Preliminary Study on Desorption of Gold Ions on Self- Flocculating Microalga and its Regeneration Potential

Microalga, possessing high binding affinity to different metals, has been considered as a promising biosorbent. Precious metals recovery and adsorbent regeneration are important for the financial competitiveness of biosorption with other processes. In this study, the desorbing agent thiourea was stu...

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Main Authors: N. Shen, E. Chirwa
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2018-06-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/3047
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author N. Shen
E. Chirwa
author_facet N. Shen
E. Chirwa
author_sort N. Shen
collection DOAJ
description Microalga, possessing high binding affinity to different metals, has been considered as a promising biosorbent. Precious metals recovery and adsorbent regeneration are important for the financial competitiveness of biosorption with other processes. In this study, the desorbing agent thiourea was studied at different concentrations, contact time, pH and temperatures to optimize gold elution from the self-flocculating microalgae Scenedesmus obliquus AS-6-1. The variation in desorption performance with the adsorption time was also investigated. The gold-loaded biomass of S. obliquus AS-6-1 was regenerated efficiently by 0.2 M ofthiourea at 25 ? and pH of 1.0 within 15 minutes. The adsorption time had significant effect on subsequentdesorption, with a decrease in desorption efficiency with an increase in adsorption time. S. obliquus AS-6-1 asbiosorbent remained efficient biosorption and desorption potential for gold(III) recovery in the first two adsorption/desorption cycles. The microalga cells could be harvested/separated from solutions by their gravity sedimentation. However, more studies are still required to enhance the regeneration of S. obliquus AS-6-1 by improving its flocculating property.
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spelling doaj.art-4870684b8cd145369bcc2da89236e9fb2022-12-21T21:58:03ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162018-06-016510.3303/CET1865139Preliminary Study on Desorption of Gold Ions on Self- Flocculating Microalga and its Regeneration PotentialN. ShenE. ChirwaMicroalga, possessing high binding affinity to different metals, has been considered as a promising biosorbent. Precious metals recovery and adsorbent regeneration are important for the financial competitiveness of biosorption with other processes. In this study, the desorbing agent thiourea was studied at different concentrations, contact time, pH and temperatures to optimize gold elution from the self-flocculating microalgae Scenedesmus obliquus AS-6-1. The variation in desorption performance with the adsorption time was also investigated. The gold-loaded biomass of S. obliquus AS-6-1 was regenerated efficiently by 0.2 M ofthiourea at 25 ? and pH of 1.0 within 15 minutes. The adsorption time had significant effect on subsequentdesorption, with a decrease in desorption efficiency with an increase in adsorption time. S. obliquus AS-6-1 asbiosorbent remained efficient biosorption and desorption potential for gold(III) recovery in the first two adsorption/desorption cycles. The microalga cells could be harvested/separated from solutions by their gravity sedimentation. However, more studies are still required to enhance the regeneration of S. obliquus AS-6-1 by improving its flocculating property.https://www.cetjournal.it/index.php/cet/article/view/3047
spellingShingle N. Shen
E. Chirwa
Preliminary Study on Desorption of Gold Ions on Self- Flocculating Microalga and its Regeneration Potential
Chemical Engineering Transactions
title Preliminary Study on Desorption of Gold Ions on Self- Flocculating Microalga and its Regeneration Potential
title_full Preliminary Study on Desorption of Gold Ions on Self- Flocculating Microalga and its Regeneration Potential
title_fullStr Preliminary Study on Desorption of Gold Ions on Self- Flocculating Microalga and its Regeneration Potential
title_full_unstemmed Preliminary Study on Desorption of Gold Ions on Self- Flocculating Microalga and its Regeneration Potential
title_short Preliminary Study on Desorption of Gold Ions on Self- Flocculating Microalga and its Regeneration Potential
title_sort preliminary study on desorption of gold ions on self flocculating microalga and its regeneration potential
url https://www.cetjournal.it/index.php/cet/article/view/3047
work_keys_str_mv AT nshen preliminarystudyondesorptionofgoldionsonselfflocculatingmicroalgaanditsregenerationpotential
AT echirwa preliminarystudyondesorptionofgoldionsonselfflocculatingmicroalgaanditsregenerationpotential