Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate
Electroreductive coupling of benzaldehyde is mainly hindered by the mismatch between initial formation and subsequent dimerization of the ketyl intermediates. Here the authors report a strategy to balance the active sites for the generation and dimerization of the ketyl intermediates, leading to pro...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-35463-3 |
| _version_ | 1797977331400179712 |
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| author | Jia Yu Peng Zhang Lulu Li Kailang Li Gong Zhang Jia Liu Tuo Wang Zhi-Jian Zhao Jinlong Gong |
| author_facet | Jia Yu Peng Zhang Lulu Li Kailang Li Gong Zhang Jia Liu Tuo Wang Zhi-Jian Zhao Jinlong Gong |
| author_sort | Jia Yu |
| collection | DOAJ |
| description | Electroreductive coupling of benzaldehyde is mainly hindered by the mismatch between initial formation and subsequent dimerization of the ketyl intermediates. Here the authors report a strategy to balance the active sites for the generation and dimerization of the ketyl intermediates, leading to promoted production rate of hydrobenzoin. |
| first_indexed | 2024-04-11T05:05:06Z |
| format | Article |
| id | doaj.art-49f9dd01b1b945309e57fe497f499b27 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-11T05:05:06Z |
| publishDate | 2022-12-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-49f9dd01b1b945309e57fe497f499b272022-12-25T12:22:09ZengNature PortfolioNature Communications2041-17232022-12-011311810.1038/s41467-022-35463-3Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediateJia Yu0Peng Zhang1Lulu Li2Kailang Li3Gong Zhang4Jia Liu5Tuo Wang6Zhi-Jian Zhao7Jinlong Gong8School of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversitySchool of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversitySchool of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversitySchool of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversitySchool of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversitySchool of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversitySchool of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversitySchool of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversitySchool of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin UniversityElectroreductive coupling of benzaldehyde is mainly hindered by the mismatch between initial formation and subsequent dimerization of the ketyl intermediates. Here the authors report a strategy to balance the active sites for the generation and dimerization of the ketyl intermediates, leading to promoted production rate of hydrobenzoin.https://doi.org/10.1038/s41467-022-35463-3 |
| spellingShingle | Jia Yu Peng Zhang Lulu Li Kailang Li Gong Zhang Jia Liu Tuo Wang Zhi-Jian Zhao Jinlong Gong Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate Nature Communications |
| title | Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate |
| title_full | Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate |
| title_fullStr | Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate |
| title_full_unstemmed | Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate |
| title_short | Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate |
| title_sort | electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate |
| url | https://doi.org/10.1038/s41467-022-35463-3 |
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