Ba2VO4Br
Single crystals of dibarium vanadate(V) bromide, Ba2VO4Br, were grown from a melt of Ba3(VO4)2 and BaBr2. Ba2VO4Br crystallizes in the space group Pbcm and is isotypic with the structure of chlorspodiosite, Ca2PO4Cl. Although the ionic radii in chlorspodiosite are different from those in dibarium va...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-02-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461700219X |
| _version_ | 1818547476777402368 |
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| author | Robert Haberkorn Jessica Bauer Guido Kickelbick |
| author_facet | Robert Haberkorn Jessica Bauer Guido Kickelbick |
| author_sort | Robert Haberkorn |
| collection | DOAJ |
| description | Single crystals of dibarium vanadate(V) bromide, Ba2VO4Br, were grown from a melt of Ba3(VO4)2 and BaBr2. Ba2VO4Br crystallizes in the space group Pbcm and is isotypic with the structure of chlorspodiosite, Ca2PO4Cl. Although the ionic radii in chlorspodiosite are different from those in dibarium vanadate bromide, the structures are very similar to one another. The V atom is coordinated by four O atoms, forming a slightly distorted tetrahedron. The Ba atoms occupy two different sites and are coordinated by six O atoms and three or four Br atoms, depending on the site occupied. |
| first_indexed | 2024-12-12T08:07:14Z |
| format | Article |
| id | doaj.art-47b92c3691244d1eba022ef3f3781f97 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-12T08:07:14Z |
| publishDate | 2017-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-47b92c3691244d1eba022ef3f3781f972022-12-22T00:31:54ZengInternational Union of CrystallographyIUCrData2414-31462017-02-0122x17021910.1107/S241431461700219Xwm4028Ba2VO4BrRobert Haberkorn0Jessica Bauer1Guido Kickelbick2Universität des Saarlandes, Anorganische Festkörperchemie, Campus C4.1, 66123 Saarbrücken, GermanyUniversität des Saarlandes, Anorganische Festkörperchemie, Campus C4.1, 66123 Saarbrücken, GermanyUniversität des Saarlandes, Anorganische Festkörperchemie, Campus C4.1, 66123 Saarbrücken, GermanySingle crystals of dibarium vanadate(V) bromide, Ba2VO4Br, were grown from a melt of Ba3(VO4)2 and BaBr2. Ba2VO4Br crystallizes in the space group Pbcm and is isotypic with the structure of chlorspodiosite, Ca2PO4Cl. Although the ionic radii in chlorspodiosite are different from those in dibarium vanadate bromide, the structures are very similar to one another. The V atom is coordinated by four O atoms, forming a slightly distorted tetrahedron. The Ba atoms occupy two different sites and are coordinated by six O atoms and three or four Br atoms, depending on the site occupied.http://scripts.iucr.org/cgi-bin/paper?S241431461700219Xcrystal structureX-ray diffractionsingle-crystal growthchlorspodiositeisotypism |
| spellingShingle | Robert Haberkorn Jessica Bauer Guido Kickelbick Ba2VO4Br IUCrData crystal structure X-ray diffraction single-crystal growth chlorspodiosite isotypism |
| title | Ba2VO4Br |
| title_full | Ba2VO4Br |
| title_fullStr | Ba2VO4Br |
| title_full_unstemmed | Ba2VO4Br |
| title_short | Ba2VO4Br |
| title_sort | ba2vo4br |
| topic | crystal structure X-ray diffraction single-crystal growth chlorspodiosite isotypism |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461700219X |
| work_keys_str_mv | AT roberthaberkorn ba2vo4br AT jessicabauer ba2vo4br AT guidokickelbick ba2vo4br |