Adsorption of Mefenamic Acid From Water by Bentonite Poly urea formaldehyde Composite Adsorbent

Poly urea formaldehyde –Bentonite (PUF-Bentonite) composite was tested as new adsorbent for removal of mefenamic acid (MA) from simulated wastewater in batch adsorption procedure. Developed a method for preparing poly urea formaldehyde gel in basic media by using condensation polymerization. Adsorp...

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Main Authors: Basma Abbas Abdel Majeed, Prof. Dr., Raheem Jameel Muhseen, Ass. Prof. Dr., Nawras Jameel Jassim, Ass. Lect.
Format: Article
Language:English
Published: University of Baghdad 2017-06-01
Series:Journal of Engineering
Subjects:
Online Access:http://joe.uobaghdad.edu.iq/index.php/main/article/view/19
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author Basma Abbas Abdel Majeed, Prof. Dr.
Raheem Jameel Muhseen, Ass. Prof. Dr.
Nawras Jameel Jassim, Ass. Lect.
author_facet Basma Abbas Abdel Majeed, Prof. Dr.
Raheem Jameel Muhseen, Ass. Prof. Dr.
Nawras Jameel Jassim, Ass. Lect.
author_sort Basma Abbas Abdel Majeed, Prof. Dr.
collection DOAJ
description Poly urea formaldehyde –Bentonite (PUF-Bentonite) composite was tested as new adsorbent for removal of mefenamic acid (MA) from simulated wastewater in batch adsorption procedure. Developed a method for preparing poly urea formaldehyde gel in basic media by using condensation polymerization. Adsorption experiments were carried out as a function of water pH, temperature, contact time, adsorbent dose and initial MA concentration .Effect of sharing surface with other analgesic pharmaceuticals at different pH also studied. The adsorption of MA was found to be strongly dependent to pH. The Freundlich isotherm model showed a good fit to the equilibrium adsorption data. From Dubinin–Radushkevich model the mean free energy (E) was calculated and the value of 5 KJ/mole indicated that the main mechanism governing the adsorption of MA on PUF-Bentonite composite was physical in nature. The kinetics of adsorption tested for first order, pseudo second order models and Elovich’s equation, results showed the adsorption followed the pseudo-second-order model.
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spelling doaj.art-4794dc55c77d406b8f0e0d618218a44c2023-09-02T14:07:59ZengUniversity of BaghdadJournal of Engineering1726-40732520-33392017-06-01237Adsorption of Mefenamic Acid From Water by Bentonite Poly urea formaldehyde Composite AdsorbentBasma Abbas Abdel Majeed, Prof. Dr.0Raheem Jameel Muhseen, Ass. Prof. Dr.1Nawras Jameel Jassim, Ass. Lect.2Chemical Engineering Department - University of Baghdadcollege of Pharmacy-University of BasraBasra Technical Institute -Southern Technical UniversityPoly urea formaldehyde –Bentonite (PUF-Bentonite) composite was tested as new adsorbent for removal of mefenamic acid (MA) from simulated wastewater in batch adsorption procedure. Developed a method for preparing poly urea formaldehyde gel in basic media by using condensation polymerization. Adsorption experiments were carried out as a function of water pH, temperature, contact time, adsorbent dose and initial MA concentration .Effect of sharing surface with other analgesic pharmaceuticals at different pH also studied. The adsorption of MA was found to be strongly dependent to pH. The Freundlich isotherm model showed a good fit to the equilibrium adsorption data. From Dubinin–Radushkevich model the mean free energy (E) was calculated and the value of 5 KJ/mole indicated that the main mechanism governing the adsorption of MA on PUF-Bentonite composite was physical in nature. The kinetics of adsorption tested for first order, pseudo second order models and Elovich’s equation, results showed the adsorption followed the pseudo-second-order model.http://joe.uobaghdad.edu.iq/index.php/main/article/view/19Mefenamic acid adsorptionBentoniteAnalgesicPoly urea formaldehyde
spellingShingle Basma Abbas Abdel Majeed, Prof. Dr.
Raheem Jameel Muhseen, Ass. Prof. Dr.
Nawras Jameel Jassim, Ass. Lect.
Adsorption of Mefenamic Acid From Water by Bentonite Poly urea formaldehyde Composite Adsorbent
Journal of Engineering
Mefenamic acid adsorption
Bentonite
Analgesic
Poly urea formaldehyde
title Adsorption of Mefenamic Acid From Water by Bentonite Poly urea formaldehyde Composite Adsorbent
title_full Adsorption of Mefenamic Acid From Water by Bentonite Poly urea formaldehyde Composite Adsorbent
title_fullStr Adsorption of Mefenamic Acid From Water by Bentonite Poly urea formaldehyde Composite Adsorbent
title_full_unstemmed Adsorption of Mefenamic Acid From Water by Bentonite Poly urea formaldehyde Composite Adsorbent
title_short Adsorption of Mefenamic Acid From Water by Bentonite Poly urea formaldehyde Composite Adsorbent
title_sort adsorption of mefenamic acid from water by bentonite poly urea formaldehyde composite adsorbent
topic Mefenamic acid adsorption
Bentonite
Analgesic
Poly urea formaldehyde
url http://joe.uobaghdad.edu.iq/index.php/main/article/view/19
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AT nawrasjameeljassimasslect adsorptionofmefenamicacidfromwaterbybentonitepolyureaformaldehydecompositeadsorbent