Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions
Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-<i>d<sup>8</sup></i> or in THF-<i>d<sup>8</sup></i>/water mixture...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2019-06-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/24/11/2164 |
| _version_ | 1818998162934726656 |
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| author | Hawraz I. M. Amin Carlotta Raviola Ahmed A. Amin Barbara Mannucci Stefano Protti Maurizio Fagnoni |
| author_facet | Hawraz I. M. Amin Carlotta Raviola Ahmed A. Amin Barbara Mannucci Stefano Protti Maurizio Fagnoni |
| author_sort | Hawraz I. M. Amin |
| collection | DOAJ |
| description | Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-<i>d<sup>8</sup></i> or in THF-<i>d<sup>8</sup></i>/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic substituents. |
| first_indexed | 2024-12-20T21:57:09Z |
| format | Article |
| id | doaj.art-49e84a6bb6e0438295ceefbbfa61fc6e |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-20T21:57:09Z |
| publishDate | 2019-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-49e84a6bb6e0438295ceefbbfa61fc6e2022-12-21T19:25:26ZengMDPI AGMolecules1420-30492019-06-012411216410.3390/molecules24112164molecules24112164Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free ConditionsHawraz I. M. Amin0Carlotta Raviola1Ahmed A. Amin2Barbara Mannucci3Stefano Protti4Maurizio Fagnoni5PhotoGreen Lab, Department of Chemistry, University of Pavia. Viale Taramelli 12, 27100 Pavia, ItalyPhotoGreen Lab, Department of Chemistry, University of Pavia. Viale Taramelli 12, 27100 Pavia, ItalyChemistry Department, College of Education, Salahaddin University-Erbil, Erbil 44001, IraqCentro Grandi Strumenti (CGS), University of Pavia, V. Bassi 21, 27100 Pavia, ItalyPhotoGreen Lab, Department of Chemistry, University of Pavia. Viale Taramelli 12, 27100 Pavia, ItalyPhotoGreen Lab, Department of Chemistry, University of Pavia. Viale Taramelli 12, 27100 Pavia, ItalyHydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-<i>d<sup>8</sup></i> or in THF-<i>d<sup>8</sup></i>/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic substituents.https://www.mdpi.com/1420-3049/24/11/2164arylazo sulfonesdeuterationvisible-light induced processesphotochemistry |
| spellingShingle | Hawraz I. M. Amin Carlotta Raviola Ahmed A. Amin Barbara Mannucci Stefano Protti Maurizio Fagnoni Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions Molecules arylazo sulfones deuteration visible-light induced processes photochemistry |
| title | Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions |
| title_full | Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions |
| title_fullStr | Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions |
| title_full_unstemmed | Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions |
| title_short | Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions |
| title_sort | hydro deutero deamination of arylazo sulfones under metal and photo catalyst free conditions |
| topic | arylazo sulfones deuteration visible-light induced processes photochemistry |
| url | https://www.mdpi.com/1420-3049/24/11/2164 |
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