A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln<sub>2</sub>L<sub>3</sub> Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-Dicarboxylates
In this study, novel hybrid materials exhibiting luminescent properties were prepared and characterized. A top-down approach obtained a series of polymeric materials with incorporated different amounts (0.1; 0.2; 0.5; 1, and 2 wt.%) of dopants, i.e., europium(III) and terbium(III) 1H-pyrazole-3,5-di...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2022-12-01
|
| Series: | Materials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1996-1944/15/24/8826 |
| _version_ | 1797456583778631680 |
|---|---|
| author | Renata Łyszczek Dmytro Vlasyuk Beata Podkościelna Halina Głuchowska Ryszard Piramidowicz Anna Jusza |
| author_facet | Renata Łyszczek Dmytro Vlasyuk Beata Podkościelna Halina Głuchowska Ryszard Piramidowicz Anna Jusza |
| author_sort | Renata Łyszczek |
| collection | DOAJ |
| description | In this study, novel hybrid materials exhibiting luminescent properties were prepared and characterized. A top-down approach obtained a series of polymeric materials with incorporated different amounts (0.1; 0.2; 0.5; 1, and 2 wt.%) of dopants, i.e., europium(III) and terbium(III) 1H-pyrazole-3,5-dicarboxylates, as luminescent sources. Methyl methacrylate and bisphenol A diacrylate monomers were applied for matrix formation. The resulting materials were characterized using Fourier transform infrared spectroscopy (FTIR) and thermal analysis methods (TG-DTG-DSC, TG-FTIR) in air and nitrogen atmosphere, as well as by luminescence spectroscopy. The homogeneity of the resulting materials was investigated by means of optical microscopy. All obtained materials exhibited good thermal stability in both oxidizing and inert atmospheres. The addition of lanthanide(III) complexes slightly changed the thermal decomposition pathways. The main volatile products of materials pyrolysis are carbon oxides, water, methyl methacrylic acid and its derivatives, bisphenol A, 4-propylphenol, and methane. The luminescence properties of the lanthanide complexes and the prepared hybrid materials were investigated in detail. |
| first_indexed | 2024-03-09T16:08:54Z |
| format | Article |
| id | doaj.art-4746913fb7da4839809b0ffd02a12aca |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-09T16:08:54Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-4746913fb7da4839809b0ffd02a12aca2023-11-24T16:22:25ZengMDPI AGMaterials1996-19442022-12-011524882610.3390/ma15248826A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln<sub>2</sub>L<sub>3</sub> Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-DicarboxylatesRenata Łyszczek0Dmytro Vlasyuk1Beata Podkościelna2Halina Głuchowska3Ryszard Piramidowicz4Anna Jusza5Department of General and Coordination Chemistry and Crystallography, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie–Skłodowska University, M. Curie-Skłodowskiej Sq. 2, 20-031 Lublin, PolandDepartment of General and Coordination Chemistry and Crystallography, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie–Skłodowska University, M. Curie-Skłodowskiej Sq. 2, 20-031 Lublin, PolandDepartment of Polymer Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie–Skłodowska University, Gliniana 33, 20-614 Lublin, PolandDepartment of General and Coordination Chemistry and Crystallography, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie–Skłodowska University, M. Curie-Skłodowskiej Sq. 2, 20-031 Lublin, PolandInstitute of Microelectronics and Optoelectronics, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw, PolandInstitute of Microelectronics and Optoelectronics, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw, PolandIn this study, novel hybrid materials exhibiting luminescent properties were prepared and characterized. A top-down approach obtained a series of polymeric materials with incorporated different amounts (0.1; 0.2; 0.5; 1, and 2 wt.%) of dopants, i.e., europium(III) and terbium(III) 1H-pyrazole-3,5-dicarboxylates, as luminescent sources. Methyl methacrylate and bisphenol A diacrylate monomers were applied for matrix formation. The resulting materials were characterized using Fourier transform infrared spectroscopy (FTIR) and thermal analysis methods (TG-DTG-DSC, TG-FTIR) in air and nitrogen atmosphere, as well as by luminescence spectroscopy. The homogeneity of the resulting materials was investigated by means of optical microscopy. All obtained materials exhibited good thermal stability in both oxidizing and inert atmospheres. The addition of lanthanide(III) complexes slightly changed the thermal decomposition pathways. The main volatile products of materials pyrolysis are carbon oxides, water, methyl methacrylic acid and its derivatives, bisphenol A, 4-propylphenol, and methane. The luminescence properties of the lanthanide complexes and the prepared hybrid materials were investigated in detail.https://www.mdpi.com/1996-1944/15/24/88261H-pyrazole-3,5-dicarboxylatespolymershybrid materialsluminescencethermal analysis |
| spellingShingle | Renata Łyszczek Dmytro Vlasyuk Beata Podkościelna Halina Głuchowska Ryszard Piramidowicz Anna Jusza A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln<sub>2</sub>L<sub>3</sub> Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-Dicarboxylates Materials 1H-pyrazole-3,5-dicarboxylates polymers hybrid materials luminescence thermal analysis |
| title | A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln<sub>2</sub>L<sub>3</sub> Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-Dicarboxylates |
| title_full | A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln<sub>2</sub>L<sub>3</sub> Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-Dicarboxylates |
| title_fullStr | A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln<sub>2</sub>L<sub>3</sub> Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-Dicarboxylates |
| title_full_unstemmed | A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln<sub>2</sub>L<sub>3</sub> Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-Dicarboxylates |
| title_short | A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln<sub>2</sub>L<sub>3</sub> Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-Dicarboxylates |
| title_sort | top down approach and thermal characterization of luminescent hybrid bpa da mma ln sub 2 sub l sub 3 sub materials based on lanthanide iii 1h pyrazole 3 5 dicarboxylates |
| topic | 1H-pyrazole-3,5-dicarboxylates polymers hybrid materials luminescence thermal analysis |
| url | https://www.mdpi.com/1996-1944/15/24/8826 |
| work_keys_str_mv | AT renatałyszczek atopdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT dmytrovlasyuk atopdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT beatapodkoscielna atopdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT halinagłuchowska atopdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT ryszardpiramidowicz atopdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT annajusza atopdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT renatałyszczek topdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT dmytrovlasyuk topdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT beatapodkoscielna topdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT halinagłuchowska topdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT ryszardpiramidowicz topdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates AT annajusza topdownapproachandthermalcharacterizationofluminescenthybridbpadammalnsub2sublsub3submaterialsbasedonlanthanideiii1hpyrazole35dicarboxylates |