Synthesis, liquid crystalline behaviour and structure–property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes

Two series containing 1,3-bis(1,3,4-oxadiazol-2-yl)benzene as a rigid core (RC) and alkyl or perfluoroalkyl as terminal chains were synthesized and characterized. Liquid crystal properties of the synthesized compounds have been investigated by polarizing optical microscopy, differential scanning cal...

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Main Authors: Afef Mabrouki, Malek Fouzai, Armand Soldera, Abdelkader Kriaa, Ahmed Hedhli
Format: Article
Language:English
Published: Beilstein-Institut 2020-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.16.17
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author Afef Mabrouki
Malek Fouzai
Armand Soldera
Abdelkader Kriaa
Ahmed Hedhli
author_facet Afef Mabrouki
Malek Fouzai
Armand Soldera
Abdelkader Kriaa
Ahmed Hedhli
author_sort Afef Mabrouki
collection DOAJ
description Two series containing 1,3-bis(1,3,4-oxadiazol-2-yl)benzene as a rigid core (RC) and alkyl or perfluoroalkyl as terminal chains were synthesized and characterized. Liquid crystal properties of the synthesized compounds have been investigated by polarizing optical microscopy, differential scanning calorimetry and X-ray diffraction techniques. Conformation effects of the synthesized products on the dipole moments were also investigated.
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spelling doaj.art-49e3e1100c5c46ab93e369142049db3a2022-12-21T19:43:32ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972020-01-0116114915810.3762/bjoc.16.171860-5397-16-17Synthesis, liquid crystalline behaviour and structure–property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenesAfef Mabrouki0Malek Fouzai1Armand Soldera2Abdelkader Kriaa3Ahmed Hedhli4Laboratory of Molecular Organic Chemistry, National Higher Engineering School of Tunis, 5 avenue Taha Hussein, Montfleury, 1089, Tunis, TunisiaLR99ES16 Physics Laboratory of Soft Matter and Electromagnetic Modelling, University of Tunis El Manar, 2092, Tunis, TunisiaDepartment of Chemistry, Quebec Center for Functional Materials, University of Sherbrooke, Sherbrooke, Québec, J1K 2R1, CanadaLaboratory of Molecular Organic Chemistry, National Higher Engineering School of Tunis, 5 avenue Taha Hussein, Montfleury, 1089, Tunis, TunisiaLaboratory of Molecular Organic Chemistry, National Higher Engineering School of Tunis, 5 avenue Taha Hussein, Montfleury, 1089, Tunis, TunisiaTwo series containing 1,3-bis(1,3,4-oxadiazol-2-yl)benzene as a rigid core (RC) and alkyl or perfluoroalkyl as terminal chains were synthesized and characterized. Liquid crystal properties of the synthesized compounds have been investigated by polarizing optical microscopy, differential scanning calorimetry and X-ray diffraction techniques. Conformation effects of the synthesized products on the dipole moments were also investigated.https://doi.org/10.3762/bjoc.16.17dipole momentfluorineliquid crystaloxadiazole
spellingShingle Afef Mabrouki
Malek Fouzai
Armand Soldera
Abdelkader Kriaa
Ahmed Hedhli
Synthesis, liquid crystalline behaviour and structure–property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes
Beilstein Journal of Organic Chemistry
dipole moment
fluorine
liquid crystal
oxadiazole
title Synthesis, liquid crystalline behaviour and structure–property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes
title_full Synthesis, liquid crystalline behaviour and structure–property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes
title_fullStr Synthesis, liquid crystalline behaviour and structure–property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes
title_full_unstemmed Synthesis, liquid crystalline behaviour and structure–property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes
title_short Synthesis, liquid crystalline behaviour and structure–property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes
title_sort synthesis liquid crystalline behaviour and structure property relationships of 1 3 bis 5 substituted 1 3 4 oxadiazol 2 yl benzenes
topic dipole moment
fluorine
liquid crystal
oxadiazole
url https://doi.org/10.3762/bjoc.16.17
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