Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexes
This data article contains the 1H Nuclear Magnetic Resonance (NMR), ultraviolet and visible (UV–vis) and Attenuated Total Reflectance Fourier Transformed Infra-red (ATR FTIR) characterization of a series of organophosphorus-containing rhodium(I) complexes. The electrochemical data acquired by means...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Elsevier
2018-12-01
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| Series: | Data in Brief |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2352340918313209 |
| _version_ | 1818863822437351424 |
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| author | P.S. Manana E. Erasmus |
| author_facet | P.S. Manana E. Erasmus |
| author_sort | P.S. Manana |
| collection | DOAJ |
| description | This data article contains the 1H Nuclear Magnetic Resonance (NMR), ultraviolet and visible (UV–vis) and Attenuated Total Reflectance Fourier Transformed Infra-red (ATR FTIR) characterization of a series of organophosphorus-containing rhodium(I) complexes. The electrochemical data acquired by means of cyclic voltammetry of the three organophosphorus-containing ligands (with the structure C6H5XPPh2, where X = O, S and NH) and their acetylacetonato (monocarbonyl) organophosphorus rhodium(I) compounds, [Rh(acac)CO(C6H5XPPh2)] are reported. Additionally, the kinetic data of the oxidative addition of methyl iodide to the rhodium(I) complexes, are also presented. |
| first_indexed | 2024-12-19T10:21:52Z |
| format | Article |
| id | doaj.art-47511bf1beeb4a7eb4e6f8825e005c54 |
| institution | Directory Open Access Journal |
| issn | 2352-3409 |
| language | English |
| last_indexed | 2024-12-19T10:21:52Z |
| publishDate | 2018-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Data in Brief |
| spelling | doaj.art-47511bf1beeb4a7eb4e6f8825e005c542022-12-21T20:26:02ZengElsevierData in Brief2352-34092018-12-012113891402Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexesP.S. Manana0E. Erasmus1Department of Chemistry, University of the Free State, Bloemfontein 9300, South AfricaCorresponding author.; Department of Chemistry, University of the Free State, Bloemfontein 9300, South AfricaThis data article contains the 1H Nuclear Magnetic Resonance (NMR), ultraviolet and visible (UV–vis) and Attenuated Total Reflectance Fourier Transformed Infra-red (ATR FTIR) characterization of a series of organophosphorus-containing rhodium(I) complexes. The electrochemical data acquired by means of cyclic voltammetry of the three organophosphorus-containing ligands (with the structure C6H5XPPh2, where X = O, S and NH) and their acetylacetonato (monocarbonyl) organophosphorus rhodium(I) compounds, [Rh(acac)CO(C6H5XPPh2)] are reported. Additionally, the kinetic data of the oxidative addition of methyl iodide to the rhodium(I) complexes, are also presented.http://www.sciencedirect.com/science/article/pii/S2352340918313209 |
| spellingShingle | P.S. Manana E. Erasmus Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexes Data in Brief |
| title | Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexes |
| title_full | Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexes |
| title_fullStr | Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexes |
| title_full_unstemmed | Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexes |
| title_short | Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexes |
| title_sort | characterisation electrochemical and oxidative addition data of organophosphorus containing rhodium i complexes |
| url | http://www.sciencedirect.com/science/article/pii/S2352340918313209 |
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