Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties
A set of five vitrimers with glass transition temperatures in the range of 80–90 °C were designed to assess the effect of the network structure and disulfide concentration on their dynamic and mechanical properties, and to find the best performing system overall compared to the commercial Araldite L...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-10-01
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| Series: | Polymers |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4360/15/20/4123 |
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| author | Itxaso Azcune Edurne Elorza Alaitz Ruiz de Luzuriaga Arrate Huegun Alaitz Rekondo Hans-Jürgen Grande |
| author_facet | Itxaso Azcune Edurne Elorza Alaitz Ruiz de Luzuriaga Arrate Huegun Alaitz Rekondo Hans-Jürgen Grande |
| author_sort | Itxaso Azcune |
| collection | DOAJ |
| description | A set of five vitrimers with glass transition temperatures in the range of 80–90 °C were designed to assess the effect of the network structure and disulfide concentration on their dynamic and mechanical properties, and to find the best performing system overall compared to the commercial Araldite LY1564/Aradur 3486 commercial thermoset system. Vitrimer networks were prepared by incorporating mono- and bifunctional epoxy reactive diluents and an amine chain extender into the Araldite LY1564/4-aminophenyldisulfide system. |
| first_indexed | 2024-03-10T20:56:30Z |
| format | Article |
| id | doaj.art-482d12269d09481e9d6ed1daee18af3e |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-10T20:56:30Z |
| publishDate | 2023-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-482d12269d09481e9d6ed1daee18af3e2023-11-19T17:51:32ZengMDPI AGPolymers2073-43602023-10-011520412310.3390/polym15204123Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer PropertiesItxaso Azcune0Edurne Elorza1Alaitz Ruiz de Luzuriaga2Arrate Huegun3Alaitz Rekondo4Hans-Jürgen Grande5CIDETEC, Basque Research and Technology Alliance (BRTA), Paseo Miramón 196, 20014 Donostia-San Sebastian, SpainCIDETEC, Basque Research and Technology Alliance (BRTA), Paseo Miramón 196, 20014 Donostia-San Sebastian, SpainCIDETEC, Basque Research and Technology Alliance (BRTA), Paseo Miramón 196, 20014 Donostia-San Sebastian, SpainCIDETEC, Basque Research and Technology Alliance (BRTA), Paseo Miramón 196, 20014 Donostia-San Sebastian, SpainCIDETEC, Basque Research and Technology Alliance (BRTA), Paseo Miramón 196, 20014 Donostia-San Sebastian, SpainCIDETEC, Basque Research and Technology Alliance (BRTA), Paseo Miramón 196, 20014 Donostia-San Sebastian, SpainA set of five vitrimers with glass transition temperatures in the range of 80–90 °C were designed to assess the effect of the network structure and disulfide concentration on their dynamic and mechanical properties, and to find the best performing system overall compared to the commercial Araldite LY1564/Aradur 3486 commercial thermoset system. Vitrimer networks were prepared by incorporating mono- and bifunctional epoxy reactive diluents and an amine chain extender into the Araldite LY1564/4-aminophenyldisulfide system.https://www.mdpi.com/2073-4360/15/20/4123vitrimersdisulfide exchangenetwork cross linking densitydisulfide concentration |
| spellingShingle | Itxaso Azcune Edurne Elorza Alaitz Ruiz de Luzuriaga Arrate Huegun Alaitz Rekondo Hans-Jürgen Grande Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties Polymers vitrimers disulfide exchange network cross linking density disulfide concentration |
| title | Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties |
| title_full | Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties |
| title_fullStr | Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties |
| title_full_unstemmed | Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties |
| title_short | Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties |
| title_sort | analysis of the effect of network structure and disulfide concentration on vitrimer properties |
| topic | vitrimers disulfide exchange network cross linking density disulfide concentration |
| url | https://www.mdpi.com/2073-4360/15/20/4123 |
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