Nanomaterial accumulation in boiling brines enhances epithermal bonanzas

Abstract Epithermal bonanza-type ores, characterized by weight-percent contents of e.g., gold and silver in a few mm to cm, are generated by mixtures of magmatic-derived hydrothermal brines and external fluids (e.g., meteoric) that transport a variety of metals to the site of deposition. However, th...

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Main Authors: Néstor Cano, José M. González-Jiménez, Antoni Camprubí, Diego Domínguez-Carretero, Eduardo González-Partida, Joaquín A. Proenza
Format: Article
Language:English
Published: Nature Portfolio 2023-09-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-023-41756-4
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author Néstor Cano
José M. González-Jiménez
Antoni Camprubí
Diego Domínguez-Carretero
Eduardo González-Partida
Joaquín A. Proenza
author_facet Néstor Cano
José M. González-Jiménez
Antoni Camprubí
Diego Domínguez-Carretero
Eduardo González-Partida
Joaquín A. Proenza
author_sort Néstor Cano
collection DOAJ
description Abstract Epithermal bonanza-type ores, characterized by weight-percent contents of e.g., gold and silver in a few mm to cm, are generated by mixtures of magmatic-derived hydrothermal brines and external fluids (e.g., meteoric) that transport a variety of metals to the site of deposition. However, the low solubilities of precious metals in hydrothermal fluids cannot justify the high concentrations necessary to produce such type of hyper-enriched metal ore. Here we show that boiling metal-bearing brines can produce, aggregate, and accumulate metal nanomaterials, ultimately leading to focused gold + silver ± copper over-enrichments. We found direct nano-scale evidence of nanoparticulate gold- and/or silver-bearing ores formed via nonclassical growth (i.e., nanomaterial attachment) during boiling in an intermediate-sulfidation epithermal bonanza. The documented processes may explain the generation of bonanzas in metal-rich brines from a range of mineral deposit types.
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spelling doaj.art-4838075d56e7487a99cdc0dde21dcc422023-11-20T09:27:13ZengNature PortfolioScientific Reports2045-23222023-09-011311710.1038/s41598-023-41756-4Nanomaterial accumulation in boiling brines enhances epithermal bonanzasNéstor Cano0José M. González-Jiménez1Antoni Camprubí2Diego Domínguez-Carretero3Eduardo González-Partida4Joaquín A. Proenza5Programa de Posgrado en Ciencias de la Tierra, Universidad Nacional Autónoma de México (UNAM). Ciudad UniversitariaInstituto Andaluz de Ciencias de la Tierra, CSIC-Universidad de GranadaInstituto de Geología, UNAM. Ciudad UniversitariaDepartament de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de BarcelonaCentro de Geociencias, UNAMDepartament de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de BarcelonaAbstract Epithermal bonanza-type ores, characterized by weight-percent contents of e.g., gold and silver in a few mm to cm, are generated by mixtures of magmatic-derived hydrothermal brines and external fluids (e.g., meteoric) that transport a variety of metals to the site of deposition. However, the low solubilities of precious metals in hydrothermal fluids cannot justify the high concentrations necessary to produce such type of hyper-enriched metal ore. Here we show that boiling metal-bearing brines can produce, aggregate, and accumulate metal nanomaterials, ultimately leading to focused gold + silver ± copper over-enrichments. We found direct nano-scale evidence of nanoparticulate gold- and/or silver-bearing ores formed via nonclassical growth (i.e., nanomaterial attachment) during boiling in an intermediate-sulfidation epithermal bonanza. The documented processes may explain the generation of bonanzas in metal-rich brines from a range of mineral deposit types.https://doi.org/10.1038/s41598-023-41756-4
spellingShingle Néstor Cano
José M. González-Jiménez
Antoni Camprubí
Diego Domínguez-Carretero
Eduardo González-Partida
Joaquín A. Proenza
Nanomaterial accumulation in boiling brines enhances epithermal bonanzas
Scientific Reports
title Nanomaterial accumulation in boiling brines enhances epithermal bonanzas
title_full Nanomaterial accumulation in boiling brines enhances epithermal bonanzas
title_fullStr Nanomaterial accumulation in boiling brines enhances epithermal bonanzas
title_full_unstemmed Nanomaterial accumulation in boiling brines enhances epithermal bonanzas
title_short Nanomaterial accumulation in boiling brines enhances epithermal bonanzas
title_sort nanomaterial accumulation in boiling brines enhances epithermal bonanzas
url https://doi.org/10.1038/s41598-023-41756-4
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