Polyphenols Coordinated with Cu (II) in an Aqueous System Build Ion-Channel Coatings on Hair Surfaces
Recently, developments in the field of cosmetics have led to a renewed interest in hair dyeing. However, damage to the hair during the dyeing process has increased hesitation in attempting hair dyeing. As a result, hair dyes with minimal side effects have been in constant demand, and are being devel...
Main Authors: | , , , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2023-02-01
|
Series: | Materials |
Subjects: | |
Online Access: | https://www.mdpi.com/1996-1944/16/4/1333 |
_version_ | 1797619683234414592 |
---|---|
author | Lei Jin Daemyoung Yun Wei Zhang Jinsung Lee Hongchul Shin Donghyuk Kim Tae-Bong Kang Hyung-Sik Won Hohyoun Jang Whangi Kim |
author_facet | Lei Jin Daemyoung Yun Wei Zhang Jinsung Lee Hongchul Shin Donghyuk Kim Tae-Bong Kang Hyung-Sik Won Hohyoun Jang Whangi Kim |
author_sort | Lei Jin |
collection | DOAJ |
description | Recently, developments in the field of cosmetics have led to a renewed interest in hair dyeing. However, damage to the hair during the dyeing process has increased hesitation in attempting hair dyeing. As a result, hair dyes with minimal side effects have been in constant demand, and are being developed. In this study, natural-extract polyphenols, pyrogallol, and gallic acid are coordinated by CuCl<sub>2</sub> in a NaCl aqueous solution to form an oligomer, which creates an ion-channel coating on the hair surface to protect it. This work attempts to develop fast, simple, and damage-free hair-dye ingredients based on pyrogallol and gallic acid. The morphology and elements of polyphenols coated on hair are characterized. The results reveal that the hair is dyed with the polyphenol-based dye reagent successfully. Moreover, the thickness of the dyed hair continuously rises ten times after dyeing. The tensile strength of the dyed hair is also measured, showing an upward and downward trend. These results reflect the fact that pyrogallol and gallic acid are considered to be the essential and functional polyphenols, and can build ion blocks on hair, which can create new multifunctional coating materials. |
first_indexed | 2024-03-11T08:30:18Z |
format | Article |
id | doaj.art-47c150cef26748d58e79d45468f0ac2a |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-11T08:30:18Z |
publishDate | 2023-02-01 |
publisher | MDPI AG |
record_format | Article |
series | Materials |
spelling | doaj.art-47c150cef26748d58e79d45468f0ac2a2023-11-16T21:48:22ZengMDPI AGMaterials1996-19442023-02-01164133310.3390/ma16041333Polyphenols Coordinated with Cu (II) in an Aqueous System Build Ion-Channel Coatings on Hair SurfacesLei Jin0Daemyoung Yun1Wei Zhang2Jinsung Lee3Hongchul Shin4Donghyuk Kim5Tae-Bong Kang6Hyung-Sik Won7Hohyoun Jang8Whangi Kim9Department of Applied Chemistry, Konkuk University, Chungju 27478, Republic of KoreaDepartment of Applied Chemistry, Konkuk University, Chungju 27478, Republic of KoreaDepartment of Applied Chemistry, Konkuk University, Chungju 27478, Republic of KoreaSuan Hyangjang Co., Ltd., Suan bd 204, Jungwon-gu, Seongnam 13204, Republic of KoreaSuan Hyangjang Co., Ltd., Suan bd 204, Jungwon-gu, Seongnam 13204, Republic of KoreaDepartment of Applied Life Sciences, Graduate School, BK21 Program, Konkuk University, Chungju 27478, Republic of KoreaDepartment of Biotechnology, College of Biomedical & Health Science, Konkuk University, Chungju 27487, Republic of KoreaDepartment of Biotechnology, College of Biomedical & Health Science, Konkuk University, Chungju 27487, Republic of KoreaDepartment of Applied Chemistry, Konkuk University, Chungju 27478, Republic of KoreaDepartment of Applied Chemistry, Konkuk University, Chungju 27478, Republic of KoreaRecently, developments in the field of cosmetics have led to a renewed interest in hair dyeing. However, damage to the hair during the dyeing process has increased hesitation in attempting hair dyeing. As a result, hair dyes with minimal side effects have been in constant demand, and are being developed. In this study, natural-extract polyphenols, pyrogallol, and gallic acid are coordinated by CuCl<sub>2</sub> in a NaCl aqueous solution to form an oligomer, which creates an ion-channel coating on the hair surface to protect it. This work attempts to develop fast, simple, and damage-free hair-dye ingredients based on pyrogallol and gallic acid. The morphology and elements of polyphenols coated on hair are characterized. The results reveal that the hair is dyed with the polyphenol-based dye reagent successfully. Moreover, the thickness of the dyed hair continuously rises ten times after dyeing. The tensile strength of the dyed hair is also measured, showing an upward and downward trend. These results reflect the fact that pyrogallol and gallic acid are considered to be the essential and functional polyphenols, and can build ion blocks on hair, which can create new multifunctional coating materials.https://www.mdpi.com/1996-1944/16/4/1333hair dyepyrogallolgallic acidion channelcoatingaqueous system |
spellingShingle | Lei Jin Daemyoung Yun Wei Zhang Jinsung Lee Hongchul Shin Donghyuk Kim Tae-Bong Kang Hyung-Sik Won Hohyoun Jang Whangi Kim Polyphenols Coordinated with Cu (II) in an Aqueous System Build Ion-Channel Coatings on Hair Surfaces Materials hair dye pyrogallol gallic acid ion channel coating aqueous system |
title | Polyphenols Coordinated with Cu (II) in an Aqueous System Build Ion-Channel Coatings on Hair Surfaces |
title_full | Polyphenols Coordinated with Cu (II) in an Aqueous System Build Ion-Channel Coatings on Hair Surfaces |
title_fullStr | Polyphenols Coordinated with Cu (II) in an Aqueous System Build Ion-Channel Coatings on Hair Surfaces |
title_full_unstemmed | Polyphenols Coordinated with Cu (II) in an Aqueous System Build Ion-Channel Coatings on Hair Surfaces |
title_short | Polyphenols Coordinated with Cu (II) in an Aqueous System Build Ion-Channel Coatings on Hair Surfaces |
title_sort | polyphenols coordinated with cu ii in an aqueous system build ion channel coatings on hair surfaces |
topic | hair dye pyrogallol gallic acid ion channel coating aqueous system |
url | https://www.mdpi.com/1996-1944/16/4/1333 |
work_keys_str_mv | AT leijin polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT daemyoungyun polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT weizhang polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT jinsunglee polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT hongchulshin polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT donghyukkim polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT taebongkang polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT hyungsikwon polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT hohyounjang polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces AT whangikim polyphenolscoordinatedwithcuiiinanaqueoussystembuildionchannelcoatingsonhairsurfaces |