| Summary: | The variation of wood species processed in sawmills in developing countries generates composite waste which presents treatment challenges due to a lack of understanding of their physicochemical characteristics for proper planning for clean energy generation. Most of the waste is discarded or burnt openly which releases harmful gases into the environment. This study investigated the physicochemical characteristics of mixed sawdust generated from five wood species generated at a Ghanaian sawmill in Oforikrom Municipality for improving waste treatment. The particle size distribution (PSD), bulk density, proximate and ultimate values, thermogravimetric analysis (TGA) and structural analysis were used to characterize the composite sawdust for briquetting and gasification purposes. It was found that the net heating value (17.46 MJ/kg), some proximate and ultimate values meet briquette standard but high percentages of ash (2.95%), moisture (41.48%) and the possibility of nitrogen oxides emissions were notable challenges. PSD resulted in different high fine fractions which are unsuitable for densification. The increase of sieving amplitudes at 30, 50 and 80 rpm generated an average increase in sieve efficiency of fines by 4.22%. Mixing of fines (42.38–46.6%) and optimum particle size (53.40–57.62%) fractions was suggested as the best approach to enhance briquette density and durability. The FTIR spectra showed a range of peaks such as 1734.46 cm−1, 1620.48 cm−1, 1506.50 cm−1, 1462.02 cm−1, 1420.32 cm−1 etc. for functional groups identification. Composite sawdust spectra showed high absorbance with no shift of wavenumbers compared with temperate woods, however, it deviated massively when compared with industrial cellulose and organosolv lignin. TGA indicated that exact mixed wood pyrolysis temperatures, volatile and biochar fractions will always depend on sample compositions. The increase in heating rates yielded little significance to volatiles and char increments. Collection of clean sawdust and rooftop drying were recommended as a way of enhancing sawdust properties. Composite sawdust has a promising potential to support Ghana's activities for meeting the renewable energy generation targets. The understanding of these potential assessments is significant to boost the local municipality energy supply.
|
|---|