Fast synthesis of large-area bilayer graphene film on Cu
Abstract Bilayer graphene (BLG) is intriguing for its unique properties and potential applications in electronics, photonics, and mechanics. However, the chemical vapor deposition synthesis of large-area high-quality bilayer graphene on Cu is suffering from a low growth rate and limited bilayer cove...
| Main Authors: | , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2023-06-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-023-38877-9 |
| _version_ | 1797811401375350784 |
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| author | Jincan Zhang Xiaoting Liu Mengqi Zhang Rui Zhang Huy Q. Ta Jianbo Sun Wendong Wang Wenqing Zhu Tiantian Fang Kaicheng Jia Xiucai Sun Xintong Zhang Yeshu Zhu Jiaxin Shao Yuchen Liu Xin Gao Qian Yang Luzhao Sun Qin Li Fushun Liang Heng Chen Liming Zheng Fuyi Wang Wanjian Yin Xiaoding Wei Jianbo Yin Thomas Gemming Mark. H. Rummeli Haihui Liu Hailin Peng Li Lin Zhongfan Liu |
| author_facet | Jincan Zhang Xiaoting Liu Mengqi Zhang Rui Zhang Huy Q. Ta Jianbo Sun Wendong Wang Wenqing Zhu Tiantian Fang Kaicheng Jia Xiucai Sun Xintong Zhang Yeshu Zhu Jiaxin Shao Yuchen Liu Xin Gao Qian Yang Luzhao Sun Qin Li Fushun Liang Heng Chen Liming Zheng Fuyi Wang Wanjian Yin Xiaoding Wei Jianbo Yin Thomas Gemming Mark. H. Rummeli Haihui Liu Hailin Peng Li Lin Zhongfan Liu |
| author_sort | Jincan Zhang |
| collection | DOAJ |
| description | Abstract Bilayer graphene (BLG) is intriguing for its unique properties and potential applications in electronics, photonics, and mechanics. However, the chemical vapor deposition synthesis of large-area high-quality bilayer graphene on Cu is suffering from a low growth rate and limited bilayer coverage. Herein, we demonstrate the fast synthesis of meter-sized bilayer graphene film on commercial polycrystalline Cu foils by introducing trace CO2 during high-temperature growth. Continuous bilayer graphene with a high ratio of AB-stacking structure can be obtained within 20 min, which exhibits enhanced mechanical strength, uniform transmittance, and low sheet resistance in large area. Moreover, 96 and 100% AB-stacking structures were achieved in bilayer graphene grown on single-crystal Cu(111) foil and ultraflat single-crystal Cu(111)/sapphire substrates, respectively. The AB-stacking bilayer graphene exhibits tunable bandgap and performs well in photodetection. This work provides important insights into the growth mechanism and the mass production of large-area high-quality BLG on Cu. |
| first_indexed | 2024-03-13T07:23:07Z |
| format | Article |
| id | doaj.art-474da1aed7284df5937f8b76849d21de |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-03-13T07:23:07Z |
| publishDate | 2023-06-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-474da1aed7284df5937f8b76849d21de2023-06-04T11:32:33ZengNature PortfolioNature Communications2041-17232023-06-011411910.1038/s41467-023-38877-9Fast synthesis of large-area bilayer graphene film on CuJincan Zhang0Xiaoting Liu1Mengqi Zhang2Rui Zhang3Huy Q. Ta4Jianbo Sun5Wendong Wang6Wenqing Zhu7Tiantian Fang8Kaicheng Jia9Xiucai Sun10Xintong Zhang11Yeshu Zhu12Jiaxin Shao13Yuchen Liu14Xin Gao15Qian Yang16Luzhao Sun17Qin Li18Fushun Liang19Heng Chen20Liming Zheng21Fuyi Wang22Wanjian Yin23Xiaoding Wei24Jianbo Yin25Thomas Gemming26Mark. H. Rummeli27Haihui Liu28Hailin Peng29Li Lin30Zhongfan Liu31Center for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityBeijing Graphene InstituteDepartment of Physics and Astronomy, University of ManchesterLeibniz Institute for Solid State and Materials Research DresdenBeijing Graphene InstituteDepartment of Physics and Astronomy, University of ManchesterState Key Laboratory for Turbulence and Complex System, Department of Mechanics and Engineering Science, College of Engineering, Peking UniversityCAS Key Laboratory of Analytical Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of SciencesCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityBeijing Graphene InstituteCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityBeijing Graphene InstituteCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityBeijing Graphene InstituteCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityBeijing National Laboratory for Molecular Sciences, National Centre for Mass Spectrometry in Beijing, CAS Key Laboratory of Analytical Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of SciencesSoochow Institute for Energy and Materials Innovations, Soochow UniversityState Key Laboratory for Turbulence and Complex System, Department of Mechanics and Engineering Science, College of Engineering, Peking UniversityBeijing Graphene InstituteLeibniz Institute for Solid State and Materials Research DresdenLeibniz Institute for Solid State and Materials Research DresdenSchool of Material Science and Engineering, Tianjin Key Laboratory of Advanced Fibers and Energy Storage, State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversitySchool of Materials Science and Engineering, Peking UniversityCenter for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking UniversityAbstract Bilayer graphene (BLG) is intriguing for its unique properties and potential applications in electronics, photonics, and mechanics. However, the chemical vapor deposition synthesis of large-area high-quality bilayer graphene on Cu is suffering from a low growth rate and limited bilayer coverage. Herein, we demonstrate the fast synthesis of meter-sized bilayer graphene film on commercial polycrystalline Cu foils by introducing trace CO2 during high-temperature growth. Continuous bilayer graphene with a high ratio of AB-stacking structure can be obtained within 20 min, which exhibits enhanced mechanical strength, uniform transmittance, and low sheet resistance in large area. Moreover, 96 and 100% AB-stacking structures were achieved in bilayer graphene grown on single-crystal Cu(111) foil and ultraflat single-crystal Cu(111)/sapphire substrates, respectively. The AB-stacking bilayer graphene exhibits tunable bandgap and performs well in photodetection. This work provides important insights into the growth mechanism and the mass production of large-area high-quality BLG on Cu.https://doi.org/10.1038/s41467-023-38877-9 |
| spellingShingle | Jincan Zhang Xiaoting Liu Mengqi Zhang Rui Zhang Huy Q. Ta Jianbo Sun Wendong Wang Wenqing Zhu Tiantian Fang Kaicheng Jia Xiucai Sun Xintong Zhang Yeshu Zhu Jiaxin Shao Yuchen Liu Xin Gao Qian Yang Luzhao Sun Qin Li Fushun Liang Heng Chen Liming Zheng Fuyi Wang Wanjian Yin Xiaoding Wei Jianbo Yin Thomas Gemming Mark. H. Rummeli Haihui Liu Hailin Peng Li Lin Zhongfan Liu Fast synthesis of large-area bilayer graphene film on Cu Nature Communications |
| title | Fast synthesis of large-area bilayer graphene film on Cu |
| title_full | Fast synthesis of large-area bilayer graphene film on Cu |
| title_fullStr | Fast synthesis of large-area bilayer graphene film on Cu |
| title_full_unstemmed | Fast synthesis of large-area bilayer graphene film on Cu |
| title_short | Fast synthesis of large-area bilayer graphene film on Cu |
| title_sort | fast synthesis of large area bilayer graphene film on cu |
| url | https://doi.org/10.1038/s41467-023-38877-9 |
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