Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis Method
This research was conducted to develop a green synthesis method for zero valent iron (ZVI) preparation. The ZVI was synthesized by reacting FeCl2 with polyphenols extracted from kepok banana peels. This polyphenol extraction process was carried out using three different solvents, namely: water, chlo...
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| Format: | Article |
| Language: | English |
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The Center for Science Innovation
2022-06-01
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| Series: | Chemistry and Materials |
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| Online Access: | https://piscience.org/index.php/cma/article/view/24 |
| _version_ | 1827898537076064256 |
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| author | Devi Indrawati Syafei Sahid Hidayat Yusmaniar |
| author_facet | Devi Indrawati Syafei Sahid Hidayat Yusmaniar |
| author_sort | Devi Indrawati Syafei |
| collection | DOAJ |
| description | This research was conducted to develop a green synthesis method for zero valent iron (ZVI) preparation. The ZVI was synthesized by reacting FeCl2 with polyphenols extracted from kepok banana peels. This polyphenol extraction process was carried out using three different solvents, namely: water, chloroform, and ethyl acetate. Gas chromatography mass spectroscopy test showed three main phenolic compounds contained in the banana peel extract, namely: 2-methoxy-4-vinylphenol, 4-methoxy-2-vinylphenol, and 2-methoxy-5-vinylphenol. The optimum composition of FeCl2 and polyphenol was 3:2. Fourier transform infra red spectroscopy data confirmed that the synthesized ZVI contains organic compounds having –OH and C=O groups which are assumed to be capping agents that can maintain stability. This has also been supported by the results of the energy dispersive X-ray analysis where there are carbon atoms (C) and oxygen atoms (O) in ZVI. The ZVI particle size was uneven and form a compact solid. The largest particle size distribution of ZVI is in the range of 234.49 nm - 407.49 nm with the average size of ZVI beings 616.26 nm. The results of the XRD analysis have also confirmed the formation of a simple cubic ZVI with fine crystallite size of ca 26.64 nm. |
| first_indexed | 2024-03-12T23:05:33Z |
| format | Article |
| id | doaj.art-47f22986a98647a9bd3654cbfb9ce1b0 |
| institution | Directory Open Access Journal |
| issn | 2828-271X 2828-2310 |
| language | English |
| last_indexed | 2024-03-12T23:05:33Z |
| publishDate | 2022-06-01 |
| publisher | The Center for Science Innovation |
| record_format | Article |
| series | Chemistry and Materials |
| spelling | doaj.art-47f22986a98647a9bd3654cbfb9ce1b02023-07-19T02:26:46ZengThe Center for Science InnovationChemistry and Materials2828-271X2828-23102022-06-0112454910.56425/cma.v1i2.2424Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis MethodDevi Indrawati Syafei0Sahid HidayatYusmaniarThe Center for Science InnovationThis research was conducted to develop a green synthesis method for zero valent iron (ZVI) preparation. The ZVI was synthesized by reacting FeCl2 with polyphenols extracted from kepok banana peels. This polyphenol extraction process was carried out using three different solvents, namely: water, chloroform, and ethyl acetate. Gas chromatography mass spectroscopy test showed three main phenolic compounds contained in the banana peel extract, namely: 2-methoxy-4-vinylphenol, 4-methoxy-2-vinylphenol, and 2-methoxy-5-vinylphenol. The optimum composition of FeCl2 and polyphenol was 3:2. Fourier transform infra red spectroscopy data confirmed that the synthesized ZVI contains organic compounds having –OH and C=O groups which are assumed to be capping agents that can maintain stability. This has also been supported by the results of the energy dispersive X-ray analysis where there are carbon atoms (C) and oxygen atoms (O) in ZVI. The ZVI particle size was uneven and form a compact solid. The largest particle size distribution of ZVI is in the range of 234.49 nm - 407.49 nm with the average size of ZVI beings 616.26 nm. The results of the XRD analysis have also confirmed the formation of a simple cubic ZVI with fine crystallite size of ca 26.64 nm.https://piscience.org/index.php/cma/article/view/24polyphenolbanana peelextraction zero-valent iron |
| spellingShingle | Devi Indrawati Syafei Sahid Hidayat Yusmaniar Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis Method Chemistry and Materials polyphenol banana peel extraction zero-valent iron |
| title | Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis Method |
| title_full | Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis Method |
| title_fullStr | Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis Method |
| title_full_unstemmed | Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis Method |
| title_short | Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis Method |
| title_sort | synthesis and characterization of zero valent iron prepared using green synthesis method |
| topic | polyphenol banana peel extraction zero-valent iron |
| url | https://piscience.org/index.php/cma/article/view/24 |
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