Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate

Electroreductive coupling of benzaldehyde is mainly hindered by the mismatch between initial formation and subsequent dimerization of the ketyl intermediates. Here the authors report a strategy to balance the active sites for the generation and dimerization of the ketyl intermediates, leading to pro...

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Bibliographic Details
Main Authors: Jia Yu, Peng Zhang, Lulu Li, Kailang Li, Gong Zhang, Jia Liu, Tuo Wang, Zhi-Jian Zhao, Jinlong Gong
Format: Article
Language:English
Published: Nature Portfolio 2022-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-35463-3
Description
Summary:Electroreductive coupling of benzaldehyde is mainly hindered by the mismatch between initial formation and subsequent dimerization of the ketyl intermediates. Here the authors report a strategy to balance the active sites for the generation and dimerization of the ketyl intermediates, leading to promoted production rate of hydrobenzoin.
ISSN:2041-1723