Visible light mediated aerobic oxidative hydroxylation of 2-oxindole-3-carboxylate esters: an alternative approach to 3-hydroxy-2-oxindoles
A convenient aerobic oxidative hydroxylation of 3-substituted oxindoles under mild reaction conditions is described herein. This process was accomplished by the activation of molecular oxygen in the air in the presence of a photocatalyst under the irradiation of visible light. The desired product wa...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2020-11-01
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| Series: | Heterocyclic Communications |
| Subjects: | |
| Online Access: | http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2019-0114/hc-2019-0114.xml?format=INT |
| _version_ | 1818725909589393408 |
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| author | Wang Jinge Osman Siyitemer Lu Xinjiang Chen Junyi Xia Xu-Dong |
| author_facet | Wang Jinge Osman Siyitemer Lu Xinjiang Chen Junyi Xia Xu-Dong |
| author_sort | Wang Jinge |
| collection | DOAJ |
| description | A convenient aerobic oxidative hydroxylation of 3-substituted oxindoles under mild reaction conditions is described herein. This process was accomplished by the activation of molecular oxygen in the air in the presence of a photocatalyst under the irradiation of visible light. The desired product was delivered in up to 89% yield without the addition of base or stoichiometric oxidant. |
| first_indexed | 2024-12-17T21:49:48Z |
| format | Article |
| id | doaj.art-48ba6f7eddf0451d8ec36c100b720195 |
| institution | Directory Open Access Journal |
| issn | 2191-0197 |
| language | English |
| last_indexed | 2024-12-17T21:49:48Z |
| publishDate | 2020-11-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Heterocyclic Communications |
| spelling | doaj.art-48ba6f7eddf0451d8ec36c100b7201952022-12-21T21:31:21ZengDe GruyterHeterocyclic Communications2191-01972020-11-0126116817510.1515/hc-2019-0114hc-2019-0114Visible light mediated aerobic oxidative hydroxylation of 2-oxindole-3-carboxylate esters: an alternative approach to 3-hydroxy-2-oxindolesWang Jinge0Osman Siyitemer1Lu Xinjiang2Chen Junyi3Xia Xu-Dong4Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, College of Life Sciences, Tarim University, Alar, Xinjiang843300, P. R. ChinaEngineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, College of Life Sciences, Tarim University, Alar, Xinjiang843300, P. R. ChinaEngineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, College of Life Sciences, Tarim University, Alar, Xinjiang843300, P. R. ChinaEngineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, College of Life Sciences, Tarim University, Alar, Xinjiang843300, P. R. ChinaEngineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, College of Life Sciences, Tarim University, Alar, Xinjiang843300, P. R. ChinaA convenient aerobic oxidative hydroxylation of 3-substituted oxindoles under mild reaction conditions is described herein. This process was accomplished by the activation of molecular oxygen in the air in the presence of a photocatalyst under the irradiation of visible light. The desired product was delivered in up to 89% yield without the addition of base or stoichiometric oxidant.http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2019-0114/hc-2019-0114.xml?format=INTvisible lightphotocatalysisoxindoleaerobic oxidation |
| spellingShingle | Wang Jinge Osman Siyitemer Lu Xinjiang Chen Junyi Xia Xu-Dong Visible light mediated aerobic oxidative hydroxylation of 2-oxindole-3-carboxylate esters: an alternative approach to 3-hydroxy-2-oxindoles Heterocyclic Communications visible light photocatalysis oxindole aerobic oxidation |
| title | Visible light mediated aerobic oxidative hydroxylation of 2-oxindole-3-carboxylate esters: an alternative approach to 3-hydroxy-2-oxindoles |
| title_full | Visible light mediated aerobic oxidative hydroxylation of 2-oxindole-3-carboxylate esters: an alternative approach to 3-hydroxy-2-oxindoles |
| title_fullStr | Visible light mediated aerobic oxidative hydroxylation of 2-oxindole-3-carboxylate esters: an alternative approach to 3-hydroxy-2-oxindoles |
| title_full_unstemmed | Visible light mediated aerobic oxidative hydroxylation of 2-oxindole-3-carboxylate esters: an alternative approach to 3-hydroxy-2-oxindoles |
| title_short | Visible light mediated aerobic oxidative hydroxylation of 2-oxindole-3-carboxylate esters: an alternative approach to 3-hydroxy-2-oxindoles |
| title_sort | visible light mediated aerobic oxidative hydroxylation of 2 oxindole 3 carboxylate esters an alternative approach to 3 hydroxy 2 oxindoles |
| topic | visible light photocatalysis oxindole aerobic oxidation |
| url | http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2019-0114/hc-2019-0114.xml?format=INT |
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