Treatment of bauxite residues: Acidic leaching: First part

Introduction/purpose: Bauxite residue as a waste product from the aluminium industry produced through the Bayer process is mainly composed of iron oxide, titanium oxide, silicon oxide and undissolved alumina together with a wide range of other oxides and a minor content of rare earth elements, galli...

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Main Authors: Srećko R. Stopić, Vladimir Damjanović, Radislav Filipović, Mary D. Kamara, Bernd G. Friedrich
Format: Article
Language:English
Published: University of Defence in Belgrade 2023-10-01
Series:Vojnotehnički Glasnik
Subjects:
Online Access:https://scindeks.ceon.rs/article.aspx?artid=0042-84692304069S
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author Srećko R. Stopić
Vladimir Damjanović
Radislav Filipović
Mary D. Kamara
Bernd G. Friedrich
author_facet Srećko R. Stopić
Vladimir Damjanović
Radislav Filipović
Mary D. Kamara
Bernd G. Friedrich
author_sort Srećko R. Stopić
collection DOAJ
description Introduction/purpose: Bauxite residue as a waste product from the aluminium industry produced through the Bayer process is mainly composed of iron oxide, titanium oxide, silicon oxide and undissolved alumina together with a wide range of other oxides and a minor content of rare earth elements, gallium, vanadium and scandium, which vary according to the country of origin of the bauxite. The extraction of valuable elements from bauxite residues and the minimisation of bauxite residues during different treatments are an open research field. Methods: Different hydrometallurgical and pyrometallurgical methods were used for the treatment of bauxite residues. In this study, the results of the hydrometallurgical treatment of bauxite residue from Alumina Zvornik using sulfuric acid and hydrochloric acid will be shown in order to study the change of the mineralogical composition. Leaching efficiency will be calculated using the ICP OES analysis. The XRD-Analysis was used for the characterization of the initial material and solid residues studying the change of the mineralogical phases. Results: Leaching of bauxite residues with sulphuric and hydrochloric acid leads partially to the change of mineralogical structure and the transfer of elements into a liquid phase. Natural precipitation of iron is observed over time. Silica gel formation is confirmed during leaching of bauxite residues with hydrochloric acid. Conclusion: A new research strategy for treating bauxite residue is needed in order to ensure a complete change of the initial minearlogical structure and the most efficient transfer of metals into a liquid phase.
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spelling doaj.art-48f0201cea9541d1a9acb8197e74daff2023-12-22T08:13:29ZengUniversity of Defence in BelgradeVojnotehnički Glasnik0042-84692217-47532023-10-017141069108610.5937/vojtehg71-46212Treatment of bauxite residues: Acidic leaching: First partSrećko R. Stopić0https://orcid.org/0000-0002-1752-5378Vladimir Damjanović1https://orcid.org/0000-0002-5375-440XRadislav Filipović2https://orcid.org/0009-0000-9938-2499Mary D. Kamara3https://orcid.org/0009-0005-1923-3570 Bernd G. Friedrich4https://orcid.org/0000-0002-2934-2034 RWTH Aachen University, IME Process Metallurgy and Metal Recycling, Aachen, Federal Republic of GermanyAlumina Ltd, Zvornik, Republic of Srpska, Bosnia and HerzegovinaAlumina Ltd, Zvornik, Republic of Srpska, Bosnia and HerzegovinaRWTH Aachen University, IME Process Metallurgy and Metal Recycling, Aachen, Federal Republic of GermanyRWTH Aachen University, IME Process Metallurgy and Metal Recycling, Aachen, Federal Republic of GermanyIntroduction/purpose: Bauxite residue as a waste product from the aluminium industry produced through the Bayer process is mainly composed of iron oxide, titanium oxide, silicon oxide and undissolved alumina together with a wide range of other oxides and a minor content of rare earth elements, gallium, vanadium and scandium, which vary according to the country of origin of the bauxite. The extraction of valuable elements from bauxite residues and the minimisation of bauxite residues during different treatments are an open research field. Methods: Different hydrometallurgical and pyrometallurgical methods were used for the treatment of bauxite residues. In this study, the results of the hydrometallurgical treatment of bauxite residue from Alumina Zvornik using sulfuric acid and hydrochloric acid will be shown in order to study the change of the mineralogical composition. Leaching efficiency will be calculated using the ICP OES analysis. The XRD-Analysis was used for the characterization of the initial material and solid residues studying the change of the mineralogical phases. Results: Leaching of bauxite residues with sulphuric and hydrochloric acid leads partially to the change of mineralogical structure and the transfer of elements into a liquid phase. Natural precipitation of iron is observed over time. Silica gel formation is confirmed during leaching of bauxite residues with hydrochloric acid. Conclusion: A new research strategy for treating bauxite residue is needed in order to ensure a complete change of the initial minearlogical structure and the most efficient transfer of metals into a liquid phase.https://scindeks.ceon.rs/article.aspx?artid=0042-84692304069Sbauxite residuesaluminiumhydrometallurgyacidrecyclingrare earth elements
spellingShingle Srećko R. Stopić
Vladimir Damjanović
Radislav Filipović
Mary D. Kamara
Bernd G. Friedrich
Treatment of bauxite residues: Acidic leaching: First part
Vojnotehnički Glasnik
bauxite residues
aluminium
hydrometallurgy
acid
recycling
rare earth elements
title Treatment of bauxite residues: Acidic leaching: First part
title_full Treatment of bauxite residues: Acidic leaching: First part
title_fullStr Treatment of bauxite residues: Acidic leaching: First part
title_full_unstemmed Treatment of bauxite residues: Acidic leaching: First part
title_short Treatment of bauxite residues: Acidic leaching: First part
title_sort treatment of bauxite residues acidic leaching first part
topic bauxite residues
aluminium
hydrometallurgy
acid
recycling
rare earth elements
url https://scindeks.ceon.rs/article.aspx?artid=0042-84692304069S
work_keys_str_mv AT sreckorstopic treatmentofbauxiteresiduesacidicleachingfirstpart
AT vladimirdamjanovic treatmentofbauxiteresiduesacidicleachingfirstpart
AT radislavfilipovic treatmentofbauxiteresiduesacidicleachingfirstpart
AT marydkamara treatmentofbauxiteresiduesacidicleachingfirstpart
AT berndgfriedrich treatmentofbauxiteresiduesacidicleachingfirstpart