Palladacycles as Functionalized Metal-Ligand Precursors, Contain Tridentate [Csp<sup>2</sup>, N, S] Ligands
The reactivity of R–CH=N–(C6H4–2–SMe) with R = 4–Br–C6H5, R = 3–Br–C6H5, R = 2–Cl–C6H5 with palladium (II) salts was investigated in this study. We were able to prepare and characterize the cyclometallation complexes. The thioimines act as a [Csp2, phenyl, N, S] tridentate group, according to the X-...
| Váldodahkkit: | , , |
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| Materiálatiipa: | Artihkal |
| Giella: | English |
| Almmustuhtton: |
MDPI AG
2021-11-01
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| Ráidu: | Chemistry Proceedings |
| Fáttát: | |
| Liŋkkat: | https://www.mdpi.com/2673-4583/8/1/70 |
| Čoahkkáigeassu: | The reactivity of R–CH=N–(C6H4–2–SMe) with R = 4–Br–C6H5, R = 3–Br–C6H5, R = 2–Cl–C6H5 with palladium (II) salts was investigated in this study. We were able to prepare and characterize the cyclometallation complexes. The thioimines act as a [Csp2, phenyl, N, S] tridentate group, according to the X-ray crystal structures in the latter complex. |
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| ISSN: | 2673-4583 |