Preparation Efficiency of Nuclear Spin Singlet State: A Comparison Among Three Pulse Sequences

The preparation and detection of the nuclear singlet state are valuable and prospective for many applications related with compound molecular analysis. In this work, a proton spin coupled system containing two H nuclei in tripeptide (Ala-Gly-Gly, AGG) was selected as research object, and singlets we...

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Main Authors: Yi LI, Jia-xiang XIN, Jia-chen WANG, Da-xiu WEI, Ye-feng YAO
Format: Article
Language:zho
Published: Science Press 2021-06-01
Series:Chinese Journal of Magnetic Resonance
Subjects:
Online Access:http://121.43.60.238/bpxzz/article/2021/1000-4556/2020-2832.shtml
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author Yi LI
Jia-xiang XIN
Jia-chen WANG
Da-xiu WEI
Ye-feng YAO
author_facet Yi LI
Jia-xiang XIN
Jia-chen WANG
Da-xiu WEI
Ye-feng YAO
author_sort Yi LI
collection DOAJ
description The preparation and detection of the nuclear singlet state are valuable and prospective for many applications related with compound molecular analysis. In this work, a proton spin coupled system containing two H nuclei in tripeptide (Ala-Gly-Gly, AGG) was selected as research object, and singlets were prepared with three sets of different pulse sequences based on different principles. The lifetime of those singlets were measured, and the singlet preparation efficiencies of different sequences were compared. The results indicated that for the same spin coupling system of the same molecule, there is no significant difference in the lifetime of the singlet state prepared by different pulse sequences, while their preparation efficiencies could be relatively different.
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spelling doaj.art-47b8cf3785ff4ea58667217ae04a14ea2022-12-21T23:30:45ZzhoScience PressChinese Journal of Magnetic Resonance1000-45562021-06-0138222723810.11938/cjmr20202832Preparation Efficiency of Nuclear Spin Singlet State: A Comparison Among Three Pulse SequencesYi LI0Jia-xiang XIN1Jia-chen WANG2Da-xiu WEI3Ye-feng YAO4Shanghai Key Laboratory of Magnetic Resonance, College of Physics and Electronic Science, East China Normal University, Shanghai 200062, ChinaShanghai Key Laboratory of Magnetic Resonance, College of Physics and Electronic Science, East China Normal University, Shanghai 200062, ChinaShanghai Key Laboratory of Magnetic Resonance, College of Physics and Electronic Science, East China Normal University, Shanghai 200062, ChinaShanghai Key Laboratory of Magnetic Resonance, College of Physics and Electronic Science, East China Normal University, Shanghai 200062, ChinaShanghai Key Laboratory of Magnetic Resonance, College of Physics and Electronic Science, East China Normal University, Shanghai 200062, ChinaThe preparation and detection of the nuclear singlet state are valuable and prospective for many applications related with compound molecular analysis. In this work, a proton spin coupled system containing two H nuclei in tripeptide (Ala-Gly-Gly, AGG) was selected as research object, and singlets were prepared with three sets of different pulse sequences based on different principles. The lifetime of those singlets were measured, and the singlet preparation efficiencies of different sequences were compared. The results indicated that for the same spin coupling system of the same molecule, there is no significant difference in the lifetime of the singlet state prepared by different pulse sequences, while their preparation efficiencies could be relatively different.http://121.43.60.238/bpxzz/article/2021/1000-4556/2020-2832.shtmlnuclear magnetic resonance (nmr)nuclear spin singlet statepreparation efficiencyagg peptidepulse sequence
spellingShingle Yi LI
Jia-xiang XIN
Jia-chen WANG
Da-xiu WEI
Ye-feng YAO
Preparation Efficiency of Nuclear Spin Singlet State: A Comparison Among Three Pulse Sequences
Chinese Journal of Magnetic Resonance
nuclear magnetic resonance (nmr)
nuclear spin singlet state
preparation efficiency
agg peptide
pulse sequence
title Preparation Efficiency of Nuclear Spin Singlet State: A Comparison Among Three Pulse Sequences
title_full Preparation Efficiency of Nuclear Spin Singlet State: A Comparison Among Three Pulse Sequences
title_fullStr Preparation Efficiency of Nuclear Spin Singlet State: A Comparison Among Three Pulse Sequences
title_full_unstemmed Preparation Efficiency of Nuclear Spin Singlet State: A Comparison Among Three Pulse Sequences
title_short Preparation Efficiency of Nuclear Spin Singlet State: A Comparison Among Three Pulse Sequences
title_sort preparation efficiency of nuclear spin singlet state a comparison among three pulse sequences
topic nuclear magnetic resonance (nmr)
nuclear spin singlet state
preparation efficiency
agg peptide
pulse sequence
url http://121.43.60.238/bpxzz/article/2021/1000-4556/2020-2832.shtml
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AT jiaxiangxin preparationefficiencyofnuclearspinsingletstateacomparisonamongthreepulsesequences
AT jiachenwang preparationefficiencyofnuclearspinsingletstateacomparisonamongthreepulsesequences
AT daxiuwei preparationefficiencyofnuclearspinsingletstateacomparisonamongthreepulsesequences
AT yefengyao preparationefficiencyofnuclearspinsingletstateacomparisonamongthreepulsesequences