Tensor Approximation of Slater-Type Orbital Basis Functions

This paper deals with a tensor representation of the Slater-type orbital basis functions. Localized basis systems are primarily used in electronic structure calculations. A choice of the system is usually limited to Gaussian-type orbitals due to the impossibility of the analytical evaluation of nece...

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Main Author: Martin Mrovec
Format: Article
Language:English
Published: VSB-Technical University of Ostrava 2017-01-01
Series:Advances in Electrical and Electronic Engineering
Subjects:
Online Access:http://advances.utc.sk/index.php/AEEE/article/view/2235
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author Martin Mrovec
author_facet Martin Mrovec
author_sort Martin Mrovec
collection DOAJ
description This paper deals with a tensor representation of the Slater-type orbital basis functions. Localized basis systems are primarily used in electronic structure calculations. A choice of the system is usually limited to Gaussian-type orbitals due to the impossibility of the analytical evaluation of necessary integrals using other basis types. Unfortunately, it is not possible to use direct discretization techniques due to the dimensionality of the problem so the numerical integration is problematic. Tensor Numerical Methods overcome this problem by using special data representations, which are discussed. Finally, it is demonstrated how to use these methods to construct a tensor approximation of Slater-type orbital basis functions including an error estimate and its numerical verification.
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spelling doaj.art-4784412dd30f47f7baa515b00b498a0f2023-05-14T20:50:11ZengVSB-Technical University of OstravaAdvances in Electrical and Electronic Engineering1336-13761804-31192017-01-0115231432110.15598/aeee.v15i2.2235901Tensor Approximation of Slater-Type Orbital Basis FunctionsMartin Mrovec0Department of Applied Mathematics, Faculty of Electrical Engineering and Computer Science, VSB-Technical University of Ostrava, 17. listopadu 15/2172, Ostrava 708 33, Czech Republic & IT4Innovations National Supercomputing Center, VSB-Technical University of Ostrava, Studentska 6231/1B, Ostrava 708 33, Czech RepublicThis paper deals with a tensor representation of the Slater-type orbital basis functions. Localized basis systems are primarily used in electronic structure calculations. A choice of the system is usually limited to Gaussian-type orbitals due to the impossibility of the analytical evaluation of necessary integrals using other basis types. Unfortunately, it is not possible to use direct discretization techniques due to the dimensionality of the problem so the numerical integration is problematic. Tensor Numerical Methods overcome this problem by using special data representations, which are discussed. Finally, it is demonstrated how to use these methods to construct a tensor approximation of Slater-type orbital basis functions including an error estimate and its numerical verification.http://advances.utc.sk/index.php/AEEE/article/view/2235electronic structuregaussian-type orbitalsinc approximationslater-type orbitaltensor numerical methods.
spellingShingle Martin Mrovec
Tensor Approximation of Slater-Type Orbital Basis Functions
Advances in Electrical and Electronic Engineering
electronic structure
gaussian-type orbital
sinc approximation
slater-type orbital
tensor numerical methods.
title Tensor Approximation of Slater-Type Orbital Basis Functions
title_full Tensor Approximation of Slater-Type Orbital Basis Functions
title_fullStr Tensor Approximation of Slater-Type Orbital Basis Functions
title_full_unstemmed Tensor Approximation of Slater-Type Orbital Basis Functions
title_short Tensor Approximation of Slater-Type Orbital Basis Functions
title_sort tensor approximation of slater type orbital basis functions
topic electronic structure
gaussian-type orbital
sinc approximation
slater-type orbital
tensor numerical methods.
url http://advances.utc.sk/index.php/AEEE/article/view/2235
work_keys_str_mv AT martinmrovec tensorapproximationofslatertypeorbitalbasisfunctions