Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications

Articulated structures of naphthalene-based donor (D)-acceptor (A) type dipolar dye and aggregation-induced emission luminogen (AIEgen) based on tetraphenylethylene (TPE) were synthesized, and their photophysical properties were analyzed for the first time. There are many fluorophore backbones, whic...

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Main Authors: Na Hee Kim, Byeong Wook Kim, Youngseo Kim, Junho K. Hur, Junyang Jung, Yohan Oh, Sungnam Park, B. Moon Kim, Dokyoung Kim
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/8/1939
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author Na Hee Kim
Byeong Wook Kim
Youngseo Kim
Junho K. Hur
Junyang Jung
Yohan Oh
Sungnam Park
B. Moon Kim
Dokyoung Kim
author_facet Na Hee Kim
Byeong Wook Kim
Youngseo Kim
Junho K. Hur
Junyang Jung
Yohan Oh
Sungnam Park
B. Moon Kim
Dokyoung Kim
author_sort Na Hee Kim
collection DOAJ
description Articulated structures of naphthalene-based donor (D)-acceptor (A) type dipolar dye and aggregation-induced emission luminogen (AIEgen) based on tetraphenylethylene (TPE) were synthesized, and their photophysical properties were analyzed for the first time. There are many fluorophore backbones, which have dipolar structure and AIEgen. However, there has been neither property analysis nor research that closely articulates DA and AIE through non-conjugation linker. We have therefore prepared two representative fluorophores; DA-AIE series (DA-AIE-M and DA-AIE-D), and characterized their UV/vis absorption and emission properties with quantum chemical calculations. In addition, we utilized the unique photophysical properties of DA-AIE-D for monitoring a trace of dimethyl sulfoxide (DMSO) in aqueous media, including real water samples.
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spelling doaj.art-47e45a13ea424855b4577918994c88612023-11-19T22:09:59ZengMDPI AGMaterials1996-19442020-04-01138193910.3390/ma13081939Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and ApplicationsNa Hee Kim0Byeong Wook Kim1Youngseo Kim2Junho K. Hur3Junyang Jung4Yohan Oh5Sungnam Park6B. Moon Kim7Dokyoung Kim8Department of Biomedical Science, Graduate School, Kyung Hee University, Seoul 02447, KoreaDepartment of Chemistry, College of Natural Sciences, Seoul National University, Seoul 08826, KoreaDepartment of Chemistry, Korea University, Seoul 02841, KoreaDepartment of Biomedical Science, Graduate School, Kyung Hee University, Seoul 02447, KoreaDepartment of Biomedical Science, Graduate School, Kyung Hee University, Seoul 02447, KoreaDepartment of Biomedical Science, Graduate School of Biomedical Science and Engineering, Hanyang University, Seoul 04763, KoreaDepartment of Chemistry, Korea University, Seoul 02841, KoreaDepartment of Chemistry, College of Natural Sciences, Seoul National University, Seoul 08826, KoreaDepartment of Biomedical Science, Graduate School, Kyung Hee University, Seoul 02447, KoreaArticulated structures of naphthalene-based donor (D)-acceptor (A) type dipolar dye and aggregation-induced emission luminogen (AIEgen) based on tetraphenylethylene (TPE) were synthesized, and their photophysical properties were analyzed for the first time. There are many fluorophore backbones, which have dipolar structure and AIEgen. However, there has been neither property analysis nor research that closely articulates DA and AIE through non-conjugation linker. We have therefore prepared two representative fluorophores; DA-AIE series (DA-AIE-M and DA-AIE-D), and characterized their UV/vis absorption and emission properties with quantum chemical calculations. In addition, we utilized the unique photophysical properties of DA-AIE-D for monitoring a trace of dimethyl sulfoxide (DMSO) in aqueous media, including real water samples.https://www.mdpi.com/1996-1944/13/8/1939fluorophoredipolar dyefunctionalized naphthaleneaggregation-induced emissionDMSO sensing
spellingShingle Na Hee Kim
Byeong Wook Kim
Youngseo Kim
Junho K. Hur
Junyang Jung
Yohan Oh
Sungnam Park
B. Moon Kim
Dokyoung Kim
Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications
Materials
fluorophore
dipolar dye
functionalized naphthalene
aggregation-induced emission
DMSO sensing
title Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications
title_full Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications
title_fullStr Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications
title_full_unstemmed Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications
title_short Articulated Structures of D-A Type Dipolar Dye with AIEgen: Synthesis, Photophysical Properties, and Applications
title_sort articulated structures of d a type dipolar dye with aiegen synthesis photophysical properties and applications
topic fluorophore
dipolar dye
functionalized naphthalene
aggregation-induced emission
DMSO sensing
url https://www.mdpi.com/1996-1944/13/8/1939
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