Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium]
The title compound, [Li2(SO4)(C3H7NO2)(H2O)]n, is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO4] and [SO4] tetrahedra parallel to (010) with the β-alanine molecules locate...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812002115 |
| _version_ | 1818491494031425536 |
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| author | M. Daniel Sweetlin Shibu M. Eapen S. Perumal S. Ramalingom |
| author_facet | M. Daniel Sweetlin Shibu M. Eapen S. Perumal S. Ramalingom |
| author_sort | M. Daniel Sweetlin |
| collection | DOAJ |
| description | The title compound, [Li2(SO4)(C3H7NO2)(H2O)]n, is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO4] and [SO4] tetrahedra parallel to (010) with the β-alanine molecules located between the sheets. The two independent Li+ cations are four-coordinated by O atoms in a distorted tetrahedral geometry. The crystal structure is formed by stacking of alternate organic and inorganic layers along the a axis. The crystal structure is further stabilized by N—H...O hydrogen bonds. |
| first_indexed | 2024-12-10T17:31:33Z |
| format | Article |
| id | doaj.art-48f1561b017e4e7897e647f19e774c7b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:31:33Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-48f1561b017e4e7897e647f19e774c7b2022-12-22T01:39:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m206m20710.1107/S1600536812002115Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium]M. Daniel SweetlinShibu M. EapenS. PerumalS. RamalingomThe title compound, [Li2(SO4)(C3H7NO2)(H2O)]n, is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO4] and [SO4] tetrahedra parallel to (010) with the β-alanine molecules located between the sheets. The two independent Li+ cations are four-coordinated by O atoms in a distorted tetrahedral geometry. The crystal structure is formed by stacking of alternate organic and inorganic layers along the a axis. The crystal structure is further stabilized by N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812002115 |
| spellingShingle | M. Daniel Sweetlin Shibu M. Eapen S. Perumal S. Ramalingom Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium] Acta Crystallographica Section E |
| title | Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium] |
| title_full | Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium] |
| title_fullStr | Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium] |
| title_full_unstemmed | Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium] |
| title_short | Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium] |
| title_sort | poly amp 956 3 amp 946 alanine aqua amp 956 4 sulfato dilithium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812002115 |
| work_keys_str_mv | AT mdanielsweetlin polyamp9563amp946alanineaquaamp9564sulfatodilithium AT shibumeapen polyamp9563amp946alanineaquaamp9564sulfatodilithium AT sperumal polyamp9563amp946alanineaquaamp9564sulfatodilithium AT sramalingom polyamp9563amp946alanineaquaamp9564sulfatodilithium |