Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation
In this research hydrogenation kinetic of alpha-methylstyrene (AMS) on Pd/Al2O3catalyst was studied. The reaction is mildly exothermic (ÄH=-109 kJ/mol). Intrinsickinetic law was investigated under wide range of operating conditions 0.1 and 0.2 gmcatalyst loading, 0.5-100 wt% AMS, 10, 15 and 20 bar p...
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Format: | Article |
Language: | English |
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Unviversity of Technology- Iraq
2009-05-01
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Series: | Engineering and Technology Journal |
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Online Access: | https://etj.uotechnology.edu.iq/article_35640_aed6c19cdb725e6932f777de5a6cac11.pdf |
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author | Zaidoon M. Shakoor Mumtaz A. Zablouk Adel A. Shuhaib |
author_facet | Zaidoon M. Shakoor Mumtaz A. Zablouk Adel A. Shuhaib |
author_sort | Zaidoon M. Shakoor |
collection | DOAJ |
description | In this research hydrogenation kinetic of alpha-methylstyrene (AMS) on Pd/Al2O3catalyst was studied. The reaction is mildly exothermic (ÄH=-109 kJ/mol). Intrinsickinetic law was investigated under wide range of operating conditions 0.1 and 0.2 gmcatalyst loading, 0.5-100 wt% AMS, 10, 15 and 20 bar pressure and 343-373 Ktemperature.The experiment data are fitted to estimate the kinetic parameters for different reactionmechanisms by using ACM (Aspen Custom Modeler) software. Finally the results ofproduced reaction mechanisms are compared with experimental results to obtain theoptimum reaction mechanism |
first_indexed | 2024-03-08T06:06:27Z |
format | Article |
id | doaj.art-483567ebfff74d598d335f7e148f74fe |
institution | Directory Open Access Journal |
issn | 1681-6900 2412-0758 |
language | English |
last_indexed | 2024-03-08T06:06:27Z |
publishDate | 2009-05-01 |
publisher | Unviversity of Technology- Iraq |
record_format | Article |
series | Engineering and Technology Journal |
spelling | doaj.art-483567ebfff74d598d335f7e148f74fe2024-02-04T17:49:20ZengUnviversity of Technology- IraqEngineering and Technology Journal1681-69002412-07582009-05-012771301131610.30684/etj.27.7.735640Reaction Kinetic ofá-methylstyrene (AMS) HydrogenationZaidoon M. ShakoorMumtaz A. ZabloukAdel A. ShuhaibIn this research hydrogenation kinetic of alpha-methylstyrene (AMS) on Pd/Al2O3catalyst was studied. The reaction is mildly exothermic (ÄH=-109 kJ/mol). Intrinsickinetic law was investigated under wide range of operating conditions 0.1 and 0.2 gmcatalyst loading, 0.5-100 wt% AMS, 10, 15 and 20 bar pressure and 343-373 Ktemperature.The experiment data are fitted to estimate the kinetic parameters for different reactionmechanisms by using ACM (Aspen Custom Modeler) software. Finally the results ofproduced reaction mechanisms are compared with experimental results to obtain theoptimum reaction mechanismhttps://etj.uotechnology.edu.iq/article_35640_aed6c19cdb725e6932f777de5a6cac11.pdfmethylstyrenehydrogenationmechanismcatalytic reaction |
spellingShingle | Zaidoon M. Shakoor Mumtaz A. Zablouk Adel A. Shuhaib Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation Engineering and Technology Journal methylstyrene hydrogenation mechanism catalytic reaction |
title | Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation |
title_full | Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation |
title_fullStr | Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation |
title_full_unstemmed | Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation |
title_short | Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation |
title_sort | reaction kinetic ofa methylstyrene ams hydrogenation |
topic | methylstyrene hydrogenation mechanism catalytic reaction |
url | https://etj.uotechnology.edu.iq/article_35640_aed6c19cdb725e6932f777de5a6cac11.pdf |
work_keys_str_mv | AT zaidoonmshakoor reactionkineticofamethylstyreneamshydrogenation AT mumtazazablouk reactionkineticofamethylstyreneamshydrogenation AT adelashuhaib reactionkineticofamethylstyreneamshydrogenation |