Acetylene–ammonia–18-crown-6 (1/2/1)
The title compound, C2H2·C12H24O6·2NH3, was formed by co-crystallization of 18-crown-6 and acetylene in liquid ammonia. The 18-crown-6 molecule has threefold rotoinversion symmetry. The acteylene molecule lies on the threefold axis and the whole molecule is generated by an...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-10-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812038792 |
| _version_ | 1818974044860448768 |
|---|---|
| author | Tobias Grassl Markus Hamberger Nikolaus Korber |
| author_facet | Tobias Grassl Markus Hamberger Nikolaus Korber |
| author_sort | Tobias Grassl |
| collection | DOAJ |
| description | The title compound, C2H2·C12H24O6·2NH3, was formed by co-crystallization of 18-crown-6 and acetylene in liquid ammonia. The 18-crown-6 molecule has threefold rotoinversion symmetry. The acteylene molecule lies on the threefold axis and the whole molecule is generated by an inversion center. The two ammonia molecules are also located on the threefold axis and are related by inversion symmetry. In the crystal, the ammonia molecules are located below and above the crown ether plane and are connected by intermolecular N—H...O hydrogen bonds. The acetylene molecules are additionally linked by weak C—H...N interactions into chains that propagate in the direction of the crystallographic c axis. The 18-crown-6 molecule [occupancy ratio 0.830 (4):0.170 (4)] is disordered and was refined using a split model. |
| first_indexed | 2024-12-20T15:33:48Z |
| format | Article |
| id | doaj.art-492f1f2f91fc403fa6036a678a701317 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:33:48Z |
| publishDate | 2012-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-492f1f2f91fc403fa6036a678a7013172022-12-21T19:35:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810o2933o293310.1107/S1600536812038792Acetylene–ammonia–18-crown-6 (1/2/1)Tobias GrasslMarkus HambergerNikolaus KorberThe title compound, C2H2·C12H24O6·2NH3, was formed by co-crystallization of 18-crown-6 and acetylene in liquid ammonia. The 18-crown-6 molecule has threefold rotoinversion symmetry. The acteylene molecule lies on the threefold axis and the whole molecule is generated by an inversion center. The two ammonia molecules are also located on the threefold axis and are related by inversion symmetry. In the crystal, the ammonia molecules are located below and above the crown ether plane and are connected by intermolecular N—H...O hydrogen bonds. The acetylene molecules are additionally linked by weak C—H...N interactions into chains that propagate in the direction of the crystallographic c axis. The 18-crown-6 molecule [occupancy ratio 0.830 (4):0.170 (4)] is disordered and was refined using a split model.http://scripts.iucr.org/cgi-bin/paper?S1600536812038792 |
| spellingShingle | Tobias Grassl Markus Hamberger Nikolaus Korber Acetylene–ammonia–18-crown-6 (1/2/1) Acta Crystallographica Section E |
| title | Acetylene–ammonia–18-crown-6 (1/2/1) |
| title_full | Acetylene–ammonia–18-crown-6 (1/2/1) |
| title_fullStr | Acetylene–ammonia–18-crown-6 (1/2/1) |
| title_full_unstemmed | Acetylene–ammonia–18-crown-6 (1/2/1) |
| title_short | Acetylene–ammonia–18-crown-6 (1/2/1) |
| title_sort | acetylene amp 8211 ammonia amp 8211 18 crown 6 1 2 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812038792 |
| work_keys_str_mv | AT tobiasgrassl acetyleneamp8211ammoniaamp821118crown6121 AT markushamberger acetyleneamp8211ammoniaamp821118crown6121 AT nikolauskorber acetyleneamp8211ammoniaamp821118crown6121 |