The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene
In Raman spectroscopy of graphite and graphene, the D band at ∼ 1355 cm−1 is used as the indication of the dirtiness of a sample. However, our analysis suggests that the physics behind the D band is closely related to a very clear idea for describing a molecule, namely bonding and antibonding orbita...
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MDPI AG
2013-02-01
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Series: | Crystals |
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Online Access: | http://www.mdpi.com/2073-4352/3/1/120 |
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author | Tetsuomi Sogawa Yasuhiro Tokura Ken-ichi Sasaki |
author_facet | Tetsuomi Sogawa Yasuhiro Tokura Ken-ichi Sasaki |
author_sort | Tetsuomi Sogawa |
collection | DOAJ |
description | In Raman spectroscopy of graphite and graphene, the D band at ∼ 1355 cm−1 is used as the indication of the dirtiness of a sample. However, our analysis suggests that the physics behind the D band is closely related to a very clear idea for describing a molecule, namely bonding and antibonding orbitals in graphene. In this paper, we review our recent work on the mechanism for activating the D band at a graphene edge. |
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institution | Directory Open Access Journal |
issn | 2073-4352 |
language | English |
last_indexed | 2024-12-10T07:57:16Z |
publishDate | 2013-02-01 |
publisher | MDPI AG |
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series | Crystals |
spelling | doaj.art-476ab4f8130b42968490ca27cfc0b3de2022-12-22T01:56:53ZengMDPI AGCrystals2073-43522013-02-013112014010.3390/cryst3010120The Origin of Raman D Band: Bonding and Antibonding Orbitals in GrapheneTetsuomi SogawaYasuhiro TokuraKen-ichi SasakiIn Raman spectroscopy of graphite and graphene, the D band at ∼ 1355 cm−1 is used as the indication of the dirtiness of a sample. However, our analysis suggests that the physics behind the D band is closely related to a very clear idea for describing a molecule, namely bonding and antibonding orbitals in graphene. In this paper, we review our recent work on the mechanism for activating the D band at a graphene edge.http://www.mdpi.com/2073-4352/3/1/120grapheneedgeRaman D bandmolecular orbitals |
spellingShingle | Tetsuomi Sogawa Yasuhiro Tokura Ken-ichi Sasaki The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene Crystals graphene edge Raman D band molecular orbitals |
title | The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene |
title_full | The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene |
title_fullStr | The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene |
title_full_unstemmed | The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene |
title_short | The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene |
title_sort | origin of raman d band bonding and antibonding orbitals in graphene |
topic | graphene edge Raman D band molecular orbitals |
url | http://www.mdpi.com/2073-4352/3/1/120 |
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