Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation

In this research hydrogenation kinetic of alpha-methylstyrene (AMS) on Pd/Al2O3catalyst was studied. The reaction is mildly exothermic (ÄH=-109 kJ/mol). Intrinsickinetic law was investigated under wide range of operating conditions 0.1 and 0.2 gmcatalyst loading, 0.5-100 wt% AMS, 10, 15 and 20 bar p...

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Main Authors: Zaidoon M. Shakoor, Mumtaz A. Zablouk, Adel A. Shuhaib
Format: Article
Language:English
Published: Unviversity of Technology- Iraq 2009-05-01
Series:Engineering and Technology Journal
Subjects:
Online Access:https://etj.uotechnology.edu.iq/article_35640_aed6c19cdb725e6932f777de5a6cac11.pdf
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author Zaidoon M. Shakoor
Mumtaz A. Zablouk
Adel A. Shuhaib
author_facet Zaidoon M. Shakoor
Mumtaz A. Zablouk
Adel A. Shuhaib
author_sort Zaidoon M. Shakoor
collection DOAJ
description In this research hydrogenation kinetic of alpha-methylstyrene (AMS) on Pd/Al2O3catalyst was studied. The reaction is mildly exothermic (ÄH=-109 kJ/mol). Intrinsickinetic law was investigated under wide range of operating conditions 0.1 and 0.2 gmcatalyst loading, 0.5-100 wt% AMS, 10, 15 and 20 bar pressure and 343-373 Ktemperature.The experiment data are fitted to estimate the kinetic parameters for different reactionmechanisms by using ACM (Aspen Custom Modeler) software. Finally the results ofproduced reaction mechanisms are compared with experimental results to obtain theoptimum reaction mechanism
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spelling doaj.art-483567ebfff74d598d335f7e148f74fe2024-02-04T17:49:20ZengUnviversity of Technology- IraqEngineering and Technology Journal1681-69002412-07582009-05-012771301131610.30684/etj.27.7.735640Reaction Kinetic ofá-methylstyrene (AMS) HydrogenationZaidoon M. ShakoorMumtaz A. ZabloukAdel A. ShuhaibIn this research hydrogenation kinetic of alpha-methylstyrene (AMS) on Pd/Al2O3catalyst was studied. The reaction is mildly exothermic (ÄH=-109 kJ/mol). Intrinsickinetic law was investigated under wide range of operating conditions 0.1 and 0.2 gmcatalyst loading, 0.5-100 wt% AMS, 10, 15 and 20 bar pressure and 343-373 Ktemperature.The experiment data are fitted to estimate the kinetic parameters for different reactionmechanisms by using ACM (Aspen Custom Modeler) software. Finally the results ofproduced reaction mechanisms are compared with experimental results to obtain theoptimum reaction mechanismhttps://etj.uotechnology.edu.iq/article_35640_aed6c19cdb725e6932f777de5a6cac11.pdfmethylstyrenehydrogenationmechanismcatalytic reaction
spellingShingle Zaidoon M. Shakoor
Mumtaz A. Zablouk
Adel A. Shuhaib
Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation
Engineering and Technology Journal
methylstyrene
hydrogenation
mechanism
catalytic reaction
title Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation
title_full Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation
title_fullStr Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation
title_full_unstemmed Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation
title_short Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation
title_sort reaction kinetic ofa methylstyrene ams hydrogenation
topic methylstyrene
hydrogenation
mechanism
catalytic reaction
url https://etj.uotechnology.edu.iq/article_35640_aed6c19cdb725e6932f777de5a6cac11.pdf
work_keys_str_mv AT zaidoonmshakoor reactionkineticofamethylstyreneamshydrogenation
AT mumtazazablouk reactionkineticofamethylstyreneamshydrogenation
AT adelashuhaib reactionkineticofamethylstyreneamshydrogenation