Reversible Water Ad-/Desorption Behavior of a 3D Polycatenation Network, [Zn(bpp)(BDC)]·1.5(H<sub>2</sub>O), Constructed by 2D Undulated Layered MOF
A three-dimensional (3D) polycatenation supramolecular network with chemical formulas, [Zn(bpp)(BDC)]·1.5H<sub>2</sub>O (<b>1</b>), (bpp = 1,3-bis(4-pyridyl)propane, BDC<sup>2−</sup> = dianion of terephthalic acid), was synthesized and structurally determined. In...
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MDPI AG
2021-04-01
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| author | Chih-Chieh Wang Wei-Cheng Yi Zi-Ling Huang Wen-Chi Chien Yu-Chun Chuang Gene-Hsiang Lee |
| author_facet | Chih-Chieh Wang Wei-Cheng Yi Zi-Ling Huang Wen-Chi Chien Yu-Chun Chuang Gene-Hsiang Lee |
| author_sort | Chih-Chieh Wang |
| collection | DOAJ |
| description | A three-dimensional (3D) polycatenation supramolecular network with chemical formulas, [Zn(bpp)(BDC)]·1.5H<sub>2</sub>O (<b>1</b>), (bpp = 1,3-bis(4-pyridyl)propane, BDC<sup>2−</sup> = dianion of terephthalic acid), was synthesized and structurally determined. In compound <b>1</b>, the coordination geometry of Zn(II) ion is distorted tetrahedral, where its 2D undulated layered framework is constructed via the bridges of Zn(II) ions with bpp and BDC<sup>2−</sup> ligands. Adjacent 2D layers are arranged in a combined parallel and interpenetrated manner to complete its 3D polycatenation supramolecular architecture. Compound <b>1</b> shows a one-step dehydration process with the weight losses of 6.1%, approximately equal to the weight percentage of losing 1.5 guest water molecules. The cyclic thermogravimetric analysis reveals that compound <b>1</b> shows reversible, sponge-like water de-/adsorption behavior during de-/rehydration processes. Compound <b>1</b> also exhibits significant water vapor hysteresis isotherm. |
| first_indexed | 2024-03-10T12:38:31Z |
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| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T12:38:31Z |
| publishDate | 2021-04-01 |
| publisher | MDPI AG |
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| series | Crystals |
| spelling | doaj.art-47a48bf80c23462c90416cdc80d061ba2023-11-21T14:05:19ZengMDPI AGCrystals2073-43522021-04-0111437110.3390/cryst11040371Reversible Water Ad-/Desorption Behavior of a 3D Polycatenation Network, [Zn(bpp)(BDC)]·1.5(H<sub>2</sub>O), Constructed by 2D Undulated Layered MOFChih-Chieh Wang0Wei-Cheng Yi1Zi-Ling Huang2Wen-Chi Chien3Yu-Chun Chuang4Gene-Hsiang Lee5Department of Chemistry, Soochow University, Taipei 11106, TaiwanDepartment of Chemistry, Soochow University, Taipei 11106, TaiwanDepartment of Chemistry, Soochow University, Taipei 11106, TaiwanDepartment of Chemistry, Soochow University, Taipei 11106, TaiwanInstrumentation Center, National Taiwan University, Taipei 10617, TaiwanNational Synchrotron Radiation Research Center, Hsinchu 30076, TaiwanA three-dimensional (3D) polycatenation supramolecular network with chemical formulas, [Zn(bpp)(BDC)]·1.5H<sub>2</sub>O (<b>1</b>), (bpp = 1,3-bis(4-pyridyl)propane, BDC<sup>2−</sup> = dianion of terephthalic acid), was synthesized and structurally determined. In compound <b>1</b>, the coordination geometry of Zn(II) ion is distorted tetrahedral, where its 2D undulated layered framework is constructed via the bridges of Zn(II) ions with bpp and BDC<sup>2−</sup> ligands. Adjacent 2D layers are arranged in a combined parallel and interpenetrated manner to complete its 3D polycatenation supramolecular architecture. Compound <b>1</b> shows a one-step dehydration process with the weight losses of 6.1%, approximately equal to the weight percentage of losing 1.5 guest water molecules. The cyclic thermogravimetric analysis reveals that compound <b>1</b> shows reversible, sponge-like water de-/adsorption behavior during de-/rehydration processes. Compound <b>1</b> also exhibits significant water vapor hysteresis isotherm.https://www.mdpi.com/2073-4352/11/4/371supramolecular compoundmetal–organic frameworkH bonding interactionπ-π stacking interaction |
| spellingShingle | Chih-Chieh Wang Wei-Cheng Yi Zi-Ling Huang Wen-Chi Chien Yu-Chun Chuang Gene-Hsiang Lee Reversible Water Ad-/Desorption Behavior of a 3D Polycatenation Network, [Zn(bpp)(BDC)]·1.5(H<sub>2</sub>O), Constructed by 2D Undulated Layered MOF Crystals supramolecular compound metal–organic framework H bonding interaction π-π stacking interaction |
| title | Reversible Water Ad-/Desorption Behavior of a 3D Polycatenation Network, [Zn(bpp)(BDC)]·1.5(H<sub>2</sub>O), Constructed by 2D Undulated Layered MOF |
| title_full | Reversible Water Ad-/Desorption Behavior of a 3D Polycatenation Network, [Zn(bpp)(BDC)]·1.5(H<sub>2</sub>O), Constructed by 2D Undulated Layered MOF |
| title_fullStr | Reversible Water Ad-/Desorption Behavior of a 3D Polycatenation Network, [Zn(bpp)(BDC)]·1.5(H<sub>2</sub>O), Constructed by 2D Undulated Layered MOF |
| title_full_unstemmed | Reversible Water Ad-/Desorption Behavior of a 3D Polycatenation Network, [Zn(bpp)(BDC)]·1.5(H<sub>2</sub>O), Constructed by 2D Undulated Layered MOF |
| title_short | Reversible Water Ad-/Desorption Behavior of a 3D Polycatenation Network, [Zn(bpp)(BDC)]·1.5(H<sub>2</sub>O), Constructed by 2D Undulated Layered MOF |
| title_sort | reversible water ad desorption behavior of a 3d polycatenation network zn bpp bdc ·1 5 h sub 2 sub o constructed by 2d undulated layered mof |
| topic | supramolecular compound metal–organic framework H bonding interaction π-π stacking interaction |
| url | https://www.mdpi.com/2073-4352/11/4/371 |
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