Eudialyte-group minerals from the Monte de Trigo alkaline suite, Brazil: composition and petrological implications

ABSTRACT: The Monte de Trigo alkaline suite is a SiO2-undersaturated syenite-gabbroid association from the Serra do Mar alkaline province. Eudialyte-group minerals (EGMs) occur in one nepheline microsyenite dyke, associated with aegirine-augite, wöhlerite, låvenite, magnetite, zircon, titanite, brit...

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Main Authors: Gaston Eduardo Enrich Rojas, Excelso Ruberti, Rogério Guitarrari Azzone, Celso de Barros Gomes
Format: Article
Language:English
Published: Sociedade Brasileira de Geologia
Series:Brazilian Journal of Geology
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S2317-48892016000300411&lng=en&tlng=en
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author Gaston Eduardo Enrich Rojas
Excelso Ruberti
Rogério Guitarrari Azzone
Celso de Barros Gomes
author_facet Gaston Eduardo Enrich Rojas
Excelso Ruberti
Rogério Guitarrari Azzone
Celso de Barros Gomes
author_sort Gaston Eduardo Enrich Rojas
collection DOAJ
description ABSTRACT: The Monte de Trigo alkaline suite is a SiO2-undersaturated syenite-gabbroid association from the Serra do Mar alkaline province. Eudialyte-group minerals (EGMs) occur in one nepheline microsyenite dyke, associated with aegirine-augite, wöhlerite, låvenite, magnetite, zircon, titanite, britholite, and pyrochlore. Major compositional variations include Si (25.09- 25.57 apfu ), Nb (0.31- 0.76 apfu ), Fe (1.40-2.13 apfu ), and Mn (1.36- 2.08 apfu ). The EGMs also contain relatively high contents of Ca (6.13- 7.10 apfu ), moderate enrichment of rare earth elements (0.38-0.67 apfu ), and a relatively low Na content (11.02-12.28 apfu ), which can be correlated with their transitional agpaitic assemblage. EGM compositions indicate a complex solid solution that includes eudialyte, kentbrooksite, feklichevite, zirsilite-(Ce), georgbarsanovite, and manganoeudialyte components. EGM trace element analyses show low Sr and Ba contents and a negative Eu/Eu* anomaly, which are interpreted as characteristic of the parental magma due to the previous fractionation of plagioclase and/or alkali feldspar. The EGMs from the dyke border have higher contents of Fe, Sr (2,161-2,699 ppm), Mg (1,179-3,582 ppm), and Zn (732- 852 ppm) than those at the dyke center. These differences are related to the incorporation of xenoliths and xenocrysts of melatheralitic host rock into the nepheline-syenitic magma followed by crystal-melt diffusive exchange.
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spelling doaj.art-4884a48abbac491da65e06cecf80ce062022-12-22T00:20:29ZengSociedade Brasileira de GeologiaBrazilian Journal of Geology2317-469246341142610.1590/2317-4889201620160075S2317-48892016000300411Eudialyte-group minerals from the Monte de Trigo alkaline suite, Brazil: composition and petrological implicationsGaston Eduardo Enrich RojasExcelso RubertiRogério Guitarrari AzzoneCelso de Barros GomesABSTRACT: The Monte de Trigo alkaline suite is a SiO2-undersaturated syenite-gabbroid association from the Serra do Mar alkaline province. Eudialyte-group minerals (EGMs) occur in one nepheline microsyenite dyke, associated with aegirine-augite, wöhlerite, låvenite, magnetite, zircon, titanite, britholite, and pyrochlore. Major compositional variations include Si (25.09- 25.57 apfu ), Nb (0.31- 0.76 apfu ), Fe (1.40-2.13 apfu ), and Mn (1.36- 2.08 apfu ). The EGMs also contain relatively high contents of Ca (6.13- 7.10 apfu ), moderate enrichment of rare earth elements (0.38-0.67 apfu ), and a relatively low Na content (11.02-12.28 apfu ), which can be correlated with their transitional agpaitic assemblage. EGM compositions indicate a complex solid solution that includes eudialyte, kentbrooksite, feklichevite, zirsilite-(Ce), georgbarsanovite, and manganoeudialyte components. EGM trace element analyses show low Sr and Ba contents and a negative Eu/Eu* anomaly, which are interpreted as characteristic of the parental magma due to the previous fractionation of plagioclase and/or alkali feldspar. The EGMs from the dyke border have higher contents of Fe, Sr (2,161-2,699 ppm), Mg (1,179-3,582 ppm), and Zn (732- 852 ppm) than those at the dyke center. These differences are related to the incorporation of xenoliths and xenocrysts of melatheralitic host rock into the nepheline-syenitic magma followed by crystal-melt diffusive exchange.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S2317-48892016000300411&lng=en&tlng=enquímica mineralrochas agpaíticas, província alcalina da Serra do Mar
spellingShingle Gaston Eduardo Enrich Rojas
Excelso Ruberti
Rogério Guitarrari Azzone
Celso de Barros Gomes
Eudialyte-group minerals from the Monte de Trigo alkaline suite, Brazil: composition and petrological implications
Brazilian Journal of Geology
química mineral
rochas agpaíticas, província alcalina da Serra do Mar
title Eudialyte-group minerals from the Monte de Trigo alkaline suite, Brazil: composition and petrological implications
title_full Eudialyte-group minerals from the Monte de Trigo alkaline suite, Brazil: composition and petrological implications
title_fullStr Eudialyte-group minerals from the Monte de Trigo alkaline suite, Brazil: composition and petrological implications
title_full_unstemmed Eudialyte-group minerals from the Monte de Trigo alkaline suite, Brazil: composition and petrological implications
title_short Eudialyte-group minerals from the Monte de Trigo alkaline suite, Brazil: composition and petrological implications
title_sort eudialyte group minerals from the monte de trigo alkaline suite brazil composition and petrological implications
topic química mineral
rochas agpaíticas, província alcalina da Serra do Mar
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S2317-48892016000300411&lng=en&tlng=en
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