Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuim

Abstract Gongronema latifolium was used as a low-cost green inhibitor for mild steel by applying the weight loss method at 303–323 K. There was a decrease in percentage inhibition with temperature increase and a rise in inhibition efficiency with an increase in the concentration of inhibitor. The ob...

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Main Authors: Chiedozie C. Aralu, Helen O. Chukwuemeka-Okorie, Kovo G. Akpomie
Format: Article
Language:English
Published: SpringerOpen 2021-01-01
Series:Applied Water Science
Subjects:
Online Access:https://doi.org/10.1007/s13201-020-01351-8
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author Chiedozie C. Aralu
Helen O. Chukwuemeka-Okorie
Kovo G. Akpomie
author_facet Chiedozie C. Aralu
Helen O. Chukwuemeka-Okorie
Kovo G. Akpomie
author_sort Chiedozie C. Aralu
collection DOAJ
description Abstract Gongronema latifolium was used as a low-cost green inhibitor for mild steel by applying the weight loss method at 303–323 K. There was a decrease in percentage inhibition with temperature increase and a rise in inhibition efficiency with an increase in the concentration of inhibitor. The obtained results showed that Gongronema latifolium extract of methanol had percentage inhibition efficiencies in the range of 59.06–81.69%. Corrosion inhibition of mild steel showed a good fit to the Langmuir model compared to the Freundlich and El-Awardy adsorption models. Thermodynamics parameters, such as $$ E_{\text{a}} $$ E a , $$ Q_{\text{ads}} $$ Q ads and $$ \Delta G_{\text{ads}} $$ Δ G ads were evaluated and showed that the mechanism of corrosion inhibition of mild steel by methanol extract of Gongronema latifolium was physisorption. The results of this work indicated efficient potentials of the methanol extract of Gongronema latifolium as a low-cost corrosion inhibitor in acidic media for mild steel, which could be applied to reduce corrosion of metals in industries.
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spelling doaj.art-48b0b1a37c124e579ea49e41ac4290bc2022-12-21T22:45:24ZengSpringerOpenApplied Water Science2190-54872190-54952021-01-011121710.1007/s13201-020-01351-8Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuimChiedozie C. Aralu0Helen O. Chukwuemeka-Okorie1Kovo G. Akpomie2Department of Chemistry, Nnamdi Azikiwe UniversityDepartment of Chemistry, Michael Okpara University of AgricultureDepartment of Pure and Industrial Chemistry, University of NigeriaAbstract Gongronema latifolium was used as a low-cost green inhibitor for mild steel by applying the weight loss method at 303–323 K. There was a decrease in percentage inhibition with temperature increase and a rise in inhibition efficiency with an increase in the concentration of inhibitor. The obtained results showed that Gongronema latifolium extract of methanol had percentage inhibition efficiencies in the range of 59.06–81.69%. Corrosion inhibition of mild steel showed a good fit to the Langmuir model compared to the Freundlich and El-Awardy adsorption models. Thermodynamics parameters, such as $$ E_{\text{a}} $$ E a , $$ Q_{\text{ads}} $$ Q ads and $$ \Delta G_{\text{ads}} $$ Δ G ads were evaluated and showed that the mechanism of corrosion inhibition of mild steel by methanol extract of Gongronema latifolium was physisorption. The results of this work indicated efficient potentials of the methanol extract of Gongronema latifolium as a low-cost corrosion inhibitor in acidic media for mild steel, which could be applied to reduce corrosion of metals in industries.https://doi.org/10.1007/s13201-020-01351-8Corrosion inhibitionGongronema latifolium extractAdsorption
spellingShingle Chiedozie C. Aralu
Helen O. Chukwuemeka-Okorie
Kovo G. Akpomie
Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuim
Applied Water Science
Corrosion inhibition
Gongronema latifolium extract
Adsorption
title Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuim
title_full Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuim
title_fullStr Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuim
title_full_unstemmed Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuim
title_short Inhibition and adsorption potentials of mild steel corrosion using methanol extract of Gongronema latifoliuim
title_sort inhibition and adsorption potentials of mild steel corrosion using methanol extract of gongronema latifoliuim
topic Corrosion inhibition
Gongronema latifolium extract
Adsorption
url https://doi.org/10.1007/s13201-020-01351-8
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AT helenochukwuemekaokorie inhibitionandadsorptionpotentialsofmildsteelcorrosionusingmethanolextractofgongronemalatifoliuim
AT kovogakpomie inhibitionandadsorptionpotentialsofmildsteelcorrosionusingmethanolextractofgongronemalatifoliuim