| Summary: | An interstitial solute strengthened high entropy alloy (iHEA), Fe49.5Mn30Co10Cr10C0.5 (at.%), was successfully additively manufactured via selective laser melting. The as-built iHEA exhibits a hierarchically heterogeneous microstructure with length scales across several orders of magnitude, which engenders an enhanced strength–ductility combination relative to those fabricated by conventional processing routes. The high yield strength mainly stemmed from the dislocation strengthening besides the friction stress and grain boundary strengthening. The joint activation of multiple deformation mechanisms involving dislocation slip, deformation twinning and phase transformation can maintain the steady work-hardening behavior at high stress levels, leading to a high ductility.
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