A n‐type, Stable Electrolyte Gated Organic Transistor Based on a Printed Polymer

Abstract Electrolyte‐gated organic transistors (EGOTs) are promising and versatile devices for next‐generation biosensors, neuromorphic systems, and low‐voltage electronics. They are particularly indicated for applications where stable operation in aqueous environment and cost‐effective manufacturin...

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Main Authors: Fabrizio Antonio Viola, Filippo Melloni, Alireza Molazemhosseini, Francesco Modena, Mauro Sassi, Luca Beverina, Mario Caironi
Format: Article
Language:English
Published: Wiley-VCH 2023-01-01
Series:Advanced Electronic Materials
Subjects:
Online Access:https://doi.org/10.1002/aelm.202200573
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author Fabrizio Antonio Viola
Filippo Melloni
Alireza Molazemhosseini
Francesco Modena
Mauro Sassi
Luca Beverina
Mario Caironi
author_facet Fabrizio Antonio Viola
Filippo Melloni
Alireza Molazemhosseini
Francesco Modena
Mauro Sassi
Luca Beverina
Mario Caironi
author_sort Fabrizio Antonio Viola
collection DOAJ
description Abstract Electrolyte‐gated organic transistors (EGOTs) are promising and versatile devices for next‐generation biosensors, neuromorphic systems, and low‐voltage electronics. They are particularly indicated for applications where stable operation in aqueous environment and cost‐effective manufacturing are required. Indeed, EGOTs can be fabricated through low‐cost, large area, and scalable techniques, such as printing, from a large portfolio of solution processable organic materials, which are often able to stably operate in water or physiological solutions. Despite a large number of solution processable EGOTs have been reported in the literature so far, only a few are based on printed semiconductors, with no examples of digitally printed, i.e., inkjet printed, n‐type devices, which would easily enable complementary architectures. In this work, we propose the first example of a n‐type electrolyte gated organic transistor based on an inkjet printed polymer. The proposed device shows a high stability when operated in water and requires only 3 hours of conditioning to produce a stable response, a much faster dynamic than in the case of printed polymers currently tested for p‐type EGOTs. As a proof‐of‐concept, the proposed printed n‐type EGOT is successfully integrated with a printed single‐walled carbon‐nanotubes based p‐type device in a logic inverter, demonstrating the possibility to build simple water‐gated digital electronic circuits.
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spelling doaj.art-49c877a1d4ca4939ab98fdadb01b23772023-07-26T01:35:51ZengWiley-VCHAdvanced Electronic Materials2199-160X2023-01-0191n/an/a10.1002/aelm.202200573A n‐type, Stable Electrolyte Gated Organic Transistor Based on a Printed PolymerFabrizio Antonio Viola0Filippo Melloni1Alireza Molazemhosseini2Francesco Modena3Mauro Sassi4Luca Beverina5Mario Caironi6Center for Nano Science and Technology @PoliMi Istituto Italiano di Tecnologia via Giovanni Pascoli 70/3 Milano 20133 ItalyCenter for Nano Science and Technology @PoliMi Istituto Italiano di Tecnologia via Giovanni Pascoli 70/3 Milano 20133 ItalyCenter for Nano Science and Technology @PoliMi Istituto Italiano di Tecnologia via Giovanni Pascoli 70/3 Milano 20133 ItalyCenter for Nano Science and Technology @PoliMi Istituto Italiano di Tecnologia via Giovanni Pascoli 70/3 Milano 20133 ItalyDepartment of Materials Science Università di Milano‐Bicocca via Cozzi 55 Milano 20125 ItalyDepartment of Materials Science Università di Milano‐Bicocca via Cozzi 55 Milano 20125 ItalyCenter for Nano Science and Technology @PoliMi Istituto Italiano di Tecnologia via Giovanni Pascoli 70/3 Milano 20133 ItalyAbstract Electrolyte‐gated organic transistors (EGOTs) are promising and versatile devices for next‐generation biosensors, neuromorphic systems, and low‐voltage electronics. They are particularly indicated for applications where stable operation in aqueous environment and cost‐effective manufacturing are required. Indeed, EGOTs can be fabricated through low‐cost, large area, and scalable techniques, such as printing, from a large portfolio of solution processable organic materials, which are often able to stably operate in water or physiological solutions. Despite a large number of solution processable EGOTs have been reported in the literature so far, only a few are based on printed semiconductors, with no examples of digitally printed, i.e., inkjet printed, n‐type devices, which would easily enable complementary architectures. In this work, we propose the first example of a n‐type electrolyte gated organic transistor based on an inkjet printed polymer. The proposed device shows a high stability when operated in water and requires only 3 hours of conditioning to produce a stable response, a much faster dynamic than in the case of printed polymers currently tested for p‐type EGOTs. As a proof‐of‐concept, the proposed printed n‐type EGOT is successfully integrated with a printed single‐walled carbon‐nanotubes based p‐type device in a logic inverter, demonstrating the possibility to build simple water‐gated digital electronic circuits.https://doi.org/10.1002/aelm.202200573electrolyte‐gated transistorsorganic invertersorganic semiconductorsprinted electronicsstability
spellingShingle Fabrizio Antonio Viola
Filippo Melloni
Alireza Molazemhosseini
Francesco Modena
Mauro Sassi
Luca Beverina
Mario Caironi
A n‐type, Stable Electrolyte Gated Organic Transistor Based on a Printed Polymer
Advanced Electronic Materials
electrolyte‐gated transistors
organic inverters
organic semiconductors
printed electronics
stability
title A n‐type, Stable Electrolyte Gated Organic Transistor Based on a Printed Polymer
title_full A n‐type, Stable Electrolyte Gated Organic Transistor Based on a Printed Polymer
title_fullStr A n‐type, Stable Electrolyte Gated Organic Transistor Based on a Printed Polymer
title_full_unstemmed A n‐type, Stable Electrolyte Gated Organic Transistor Based on a Printed Polymer
title_short A n‐type, Stable Electrolyte Gated Organic Transistor Based on a Printed Polymer
title_sort n type stable electrolyte gated organic transistor based on a printed polymer
topic electrolyte‐gated transistors
organic inverters
organic semiconductors
printed electronics
stability
url https://doi.org/10.1002/aelm.202200573
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