Cocoon-shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kinetics
Rational design of hollow mesoporous silicas with distinctive morphology has attracted considerable interest for their promising applications of different functions. Herein, we reported hollow mesoporous silica ellipsoids with quasiperiodic cocoon-shape, and fully investigated the evolution of exter...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Taylor & Francis Group
2023-02-01
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| Series: | Materials Research Letters |
| Subjects: | |
| Online Access: | https://www.tandfonline.com/doi/10.1080/21663831.2022.2126736 |
| _version_ | 1828096124967190528 |
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| author | Yage Li Congyang Ma Tianjia Yu Qiang Cai |
| author_facet | Yage Li Congyang Ma Tianjia Yu Qiang Cai |
| author_sort | Yage Li |
| collection | DOAJ |
| description | Rational design of hollow mesoporous silicas with distinctive morphology has attracted considerable interest for their promising applications of different functions. Herein, we reported hollow mesoporous silica ellipsoids with quasiperiodic cocoon-shape, and fully investigated the evolution of external morphology and interior structure with solution concentrations. However, synthetic theories used so far hardly provide reasonable explanation. Therefore, a morphogenetic mechanism upon interfacial destabilization dynamics is proposed based on the experimental results, in which unstable interfaces of emulsions influenced by harmonic perturbations are employed as secondary templates for the nonequilibrium deposition/diffusion of rod-like micelles, explaining well the controllability of the morphology. |
| first_indexed | 2024-04-11T07:24:10Z |
| format | Article |
| id | doaj.art-47ea5e6c4bba4938b8d576c8796bcf30 |
| institution | Directory Open Access Journal |
| issn | 2166-3831 |
| language | English |
| last_indexed | 2024-04-11T07:24:10Z |
| publishDate | 2023-02-01 |
| publisher | Taylor & Francis Group |
| record_format | Article |
| series | Materials Research Letters |
| spelling | doaj.art-47ea5e6c4bba4938b8d576c8796bcf302022-12-22T04:37:07ZengTaylor & Francis GroupMaterials Research Letters2166-38312023-02-0111211712510.1080/21663831.2022.2126736Cocoon-shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kineticsYage Li0Congyang Ma1Tianjia Yu2Qiang Cai3Key Laboratory of Advanced Materials of Ministry of Education of China, School of Materials Science and Engineering, Tsinghua University, Beijing, People’s Republic of ChinaKey Laboratory of Advanced Materials of Ministry of Education of China, School of Materials Science and Engineering, Tsinghua University, Beijing, People’s Republic of ChinaKey Laboratory of Advanced Materials of Ministry of Education of China, School of Materials Science and Engineering, Tsinghua University, Beijing, People’s Republic of ChinaKey Laboratory of Advanced Materials of Ministry of Education of China, School of Materials Science and Engineering, Tsinghua University, Beijing, People’s Republic of ChinaRational design of hollow mesoporous silicas with distinctive morphology has attracted considerable interest for their promising applications of different functions. Herein, we reported hollow mesoporous silica ellipsoids with quasiperiodic cocoon-shape, and fully investigated the evolution of external morphology and interior structure with solution concentrations. However, synthetic theories used so far hardly provide reasonable explanation. Therefore, a morphogenetic mechanism upon interfacial destabilization dynamics is proposed based on the experimental results, in which unstable interfaces of emulsions influenced by harmonic perturbations are employed as secondary templates for the nonequilibrium deposition/diffusion of rod-like micelles, explaining well the controllability of the morphology.https://www.tandfonline.com/doi/10.1080/21663831.2022.2126736Hollow mesoporous silicasquasiperiodic shellinterfacial stabilitysecondary-templating strategymorphogenetic mechanism |
| spellingShingle | Yage Li Congyang Ma Tianjia Yu Qiang Cai Cocoon-shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kinetics Materials Research Letters Hollow mesoporous silicas quasiperiodic shell interfacial stability secondary-templating strategy morphogenetic mechanism |
| title | Cocoon-shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kinetics |
| title_full | Cocoon-shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kinetics |
| title_fullStr | Cocoon-shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kinetics |
| title_full_unstemmed | Cocoon-shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kinetics |
| title_short | Cocoon-shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kinetics |
| title_sort | cocoon shaped hollow mesoporous silica ellipsoids controlled by interfacial destabilization growth kinetics |
| topic | Hollow mesoporous silicas quasiperiodic shell interfacial stability secondary-templating strategy morphogenetic mechanism |
| url | https://www.tandfonline.com/doi/10.1080/21663831.2022.2126736 |
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