Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and Outlook

The grand challenges in renewable energy lie in our ability to comprehend efficient energy conversion systems, together with dealing with the problem of intermittency via scalable energy storage systems. Relatively little progress has been made on this at grid scale and two overriding challenges sti...

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Main Authors: Stephanie J. Boyd, Run Long, Niall J. English
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/15/4/1553
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author Stephanie J. Boyd
Run Long
Niall J. English
author_facet Stephanie J. Boyd
Run Long
Niall J. English
author_sort Stephanie J. Boyd
collection DOAJ
description The grand challenges in renewable energy lie in our ability to comprehend efficient energy conversion systems, together with dealing with the problem of intermittency via scalable energy storage systems. Relatively little progress has been made on this at grid scale and two overriding challenges still need to be addressed: (i) limiting damage to the environment and (ii) the question of environmentally friendly energy conversion. The present review focuses on a novel route for producing hydrogen, the ultimate clean fuel, from the Sun, and renewable energy source. Hydrogen can be produced by light-driven photoelectrochemical (PEC) water splitting, but it is very inefficient; rather, we focus here on how electric fields can be applied to metal oxide/water systems in tailoring the interplay with their intrinsic electric fields, and in how this can alter and boost PEC activity, drawing both on experiment and non-equilibrium molecular simulation.
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spelling doaj.art-49676fcb873b4d81ae42e151a60dd3d12023-11-23T19:45:55ZengMDPI AGEnergies1996-10732022-02-01154155310.3390/en15041553Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and OutlookStephanie J. Boyd0Run Long1Niall J. English2School of Chemical and Bioprocess Engineering, University College Dublin, D04 V1W8 Dublin, IrelandSchool of Chemistry, Beijing Normal University, Beijing 100875, ChinaSchool of Chemical and Bioprocess Engineering, University College Dublin, D04 V1W8 Dublin, IrelandThe grand challenges in renewable energy lie in our ability to comprehend efficient energy conversion systems, together with dealing with the problem of intermittency via scalable energy storage systems. Relatively little progress has been made on this at grid scale and two overriding challenges still need to be addressed: (i) limiting damage to the environment and (ii) the question of environmentally friendly energy conversion. The present review focuses on a novel route for producing hydrogen, the ultimate clean fuel, from the Sun, and renewable energy source. Hydrogen can be produced by light-driven photoelectrochemical (PEC) water splitting, but it is very inefficient; rather, we focus here on how electric fields can be applied to metal oxide/water systems in tailoring the interplay with their intrinsic electric fields, and in how this can alter and boost PEC activity, drawing both on experiment and non-equilibrium molecular simulation.https://www.mdpi.com/1996-1073/15/4/1553photoelectrochemical water splittingelectric fieldsmolecular simulationhydrogen
spellingShingle Stephanie J. Boyd
Run Long
Niall J. English
Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and Outlook
Energies
photoelectrochemical water splitting
electric fields
molecular simulation
hydrogen
title Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and Outlook
title_full Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and Outlook
title_fullStr Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and Outlook
title_full_unstemmed Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and Outlook
title_short Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and Outlook
title_sort electric field effects on photoelectrochemical water splitting perspectives and outlook
topic photoelectrochemical water splitting
electric fields
molecular simulation
hydrogen
url https://www.mdpi.com/1996-1073/15/4/1553
work_keys_str_mv AT stephaniejboyd electricfieldeffectsonphotoelectrochemicalwatersplittingperspectivesandoutlook
AT runlong electricfieldeffectsonphotoelectrochemicalwatersplittingperspectivesandoutlook
AT nialljenglish electricfieldeffectsonphotoelectrochemicalwatersplittingperspectivesandoutlook