Studies of the Application of Electrically Conductive Composite Copper Films to Cotton Fabrics
This paper presents a technology for applying copper and silver films to cotton fabrics by combining photochemical and chemical methods for the reduction of the compounds of these metals. The resulting metal-containing films have inherent electrical conductivity of metals. All the main processes des...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-11-01
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| Series: | Journal of Composites Science |
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| Online Access: | https://www.mdpi.com/2504-477X/6/11/349 |
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| author | Ramshad Abzhalov Malik Sataev Shaizada Koshkarbayeva Guzaliya Sagitova Bakyt Smailov Abdugani Azimov Bagdagul Serikbaeva Olga Kolesnikova Roman Fediuk Mugahed Amran |
| author_facet | Ramshad Abzhalov Malik Sataev Shaizada Koshkarbayeva Guzaliya Sagitova Bakyt Smailov Abdugani Azimov Bagdagul Serikbaeva Olga Kolesnikova Roman Fediuk Mugahed Amran |
| author_sort | Ramshad Abzhalov |
| collection | DOAJ |
| description | This paper presents a technology for applying copper and silver films to cotton fabrics by combining photochemical and chemical methods for the reduction of the compounds of these metals. The resulting metal-containing films have inherent electrical conductivity of metals. All the main processes described in the work were carried out by means of the compounds being sorbed by the surface of the fabric when they were wetted in appropriate solutions. The aim of the work was to study the application of electrically conductive composite copper films on cotton fabrics. The tasks to achieve this aim were to perform scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction analysis to confirm that as a result of the experiment, CuCl with a semiconductor ability was formed on the surface of the sample. The driving force behind the photochemical reduction of copper and silver halides on cotton surfaces is that, as a result of the photooxidation of cellulose molecules in the fabric, copper monochloride is first formed on the cotton surface. Subsequently, the process of obtaining silver particles based on semiconductor silver chloride obtained as a result of the transformation of copper monochloride was carried out. The physicochemical and photochemical processes leading to the formation of monovalent copper chloride, which provides sufficient adhesion to the substrate, are considered. It is shown that in this case, the oxidation of monovalent copper also occurs with the formation of soluble salts that are easily removed by washing. Since the proposed technology does not require special equipment, and the chemical reagents used are not scarce, it can be used to apply bactericidal silver films to various household items and medical applications in ordinary laundries or at home. This article examines an affordable and simple technology for producing metal films on a cotton surface due to the presence of disadvantages (time duration, high temperature, scarce reagents, special installations, etc.) of a number of well-known methods in the production of chemical coatings. |
| first_indexed | 2024-03-09T18:14:34Z |
| format | Article |
| id | doaj.art-486492d981c04aeb97eb27b0baa5f35f |
| institution | Directory Open Access Journal |
| issn | 2504-477X |
| language | English |
| last_indexed | 2024-03-09T18:14:34Z |
| publishDate | 2022-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Journal of Composites Science |
| spelling | doaj.art-486492d981c04aeb97eb27b0baa5f35f2023-11-24T08:51:40ZengMDPI AGJournal of Composites Science2504-477X2022-11-0161134910.3390/jcs6110349Studies of the Application of Electrically Conductive Composite Copper Films to Cotton FabricsRamshad Abzhalov0Malik Sataev1Shaizada Koshkarbayeva2Guzaliya Sagitova3Bakyt Smailov4Abdugani Azimov5Bagdagul Serikbaeva6Olga Kolesnikova7Roman Fediuk8Mugahed Amran9Department of “Chemical Technology of Inorganic Substance” M. Auezov, South Kazakhstan University, Shymkent 160012, KazakhstanDepartment of “Chemical Technology of Inorganic Substance” M. Auezov, South Kazakhstan University, Shymkent 160012, KazakhstanDepartment of “Chemical Technology of Inorganic Substance” M. Auezov, South Kazakhstan University, Shymkent 160012, KazakhstanDepartment of “Oil Refining and Petrochemistry” M. Auezov, South Kazakhstan University, Shymkent 160012, KazakhstanDepartment of “Standardization and Certification” M. Auezov, South Kazakhstan University, Shymkent 160012, KazakhstanDepartment of “Standardization and Certification” M. Auezov, South Kazakhstan University, Shymkent 160012, KazakhstanDepartment of “Chemical Technology of Inorganic Substance” M. Auezov, South Kazakhstan University, Shymkent 160012, KazakhstanDepartment of Science, Production and Innovation M. Auezov, South Kazakhstan University, Shymkent 160012, KazakhstanPolytechnic Institute, Far Eastern Federal University, Vladivostok 690922, RussiaDepartment of Civil Engineering, College of Engineering, Prince Sattam Bin Abdulaziz University, Alkharj 16273, Saudi ArabiaThis paper presents a technology for applying copper and silver films to cotton fabrics by combining photochemical and chemical methods for the reduction of the compounds of these metals. The resulting metal-containing films have inherent electrical conductivity of metals. All the main processes described in the work were carried out by means of the compounds being sorbed by the surface of the fabric when they were wetted in appropriate solutions. The aim of the work was to study the application of electrically conductive composite copper films on cotton fabrics. The tasks to achieve this aim were to perform scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction analysis to confirm that as a result of the experiment, CuCl with a semiconductor ability was formed on the surface of the sample. The driving force behind the photochemical reduction of copper and silver halides on cotton surfaces is that, as a result of the photooxidation of cellulose molecules in the fabric, copper monochloride is first formed on the cotton surface. Subsequently, the process of obtaining silver particles based on semiconductor silver chloride obtained as a result of the transformation of copper monochloride was carried out. The physicochemical and photochemical processes leading to the formation of monovalent copper chloride, which provides sufficient adhesion to the substrate, are considered. It is shown that in this case, the oxidation of monovalent copper also occurs with the formation of soluble salts that are easily removed by washing. Since the proposed technology does not require special equipment, and the chemical reagents used are not scarce, it can be used to apply bactericidal silver films to various household items and medical applications in ordinary laundries or at home. This article examines an affordable and simple technology for producing metal films on a cotton surface due to the presence of disadvantages (time duration, high temperature, scarce reagents, special installations, etc.) of a number of well-known methods in the production of chemical coatings.https://www.mdpi.com/2504-477X/6/11/349cotton fabricphotochemical reductioncompositecopper monochloridecoppersilver |
| spellingShingle | Ramshad Abzhalov Malik Sataev Shaizada Koshkarbayeva Guzaliya Sagitova Bakyt Smailov Abdugani Azimov Bagdagul Serikbaeva Olga Kolesnikova Roman Fediuk Mugahed Amran Studies of the Application of Electrically Conductive Composite Copper Films to Cotton Fabrics Journal of Composites Science cotton fabric photochemical reduction composite copper monochloride copper silver |
| title | Studies of the Application of Electrically Conductive Composite Copper Films to Cotton Fabrics |
| title_full | Studies of the Application of Electrically Conductive Composite Copper Films to Cotton Fabrics |
| title_fullStr | Studies of the Application of Electrically Conductive Composite Copper Films to Cotton Fabrics |
| title_full_unstemmed | Studies of the Application of Electrically Conductive Composite Copper Films to Cotton Fabrics |
| title_short | Studies of the Application of Electrically Conductive Composite Copper Films to Cotton Fabrics |
| title_sort | studies of the application of electrically conductive composite copper films to cotton fabrics |
| topic | cotton fabric photochemical reduction composite copper monochloride copper silver |
| url | https://www.mdpi.com/2504-477X/6/11/349 |
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