bis 956 trimethyl trithiophosphite 954 2p s 954 2s p |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808041809 |
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