2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.01,3.09,11]tridecane
The title compound, C16H25Cl2N, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The molecule is built up from fused six- and seven-membered rings linked to...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813007642 |
| _version_ | 1818321404910632960 |
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| author | Abdelouahd Oukhrib Ahmed Benharref Mohamed Saadi Moha Berraho Lahcen El Ammari |
| author_facet | Abdelouahd Oukhrib Ahmed Benharref Mohamed Saadi Moha Berraho Lahcen El Ammari |
| author_sort | Abdelouahd Oukhrib |
| collection | DOAJ |
| description | The title compound, C16H25Cl2N, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The molecule is built up from fused six- and seven-membered rings linked to two three-membered rings. The six-membered ring shows a half-chair conformation, whereas the seven-membered ring displays a boat conformation. The dihedral angle between the mean planes through the six- and seven-membered rings is 59.8 (2)°. The two three-membered rings lie to one side and each is nearly perpendicular to the six-membered ring, forming dihedral angles of 83.2 (2) and 86.0 (2)°. The absolute structure was established unambiguously from anomalous dispersion effects. No specific intermolecular interactions are noted in the crystal structure. |
| first_indexed | 2024-12-13T10:40:22Z |
| format | Article |
| id | doaj.art-4a0d137799f1451ead37a21e588438d0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:40:22Z |
| publishDate | 2013-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4a0d137799f1451ead37a21e588438d02022-12-21T23:50:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-04-01694o589o59010.1107/S16005368130076422,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.01,3.09,11]tridecaneAbdelouahd OukhribAhmed BenharrefMohamed SaadiMoha BerrahoLahcen El AmmariThe title compound, C16H25Cl2N, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The molecule is built up from fused six- and seven-membered rings linked to two three-membered rings. The six-membered ring shows a half-chair conformation, whereas the seven-membered ring displays a boat conformation. The dihedral angle between the mean planes through the six- and seven-membered rings is 59.8 (2)°. The two three-membered rings lie to one side and each is nearly perpendicular to the six-membered ring, forming dihedral angles of 83.2 (2) and 86.0 (2)°. The absolute structure was established unambiguously from anomalous dispersion effects. No specific intermolecular interactions are noted in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536813007642 |
| spellingShingle | Abdelouahd Oukhrib Ahmed Benharref Mohamed Saadi Moha Berraho Lahcen El Ammari 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.01,3.09,11]tridecane Acta Crystallographica Section E |
| title | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.01,3.09,11]tridecane |
| title_full | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.01,3.09,11]tridecane |
| title_fullStr | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.01,3.09,11]tridecane |
| title_full_unstemmed | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.01,3.09,11]tridecane |
| title_short | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.01,3.09,11]tridecane |
| title_sort | 2 2 dichloro 3 7 7 11 tetramethyl 10 azatetracyclo 6 5 0 01 3 09 11 tridecane |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813007642 |
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