Chemoselective Polymerization of Polar Divinyl Monomers with Rare-Earth/Phosphine Lewis Pairs
This work reports the chemoselective polymerization of polar divinyl monomers, including allyl methacrylate (AMA), vinyl methacrylate (VMA), and 4-vinylbenzyl methacrylate (VBMA), by using simple Lewis pairs comprised of homoleptic rare-earth (RE) aryloxide complexes RE(OAr)3 (RE = Sc (1), Y (2), Sm...
Main Authors: | Pengfei Xu, Lei Wu, Liqiu Dong, Xin Xu |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2018-02-01
|
Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/23/2/360 |
Similar Items
-
Exploiting the Electronic Tuneability of Carboranes as Supports for Frustrated Lewis Pairs
by: Amanda Benton, et al.
Published: (2018-11-01) -
Reactivity of Amine/E(C6F5)3 (E = B, Al) Lewis Pairs toward Linear and Cyclic Acrylic Monomers: Hydrogenation vs. Polymerization
by: Jiawei Chen, et al.
Published: (2015-05-01) -
Lewis Pair Catalysts in the Polymerization of Lactide and Related Cyclic Esters
by: Xinlei Li, et al.
Published: (2018-01-01) -
Controlled and Efficient Polymerization of Conjugated Polar Alkenes by Lewis Pairs Based on Sterically Hindered Aryloxide-Substituted Alkylaluminum
by: Xiaojun Wang, et al.
Published: (2018-02-01) -
Frustrated Lewis Pair Catalyzed Reactions
by: Rundong Zhou, et al.
Published: (2023-02-01)