Effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer-derived-matrix-based SiC/SiC composites

A carbon layer can be produced on the surfaces of the SiC fibers used in SiC-fiber-reinforced SiC matrix (SiC/SiC) composites via high-temperature heat treatment in a reductive atmosphere. This layer acts as an interfacial sliding layer and helps tailor the mechanical characteristics of the composit...

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Main Authors: Masaki Kotani, Shinji Ogihara
Format: Article
Language:English
Published: Taylor & Francis Group 2021-04-01
Series:Journal of Asian Ceramic Societies
Subjects:
Online Access:http://dx.doi.org/10.1080/21870764.2021.1896095
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author Masaki Kotani
Shinji Ogihara
author_facet Masaki Kotani
Shinji Ogihara
author_sort Masaki Kotani
collection DOAJ
description A carbon layer can be produced on the surfaces of the SiC fibers used in SiC-fiber-reinforced SiC matrix (SiC/SiC) composites via high-temperature heat treatment in a reductive atmosphere. This layer acts as an interfacial sliding layer and helps tailor the mechanical characteristics of the composites. The pyrochemical technique is more efficient and cost-effective than the more commonly used chemical vapor infiltration (CVI) for producing the aforementioned carbon layer. In this study, the effects of the pyrochemical technique on the tensile properties of polymer-derived-matrix-based SiC/SiC composites were evaluated and compared with those obtained via CVI. Although the SiC fibers tested were not weakened by the pyrochemical treatment, the composite formed using the pyrochemically treated fibers showed a lower tensile strength than that of the composite with CVI-treated fibers. This strength reduction was probably caused by a decrease in the Young’s modulus of the fibers after the pyrochemical treatment. The matrix in the former case experienced multiple fractures, leading to the decline of its load-transferring capability at lower applied stresses. This deterioration can be redeemed by increasing the fiber volume fraction (Vf), and therefore needs to be considered when designing components for composites.
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spelling doaj.art-473d039dff6f4569b80f9689c17256622022-12-21T21:58:16ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642021-04-019251953010.1080/21870764.2021.18960951896095Effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer-derived-matrix-based SiC/SiC compositesMasaki Kotani0Shinji Ogihara1Japan Aerospace Exploration AgencyTokyo University of ScienceA carbon layer can be produced on the surfaces of the SiC fibers used in SiC-fiber-reinforced SiC matrix (SiC/SiC) composites via high-temperature heat treatment in a reductive atmosphere. This layer acts as an interfacial sliding layer and helps tailor the mechanical characteristics of the composites. The pyrochemical technique is more efficient and cost-effective than the more commonly used chemical vapor infiltration (CVI) for producing the aforementioned carbon layer. In this study, the effects of the pyrochemical technique on the tensile properties of polymer-derived-matrix-based SiC/SiC composites were evaluated and compared with those obtained via CVI. Although the SiC fibers tested were not weakened by the pyrochemical treatment, the composite formed using the pyrochemically treated fibers showed a lower tensile strength than that of the composite with CVI-treated fibers. This strength reduction was probably caused by a decrease in the Young’s modulus of the fibers after the pyrochemical treatment. The matrix in the former case experienced multiple fractures, leading to the decline of its load-transferring capability at lower applied stresses. This deterioration can be redeemed by increasing the fiber volume fraction (Vf), and therefore needs to be considered when designing components for composites.http://dx.doi.org/10.1080/21870764.2021.1896095sic-fiber-reinforced sic matrix (sic/sic) compositepyrochemical treatmentchemical vapor infiltration (cvi)tensile strengthfiber properties
spellingShingle Masaki Kotani
Shinji Ogihara
Effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer-derived-matrix-based SiC/SiC composites
Journal of Asian Ceramic Societies
sic-fiber-reinforced sic matrix (sic/sic) composite
pyrochemical treatment
chemical vapor infiltration (cvi)
tensile strength
fiber properties
title Effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer-derived-matrix-based SiC/SiC composites
title_full Effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer-derived-matrix-based SiC/SiC composites
title_fullStr Effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer-derived-matrix-based SiC/SiC composites
title_full_unstemmed Effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer-derived-matrix-based SiC/SiC composites
title_short Effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer-derived-matrix-based SiC/SiC composites
title_sort effects of pyrochemical treatment for producing interfacial carbon layer on tensile properties of polymer derived matrix based sic sic composites
topic sic-fiber-reinforced sic matrix (sic/sic) composite
pyrochemical treatment
chemical vapor infiltration (cvi)
tensile strength
fiber properties
url http://dx.doi.org/10.1080/21870764.2021.1896095
work_keys_str_mv AT masakikotani effectsofpyrochemicaltreatmentforproducinginterfacialcarbonlayerontensilepropertiesofpolymerderivedmatrixbasedsicsiccomposites
AT shinjiogihara effectsofpyrochemicaltreatmentforproducinginterfacialcarbonlayerontensilepropertiesofpolymerderivedmatrixbasedsicsiccomposites