Cyclometalated Osmium Compounds and beyond: Synthesis, Properties, Applications
The synthesis of cyclometalated osmium complexes is usually more complicated than of other transition metals such as Ni, Pd, Pt, Rh, where cyclometalation reactions readily occur via direct activation of C–H bonds. It differs also from their ruthenium analogs. Cyclometalation for osmium usually occu...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-03-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/26/6/1563 |
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| author | Ricardo Cerón-Camacho Manuel A. Roque-Ramires Alexander D. Ryabov Ronan Le Lagadec |
| author_facet | Ricardo Cerón-Camacho Manuel A. Roque-Ramires Alexander D. Ryabov Ronan Le Lagadec |
| author_sort | Ricardo Cerón-Camacho |
| collection | DOAJ |
| description | The synthesis of cyclometalated osmium complexes is usually more complicated than of other transition metals such as Ni, Pd, Pt, Rh, where cyclometalation reactions readily occur via direct activation of C–H bonds. It differs also from their ruthenium analogs. Cyclometalation for osmium usually occurs under more severe conditions, in polar solvents, using specific precursors, stronger acids, or bases. Such requirements expand reaction mechanisms to electrophilic activation, transmetalation, and oxidative addition, often involving C–H bond activations. Osmacycles exhibit specific applications in homogeneous catalysis, photophysics, bioelectrocatalysis and are studied as anticancer agents. This review describes major synthetic pathways to osmacycles and related compounds and discusses their practical applications. |
| first_indexed | 2024-03-10T13:17:16Z |
| format | Article |
| id | doaj.art-4954fbee18a14f54b979ab2f26bf2e62 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T13:17:16Z |
| publishDate | 2021-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-4954fbee18a14f54b979ab2f26bf2e622023-11-21T10:16:28ZengMDPI AGMolecules1420-30492021-03-01266156310.3390/molecules26061563Cyclometalated Osmium Compounds and beyond: Synthesis, Properties, ApplicationsRicardo Cerón-Camacho0Manuel A. Roque-Ramires1Alexander D. Ryabov2Ronan Le Lagadec3CONACyT-Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacán, México D.F. 07730, MexicoInstituto de Química, UNAM, Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, Ciudad de México 04510, MexicoDepartment of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213, USAInstituto de Química, UNAM, Circuito Exterior s/n, Ciudad Universitaria, Coyoacán, Ciudad de México 04510, MexicoThe synthesis of cyclometalated osmium complexes is usually more complicated than of other transition metals such as Ni, Pd, Pt, Rh, where cyclometalation reactions readily occur via direct activation of C–H bonds. It differs also from their ruthenium analogs. Cyclometalation for osmium usually occurs under more severe conditions, in polar solvents, using specific precursors, stronger acids, or bases. Such requirements expand reaction mechanisms to electrophilic activation, transmetalation, and oxidative addition, often involving C–H bond activations. Osmacycles exhibit specific applications in homogeneous catalysis, photophysics, bioelectrocatalysis and are studied as anticancer agents. This review describes major synthetic pathways to osmacycles and related compounds and discusses their practical applications.https://www.mdpi.com/1420-3049/26/6/1563osmiumcyclometalationosmium cyclometalated complexosmacyclepincer complexcatalysis |
| spellingShingle | Ricardo Cerón-Camacho Manuel A. Roque-Ramires Alexander D. Ryabov Ronan Le Lagadec Cyclometalated Osmium Compounds and beyond: Synthesis, Properties, Applications Molecules osmium cyclometalation osmium cyclometalated complex osmacycle pincer complex catalysis |
| title | Cyclometalated Osmium Compounds and beyond: Synthesis, Properties, Applications |
| title_full | Cyclometalated Osmium Compounds and beyond: Synthesis, Properties, Applications |
| title_fullStr | Cyclometalated Osmium Compounds and beyond: Synthesis, Properties, Applications |
| title_full_unstemmed | Cyclometalated Osmium Compounds and beyond: Synthesis, Properties, Applications |
| title_short | Cyclometalated Osmium Compounds and beyond: Synthesis, Properties, Applications |
| title_sort | cyclometalated osmium compounds and beyond synthesis properties applications |
| topic | osmium cyclometalation osmium cyclometalated complex osmacycle pincer complex catalysis |
| url | https://www.mdpi.com/1420-3049/26/6/1563 |
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