2-({6-[5-Methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]imidazo[2,1-b]thiazol-5-yl}methylidene)hydrazinecarbothioamide dimethylformamide 0.25-solvate
The asymmetric unit of the title solvate, C17H16N8S2·0.25C3H7NO, consists of two C17H16N8S2 molecules and a dimethylformamide molecule disordered about a crystallographic inversion centre. Both triazole molecules feature an intramolecular C—H...N interaction, which generates an S(6) ring in each cas...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2018-01-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314618000871 |
| _version_ | 1819144469182676992 |
|---|---|
| author | Gamal A. El-Hiti Bakr F. Abdel-Wahab Mohammad Hayal Alotaibi Amany S. Hegazy Benson M. Kariuki |
| author_facet | Gamal A. El-Hiti Bakr F. Abdel-Wahab Mohammad Hayal Alotaibi Amany S. Hegazy Benson M. Kariuki |
| author_sort | Gamal A. El-Hiti |
| collection | DOAJ |
| description | The asymmetric unit of the title solvate, C17H16N8S2·0.25C3H7NO, consists of two C17H16N8S2 molecules and a dimethylformamide molecule disordered about a crystallographic inversion centre. Both triazole molecules feature an intramolecular C—H...N interaction, which generates an S(6) ring in each case. In the crystal, the components are linked by N—H...N and N—H...S hydrogen bonds to form [001] chains, which are cross-linked by weak C—H...O, C—H...N and C—H...S interactions. |
| first_indexed | 2024-12-22T12:42:38Z |
| format | Article |
| id | doaj.art-4815a43340884b969450e588bfd60f92 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-22T12:42:38Z |
| publishDate | 2018-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-4815a43340884b969450e588bfd60f922022-12-21T18:25:23ZengInternational Union of CrystallographyIUCrData2414-31462018-01-0131x18008710.1107/S2414314618000871hb42032-({6-[5-Methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]imidazo[2,1-b]thiazol-5-yl}methylidene)hydrazinecarbothioamide dimethylformamide 0.25-solvateGamal A. El-Hiti0Bakr F. Abdel-Wahab1Mohammad Hayal Alotaibi2Amany S. Hegazy3Benson M. Kariuki4Cornea Research Chair, Department of Optometry, College of Applied Medical Sciences, King Saud University, PO Box 10219, Riyadh 11433, Saudi ArabiaDepartment of Chemistry, College of Science and Humanities, Shaqra University, Duwadimi, Saudi ArabiaNational Center for Petrochemicals Technology, King Abdulaziz City for Science and Technology, PO Box 6086, Riyadh 11442, Saudi ArabiaSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UKSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UKThe asymmetric unit of the title solvate, C17H16N8S2·0.25C3H7NO, consists of two C17H16N8S2 molecules and a dimethylformamide molecule disordered about a crystallographic inversion centre. Both triazole molecules feature an intramolecular C—H...N interaction, which generates an S(6) ring in each case. In the crystal, the components are linked by N—H...N and N—H...S hydrogen bonds to form [001] chains, which are cross-linked by weak C—H...O, C—H...N and C—H...S interactions.http://scripts.iucr.org/cgi-bin/paper?S2414314618000871crystal structureheterocycletriazole |
| spellingShingle | Gamal A. El-Hiti Bakr F. Abdel-Wahab Mohammad Hayal Alotaibi Amany S. Hegazy Benson M. Kariuki 2-({6-[5-Methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]imidazo[2,1-b]thiazol-5-yl}methylidene)hydrazinecarbothioamide dimethylformamide 0.25-solvate IUCrData crystal structure heterocycle triazole |
| title | 2-({6-[5-Methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]imidazo[2,1-b]thiazol-5-yl}methylidene)hydrazinecarbothioamide dimethylformamide 0.25-solvate |
| title_full | 2-({6-[5-Methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]imidazo[2,1-b]thiazol-5-yl}methylidene)hydrazinecarbothioamide dimethylformamide 0.25-solvate |
| title_fullStr | 2-({6-[5-Methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]imidazo[2,1-b]thiazol-5-yl}methylidene)hydrazinecarbothioamide dimethylformamide 0.25-solvate |
| title_full_unstemmed | 2-({6-[5-Methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]imidazo[2,1-b]thiazol-5-yl}methylidene)hydrazinecarbothioamide dimethylformamide 0.25-solvate |
| title_short | 2-({6-[5-Methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]imidazo[2,1-b]thiazol-5-yl}methylidene)hydrazinecarbothioamide dimethylformamide 0.25-solvate |
| title_sort | 2 6 5 methyl 1 4 methylphenyl 1h 1 2 3 triazol 4 yl imidazo 2 1 b thiazol 5 yl methylidene hydrazinecarbothioamide dimethylformamide 0 25 solvate |
| topic | crystal structure heterocycle triazole |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314618000871 |
| work_keys_str_mv | AT gamalaelhiti 265methyl14methylphenyl1h123triazol4ylimidazo21bthiazol5ylmethylidenehydrazinecarbothioamidedimethylformamide025solvate AT bakrfabdelwahab 265methyl14methylphenyl1h123triazol4ylimidazo21bthiazol5ylmethylidenehydrazinecarbothioamidedimethylformamide025solvate AT mohammadhayalalotaibi 265methyl14methylphenyl1h123triazol4ylimidazo21bthiazol5ylmethylidenehydrazinecarbothioamidedimethylformamide025solvate AT amanyshegazy 265methyl14methylphenyl1h123triazol4ylimidazo21bthiazol5ylmethylidenehydrazinecarbothioamidedimethylformamide025solvate AT bensonmkariuki 265methyl14methylphenyl1h123triazol4ylimidazo21bthiazol5ylmethylidenehydrazinecarbothioamidedimethylformamide025solvate |