Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
In the title compound, C32H26BN5 or [(C14H11N5)B(C6H5)3], the B atom is approximately tetrahedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H...&...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809036071 |
| _version_ | 1828854636529844224 |
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| author | Daisuke Urakami Katsuya Inoue Shinya Hayami |
| author_facet | Daisuke Urakami Katsuya Inoue Shinya Hayami |
| author_sort | Daisuke Urakami |
| collection | DOAJ |
| description | In the title compound, C32H26BN5 or [(C14H11N5)B(C6H5)3], the B atom is approximately tetrahedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H...π interactions. The dihedral angles between the central benzene ring and the terminal rings in the heterocycle are 62.64, 73.54 and 61.60°. |
| first_indexed | 2024-12-13T00:38:37Z |
| format | Article |
| id | doaj.art-491e652dd7c0488f93e4c52981fc7457 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:38:37Z |
| publishDate | 2009-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-491e652dd7c0488f93e4c52981fc74572022-12-22T00:05:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510o2425o242510.1107/S1600536809036071Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boronDaisuke UrakamiKatsuya InoueShinya HayamiIn the title compound, C32H26BN5 or [(C14H11N5)B(C6H5)3], the B atom is approximately tetrahedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H...π interactions. The dihedral angles between the central benzene ring and the terminal rings in the heterocycle are 62.64, 73.54 and 61.60°.http://scripts.iucr.org/cgi-bin/paper?S1600536809036071 |
| spellingShingle | Daisuke Urakami Katsuya Inoue Shinya Hayami Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron Acta Crystallographica Section E |
| title | Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron |
| title_full | Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron |
| title_fullStr | Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron |
| title_full_unstemmed | Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron |
| title_short | Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron |
| title_sort | triphenyl e 4 4 phenyldiazenyl phenyl 4h 1 2 4 triazol 1 yl boron |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809036071 |
| work_keys_str_mv | AT daisukeurakami triphenyle44phenyldiazenylphenyl4h124triazol1ylboron AT katsuyainoue triphenyle44phenyldiazenylphenyl4h124triazol1ylboron AT shinyahayami triphenyle44phenyldiazenylphenyl4h124triazol1ylboron |