ANALYSIS OF LEACHATE FROM A NON-SANITARY LANDFILL AND ASSESSMENT OF REMOVAL EFFICIENCY OF CAFFEINE USING MATERIAL AND SUBSTANCE FLOW ANALYSIS

Leachate from a non-sanitary municipal solid waste landfill (L) was collected to perform physico-chemical (temperature, pH value, conductivity, COD, BOD5, NH4+-N, SO42-, Ptot, orthophosphates, turbidity, suspended solids) and microbiological (number of aerobic heterotrophs, total number of coliform...

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Main Authors: Katarina Antić, Maja Sremački, Maja Petrović, Maja Turk-Sekulić, Dragan Adamović, Dušan Sakulski, Jelena Radonić
Format: Article
Language:English
Published: Faculty of Civil Engineering Osijek 2019-01-01
Series:e-GFOS
Online Access:http://e-gfos.gfos.hr/egfos/egfospdf/23499
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author Katarina Antić
Maja Sremački
Maja Petrović
Maja Turk-Sekulić
Dragan Adamović
Dušan Sakulski
Jelena Radonić
author_facet Katarina Antić
Maja Sremački
Maja Petrović
Maja Turk-Sekulić
Dragan Adamović
Dušan Sakulski
Jelena Radonić
author_sort Katarina Antić
collection DOAJ
description Leachate from a non-sanitary municipal solid waste landfill (L) was collected to perform physico-chemical (temperature, pH value, conductivity, COD, BOD5, NH4+-N, SO42-, Ptot, orthophosphates, turbidity, suspended solids) and microbiological (number of aerobic heterotrophs, total number of coliform bacteria, total number of faecal coliform bacteria, number of intestinal enterococci) analyses. Obtained results indicate that landfill L was in methanogenic phase of waste decomposition and included the presence of two species of microorganisms: Escherichia coli and Klebsiella pneumonia. Additionally, a semi-quantitative screening analysis of collected samples was performed using QP2010-Ultra GC-MS. Sixteen organic compounds were identified, of which the following five belonged to the group of pharmaceuticals: caffeine, 22-tricosenoic acid, 4-methylthiomorpholine-1,1-dioxide, 2,6,10,14-hexadecatetraen-1-ol,3,7,11,15-tetramethyl-,acetate,(E,E,E)-, and 1,2-bis(trimethylsilyl)benzene. The software package STAN was used to conduct material and substance flow analysis. Scenario modeling was performed to assess the removal efficiency of selected technologies in terms of reducing the concentration of caffeine because of its well-known negative effects on humans and the environment. Technologies for leachate treatment, which were observed within the Scenario 1, included the hybrid wetland system, membrane bioreactor (MBR) and reverse osmosis (RO). The modeling results indicate the high removal efficiency of caffeine concentration (99.99%).
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spelling doaj.art-48fecd2ac7c5489b9a78de763950b5952022-12-22T03:17:23ZengFaculty of Civil Engineering Osijeke-GFOS1847-89482019-01-011019586710.13167/2019.19.6231919ANALYSIS OF LEACHATE FROM A NON-SANITARY LANDFILL AND ASSESSMENT OF REMOVAL EFFICIENCY OF CAFFEINE USING MATERIAL AND SUBSTANCE FLOW ANALYSISKatarina Antić0Maja Sremački1Maja Petrović2Maja Turk-Sekulić3Dragan Adamović4Dušan Sakulski5Jelena Radonić6Department of Environmental Engineering, Faculty of Technical Sciences, University of Novi SadDepartment of Environmental Engineering, Faculty of Technical Sciences, University of Novi SadDepartment of Environmental Engineering, Faculty of Technical Sciences, University of Novi SadDepartment of Environmental Engineering, Faculty of Technical Sciences, University of Novi SadDepartment of Environmental Engineering, Faculty of Technical Sciences, University of Novi SadBioSense Institute, University of Novi SadDepartment of Environmental Engineering, Faculty of Technical Sciences, University of Novi SadLeachate from a non-sanitary municipal solid waste landfill (L) was collected to perform physico-chemical (temperature, pH value, conductivity, COD, BOD5, NH4+-N, SO42-, Ptot, orthophosphates, turbidity, suspended solids) and microbiological (number of aerobic heterotrophs, total number of coliform bacteria, total number of faecal coliform bacteria, number of intestinal enterococci) analyses. Obtained results indicate that landfill L was in methanogenic phase of waste decomposition and included the presence of two species of microorganisms: Escherichia coli and Klebsiella pneumonia. Additionally, a semi-quantitative screening analysis of collected samples was performed using QP2010-Ultra GC-MS. Sixteen organic compounds were identified, of which the following five belonged to the group of pharmaceuticals: caffeine, 22-tricosenoic acid, 4-methylthiomorpholine-1,1-dioxide, 2,6,10,14-hexadecatetraen-1-ol,3,7,11,15-tetramethyl-,acetate,(E,E,E)-, and 1,2-bis(trimethylsilyl)benzene. The software package STAN was used to conduct material and substance flow analysis. Scenario modeling was performed to assess the removal efficiency of selected technologies in terms of reducing the concentration of caffeine because of its well-known negative effects on humans and the environment. Technologies for leachate treatment, which were observed within the Scenario 1, included the hybrid wetland system, membrane bioreactor (MBR) and reverse osmosis (RO). The modeling results indicate the high removal efficiency of caffeine concentration (99.99%).http://e-gfos.gfos.hr/egfos/egfospdf/23499
spellingShingle Katarina Antić
Maja Sremački
Maja Petrović
Maja Turk-Sekulić
Dragan Adamović
Dušan Sakulski
Jelena Radonić
ANALYSIS OF LEACHATE FROM A NON-SANITARY LANDFILL AND ASSESSMENT OF REMOVAL EFFICIENCY OF CAFFEINE USING MATERIAL AND SUBSTANCE FLOW ANALYSIS
e-GFOS
title ANALYSIS OF LEACHATE FROM A NON-SANITARY LANDFILL AND ASSESSMENT OF REMOVAL EFFICIENCY OF CAFFEINE USING MATERIAL AND SUBSTANCE FLOW ANALYSIS
title_full ANALYSIS OF LEACHATE FROM A NON-SANITARY LANDFILL AND ASSESSMENT OF REMOVAL EFFICIENCY OF CAFFEINE USING MATERIAL AND SUBSTANCE FLOW ANALYSIS
title_fullStr ANALYSIS OF LEACHATE FROM A NON-SANITARY LANDFILL AND ASSESSMENT OF REMOVAL EFFICIENCY OF CAFFEINE USING MATERIAL AND SUBSTANCE FLOW ANALYSIS
title_full_unstemmed ANALYSIS OF LEACHATE FROM A NON-SANITARY LANDFILL AND ASSESSMENT OF REMOVAL EFFICIENCY OF CAFFEINE USING MATERIAL AND SUBSTANCE FLOW ANALYSIS
title_short ANALYSIS OF LEACHATE FROM A NON-SANITARY LANDFILL AND ASSESSMENT OF REMOVAL EFFICIENCY OF CAFFEINE USING MATERIAL AND SUBSTANCE FLOW ANALYSIS
title_sort analysis of leachate from a non sanitary landfill and assessment of removal efficiency of caffeine using material and substance flow analysis
url http://e-gfos.gfos.hr/egfos/egfospdf/23499
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