1-(4-{[3,5-<i>bis</i>({[3,5-Dimethyl-4-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-phenoxy]methyl})phenyl]methoxy}-2,6-dimethyl-phenyl)-4-methyl-1,2,4-triazolidine-3,5-dione
Appropriately substituted N-centered urazolyl radicals are capable of generating interesting cage-like structures upon forming N-N bonds. The radicals are generated by the oxidation of the corresponding NH urazole precursors. We synthesized a triurazole precursor that we hoped would dimerize through...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-12-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2023/1/M1535 |
| _version_ | 1797609989969281024 |
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| author | Gary W. Breton James Alexander Bowron |
| author_facet | Gary W. Breton James Alexander Bowron |
| author_sort | Gary W. Breton |
| collection | DOAJ |
| description | Appropriately substituted N-centered urazolyl radicals are capable of generating interesting cage-like structures upon forming N-N bonds. The radicals are generated by the oxidation of the corresponding NH urazole precursors. We synthesized a triurazole precursor that we hoped would dimerize through the formation of three N-N bonds to afford a large molecular cage. Unfortunately, the attempts at the oxidation of the urazoles to form urazolyl radicals instead only lead to random oligomerization, forming plastic-like materials rather than the desired cages. |
| first_indexed | 2024-03-11T06:08:12Z |
| format | Article |
| id | doaj.art-4953018fce2a4e5092c514f0f4d35efe |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-11T06:08:12Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-4953018fce2a4e5092c514f0f4d35efe2023-11-17T12:49:05ZengMDPI AGMolbank1422-85992022-12-0120231M153510.3390/M15351-(4-{[3,5-<i>bis</i>({[3,5-Dimethyl-4-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-phenoxy]methyl})phenyl]methoxy}-2,6-dimethyl-phenyl)-4-methyl-1,2,4-triazolidine-3,5-dioneGary W. Breton0James Alexander Bowron1Department of Chemistry and Biochemistry, Berry College, Mount Berry, GA 30149, USADepartment of Chemistry and Biochemistry, Berry College, Mount Berry, GA 30149, USAAppropriately substituted N-centered urazolyl radicals are capable of generating interesting cage-like structures upon forming N-N bonds. The radicals are generated by the oxidation of the corresponding NH urazole precursors. We synthesized a triurazole precursor that we hoped would dimerize through the formation of three N-N bonds to afford a large molecular cage. Unfortunately, the attempts at the oxidation of the urazoles to form urazolyl radicals instead only lead to random oligomerization, forming plastic-like materials rather than the desired cages.https://www.mdpi.com/1422-8599/2023/1/M1535urazoleradicalsmolecular cages |
| spellingShingle | Gary W. Breton James Alexander Bowron 1-(4-{[3,5-<i>bis</i>({[3,5-Dimethyl-4-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-phenoxy]methyl})phenyl]methoxy}-2,6-dimethyl-phenyl)-4-methyl-1,2,4-triazolidine-3,5-dione Molbank urazole radicals molecular cages |
| title | 1-(4-{[3,5-<i>bis</i>({[3,5-Dimethyl-4-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-phenoxy]methyl})phenyl]methoxy}-2,6-dimethyl-phenyl)-4-methyl-1,2,4-triazolidine-3,5-dione |
| title_full | 1-(4-{[3,5-<i>bis</i>({[3,5-Dimethyl-4-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-phenoxy]methyl})phenyl]methoxy}-2,6-dimethyl-phenyl)-4-methyl-1,2,4-triazolidine-3,5-dione |
| title_fullStr | 1-(4-{[3,5-<i>bis</i>({[3,5-Dimethyl-4-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-phenoxy]methyl})phenyl]methoxy}-2,6-dimethyl-phenyl)-4-methyl-1,2,4-triazolidine-3,5-dione |
| title_full_unstemmed | 1-(4-{[3,5-<i>bis</i>({[3,5-Dimethyl-4-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-phenoxy]methyl})phenyl]methoxy}-2,6-dimethyl-phenyl)-4-methyl-1,2,4-triazolidine-3,5-dione |
| title_short | 1-(4-{[3,5-<i>bis</i>({[3,5-Dimethyl-4-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-phenoxy]methyl})phenyl]methoxy}-2,6-dimethyl-phenyl)-4-methyl-1,2,4-triazolidine-3,5-dione |
| title_sort | 1 4 3 5 i bis i 3 5 dimethyl 4 4 methyl 3 5 dioxo 1 2 4 triazolidin 1 yl phenoxy methyl phenyl methoxy 2 6 dimethyl phenyl 4 methyl 1 2 4 triazolidine 3 5 dione |
| topic | urazole radicals molecular cages |
| url | https://www.mdpi.com/1422-8599/2023/1/M1535 |
| work_keys_str_mv | AT garywbreton 1435ibisi35dimethyl44methyl35dioxo124triazolidin1ylphenoxymethylphenylmethoxy26dimethylphenyl4methyl124triazolidine35dione AT jamesalexanderbowron 1435ibisi35dimethyl44methyl35dioxo124triazolidin1ylphenoxymethylphenylmethoxy26dimethylphenyl4methyl124triazolidine35dione |