New Aspects of the Synthesis of <i>closo</i>-Dodecaborate Nitrilium Derivatives [B<sub>12</sub>H<sub>11</sub>NCR]<sup>−</sup> (R = <i>n</i>-C<sub>3</sub>H<sub>7</sub>, <i>i</i>-C<sub>3</sub>H<sub>7</sub>, 4-C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>, 1-C<sub>10</sub>H<sub>7</sub>): Experimental and Theoretical Studies

New Aspects of the Synthesis of <i>closo</i>-Dodecaborate Nitrilium Derivatives [B<sub>12</sub>H<sub>11</sub>NCR]<sup>−</sup> (R = <i>n</i>-C<sub>3</sub>H<sub>7</sub>, <i>i</i>-C<sub>3</sub>H<sub>7</sub>, 4-C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>, 1-C<sub>10</sub>H<sub>7</sub>): Experimental and Theoretical Studies

The preparation of novel nitrilium derivatives of <i>closo</i>-dodecaborate anion [B<sub>12</sub>H<sub>11</sub>NCR]<sup>−</sup>, R = <i>n</i>-C<sub>3</sub>H<sub>7</sub>, <i>i</i>-C<sub>3</sub>...

Full description

Bibliographic Details
Main Authors: Alexey V. Nelyubin, Ilya N. Klyukin, Alexander S. Novikov, Andrey P. Zhdanov, Nikita A. Selivanov, Alexander Yu. Bykov, Alexey S. Kubasov, Konstantin Yu. Zhizhin, Nikolay T. Kuznetsov
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Inorganics
Subjects:
nitrilium derivative
<i>closo</i>-dodecaborate
crystal structure
DFT
bond order
LUMO
Online Access:https://www.mdpi.com/2304-6740/10/11/196

Internet

https://www.mdpi.com/2304-6740/10/11/196

Similar Items