Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications
Articulated structures of naphthalene-based donor (D)-acceptor (A) type dipolar dye and aggregation-induced emission luminogen (AIEgen) based on tetraphenylethylene (TPE) were synthesized, and their photophysical properties were analyzed for the first time. There are many fluorophore backbones, whic...
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2020-04-01
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author | Na Hee Kim Byeong Wook Kim Youngseo Kim Junho K. Hur Junyang Jung Yohan Oh Sungnam Park B. Moon Kim Dokyoung Kim |
author_facet | Na Hee Kim Byeong Wook Kim Youngseo Kim Junho K. Hur Junyang Jung Yohan Oh Sungnam Park B. Moon Kim Dokyoung Kim |
author_sort | Na Hee Kim |
collection | DOAJ |
description | Articulated structures of naphthalene-based donor (D)-acceptor (A) type dipolar dye and aggregation-induced emission luminogen (AIEgen) based on tetraphenylethylene (TPE) were synthesized, and their photophysical properties were analyzed for the first time. There are many fluorophore backbones, which have dipolar structure and AIEgen. However, there has been neither property analysis nor research that closely articulates DA and AIE through non-conjugation linker. We have therefore prepared two representative fluorophores; DA-AIE series (DA-AIE-M and DA-AIE-D), and characterized their UV/vis absorption and emission properties with quantum chemical calculations. In addition, we utilized the unique photophysical properties of DA-AIE-D for monitoring a trace of dimethyl sulfoxide (DMSO) in aqueous media, including real water samples. |
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id | doaj.art-47e45a13ea424855b4577918994c8861 |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-10T20:21:08Z |
publishDate | 2020-04-01 |
publisher | MDPI AG |
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series | Materials |
spelling | doaj.art-47e45a13ea424855b4577918994c88612023-11-19T22:09:59ZengMDPI AGMaterials1996-19442020-04-01138193910.3390/ma13081939Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and ApplicationsNa Hee Kim0Byeong Wook Kim1Youngseo Kim2Junho K. Hur3Junyang Jung4Yohan Oh5Sungnam Park6B. Moon Kim7Dokyoung Kim8Department of Biomedical Science, Graduate School, Kyung Hee University, Seoul 02447, KoreaDepartment of Chemistry, College of Natural Sciences, Seoul National University, Seoul 08826, KoreaDepartment of Chemistry, Korea University, Seoul 02841, KoreaDepartment of Biomedical Science, Graduate School, Kyung Hee University, Seoul 02447, KoreaDepartment of Biomedical Science, Graduate School, Kyung Hee University, Seoul 02447, KoreaDepartment of Biomedical Science, Graduate School of Biomedical Science and Engineering, Hanyang University, Seoul 04763, KoreaDepartment of Chemistry, Korea University, Seoul 02841, KoreaDepartment of Chemistry, College of Natural Sciences, Seoul National University, Seoul 08826, KoreaDepartment of Biomedical Science, Graduate School, Kyung Hee University, Seoul 02447, KoreaArticulated structures of naphthalene-based donor (D)-acceptor (A) type dipolar dye and aggregation-induced emission luminogen (AIEgen) based on tetraphenylethylene (TPE) were synthesized, and their photophysical properties were analyzed for the first time. There are many fluorophore backbones, which have dipolar structure and AIEgen. However, there has been neither property analysis nor research that closely articulates DA and AIE through non-conjugation linker. We have therefore prepared two representative fluorophores; DA-AIE series (DA-AIE-M and DA-AIE-D), and characterized their UV/vis absorption and emission properties with quantum chemical calculations. In addition, we utilized the unique photophysical properties of DA-AIE-D for monitoring a trace of dimethyl sulfoxide (DMSO) in aqueous media, including real water samples.https://www.mdpi.com/1996-1944/13/8/1939fluorophoredipolar dyefunctionalized naphthaleneaggregation-induced emissionDMSO sensing |
spellingShingle | Na Hee Kim Byeong Wook Kim Youngseo Kim Junho K. Hur Junyang Jung Yohan Oh Sungnam Park B. Moon Kim Dokyoung Kim Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications Materials fluorophore dipolar dye functionalized naphthalene aggregation-induced emission DMSO sensing |
title | Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications |
title_full | Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications |
title_fullStr | Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications |
title_full_unstemmed | Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications |
title_short | Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications |
title_sort | articulated structures of d a type dipolar dye with aiegen synthesis photophysical properties and applications |
topic | fluorophore dipolar dye functionalized naphthalene aggregation-induced emission DMSO sensing |
url | https://www.mdpi.com/1996-1944/13/8/1939 |
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