Conservation of 87Sr/86Sr During Wine-Making of White Wines: A Geochemical Fingerprint of Geographical Provenance and Quality Production

The measuring of 87Sr/86Sr in wine, grape, and bioavailable soil fraction samples with the same uncertainty of geological materials allows fully comparing the whole wine-production chain with the peculiar geochemical isotope signature of any geographic area. Indeed, this signature is the same as the...

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Main Authors: Ines Tescione, Martina Casalini, Sara Marchionni, Eleonora Braschi, Massimo Mattei, Sandro Conticelli
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-09-01
Series:Frontiers in Environmental Science
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fenvs.2020.00153/full
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author Ines Tescione
Ines Tescione
Martina Casalini
Sara Marchionni
Eleonora Braschi
Massimo Mattei
Sandro Conticelli
Sandro Conticelli
author_facet Ines Tescione
Ines Tescione
Martina Casalini
Sara Marchionni
Eleonora Braschi
Massimo Mattei
Sandro Conticelli
Sandro Conticelli
author_sort Ines Tescione
collection DOAJ
description The measuring of 87Sr/86Sr in wine, grape, and bioavailable soil fraction samples with the same uncertainty of geological materials allows fully comparing the whole wine-production chain with the peculiar geochemical isotope signature of any geographic area. Indeed, this signature is the same as the final product inherited by the soil bioavailable fraction and, in turn, by the geological substratum of the vineyard. On the other hand, the few data available in literature that referred to white wines cast doubts for the use of this geographic tracer due to the common use of geological derived additives, such as bentonite, in the white wine-making procedure, which may overprint the original geochemical signature of the vineyard substratum. To tackle this issue, we analyzed the Sr-isotope compositions of four white wines produced over a period of almost 10 years in a high-quality organic farm, located on the volcanic units of the Vulsini Volcanic District (southern Tuscany, Italy). The 87Sr/86Sr values of rock, soil, grape, grape juice, must, and wine were compared among them and further weighted against the isotope fingerprint of the bentonite and yeast employed during the wine-making process. The 87Sr/86Sr values from the entire white-wine production chain reveal that no variations are observed from the signature imprinted by the original geological substratum (rocks and soils), suggesting that no further contribution is given by the addition of bentonite and yeast to the white wine Sr-isotope values. On the other hand, intermediate 87Sr/86Sr compositions are found when grapes from different vineyards are used for making multi-cultivar wine blends. Indeed, the experimental data clearly show that the Sr isotope composition is maintained through the wine-making process for white as well as for red wines. Both grape and final wine preserved the isotope signature inherited from the labile fraction of the soil where the vines are farmed. Our data thus confirm, also for white wines, the robustness of the Sr-isotope tool in studies where it is important to define terroirs and geographic provenance.
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spelling doaj.art-49168ce307574f82bb0daa0272075a022022-12-22T01:29:14ZengFrontiers Media S.A.Frontiers in Environmental Science2296-665X2020-09-01810.3389/fenvs.2020.00153516094Conservation of 87Sr/86Sr During Wine-Making of White Wines: A Geochemical Fingerprint of Geographical Provenance and Quality ProductionInes Tescione0Ines Tescione1Martina Casalini2Sara Marchionni3Eleonora Braschi4Massimo Mattei5Sandro Conticelli6Sandro Conticelli7Dipartimento di Scienze della Terra, Università degli Studi di Firenze, Florence, ItalyDipartimento di Scienze, Università degli Studi Roma TRE, Rome, ItalyDipartimento di Scienze della Terra, Università degli Studi di Firenze, Florence, ItalyDipartimento di Scienze della Terra, Università degli Studi di Firenze, Florence, ItalyCNR – Istituto di Geoscienze e Georisorse, Florence, ItalyDipartimento di Scienze, Università degli Studi Roma TRE, Rome, ItalyDipartimento di Scienze della Terra, Università degli Studi di Firenze, Florence, ItalyCNR – Istituto di Geologia Ambientale e Geoingegneria, Montelibretti, Rome, ItalyThe measuring of 87Sr/86Sr in wine, grape, and bioavailable soil fraction samples with the same uncertainty of geological materials allows fully comparing the whole wine-production chain with the peculiar geochemical isotope signature of any geographic area. Indeed, this signature is the same as the final product inherited by the soil bioavailable fraction and, in turn, by the geological substratum of the vineyard. On the other hand, the few data available in literature that referred to white wines cast doubts for the use of this geographic tracer due to the common use of geological derived additives, such as bentonite, in the white wine-making procedure, which may overprint the original geochemical signature of the vineyard substratum. To tackle this issue, we analyzed the Sr-isotope compositions of four white wines produced over a period of almost 10 years in a high-quality organic farm, located on the volcanic units of the Vulsini Volcanic District (southern Tuscany, Italy). The 87Sr/86Sr values of rock, soil, grape, grape juice, must, and wine were compared among them and further weighted against the isotope fingerprint of the bentonite and yeast employed during the wine-making process. The 87Sr/86Sr values from the entire white-wine production chain reveal that no variations are observed from the signature imprinted by the original geological substratum (rocks and soils), suggesting that no further contribution is given by the addition of bentonite and yeast to the white wine Sr-isotope values. On the other hand, intermediate 87Sr/86Sr compositions are found when grapes from different vineyards are used for making multi-cultivar wine blends. Indeed, the experimental data clearly show that the Sr isotope composition is maintained through the wine-making process for white as well as for red wines. Both grape and final wine preserved the isotope signature inherited from the labile fraction of the soil where the vines are farmed. Our data thus confirm, also for white wines, the robustness of the Sr-isotope tool in studies where it is important to define terroirs and geographic provenance.https://www.frontiersin.org/article/10.3389/fenvs.2020.00153/fullgeologic and geographic traceabilitySr-isotope compositionwine making processeswhite wineswine geochemistry
spellingShingle Ines Tescione
Ines Tescione
Martina Casalini
Sara Marchionni
Eleonora Braschi
Massimo Mattei
Sandro Conticelli
Sandro Conticelli
Conservation of 87Sr/86Sr During Wine-Making of White Wines: A Geochemical Fingerprint of Geographical Provenance and Quality Production
Frontiers in Environmental Science
geologic and geographic traceability
Sr-isotope composition
wine making processes
white wines
wine geochemistry
title Conservation of 87Sr/86Sr During Wine-Making of White Wines: A Geochemical Fingerprint of Geographical Provenance and Quality Production
title_full Conservation of 87Sr/86Sr During Wine-Making of White Wines: A Geochemical Fingerprint of Geographical Provenance and Quality Production
title_fullStr Conservation of 87Sr/86Sr During Wine-Making of White Wines: A Geochemical Fingerprint of Geographical Provenance and Quality Production
title_full_unstemmed Conservation of 87Sr/86Sr During Wine-Making of White Wines: A Geochemical Fingerprint of Geographical Provenance and Quality Production
title_short Conservation of 87Sr/86Sr During Wine-Making of White Wines: A Geochemical Fingerprint of Geographical Provenance and Quality Production
title_sort conservation of 87sr 86sr during wine making of white wines a geochemical fingerprint of geographical provenance and quality production
topic geologic and geographic traceability
Sr-isotope composition
wine making processes
white wines
wine geochemistry
url https://www.frontiersin.org/article/10.3389/fenvs.2020.00153/full
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