(E)-2,3-Dimethyl-N-(2-nitrobenzylidene)aniline
In the title compound, C15H14N2O2, the 2,3-dimethylanilinic and benzaldehyde groups are planar, with r.m.s. deviations of 0.0101 and 0.0241 Å, respectively, and are oriented at a dihedral angle of 11.69 (3)°. The nitro group is inclined to the be...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810024165 |
| _version_ | 1828856820737769472 |
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| author | M. Nawaz Tahir Muhammad Ilyas Tariq Shahbaz Ahmad Muhammad Sarfraz Abdul Qayyum Ather |
| author_facet | M. Nawaz Tahir Muhammad Ilyas Tariq Shahbaz Ahmad Muhammad Sarfraz Abdul Qayyum Ather |
| author_sort | M. Nawaz Tahir |
| collection | DOAJ |
| description | In the title compound, C15H14N2O2, the 2,3-dimethylanilinic and benzaldehyde groups are planar, with r.m.s. deviations of 0.0101 and 0.0241 Å, respectively, and are oriented at a dihedral angle of 11.69 (3)°. The nitro group is inclined to the benzaldehyde group by 34.02 (9)°. The molecule adopts an E configuration about the C=N bond. In the crystal, molecules are linked via C—H...O interactions, giving rise to the formation of zigzag polymeric chains extending along [010]. They are also linked by C—H...π, and π–π interactions [centroid–centroid distance of 3.7185 (11) Å] involving symmetry-related aniline and benzene rings. The H atoms of the ortho-methyl group are disordered over two sites with a refined occupancy ratio of 0.69 (2):0.31 (2). |
| first_indexed | 2024-12-13T01:23:11Z |
| format | Article |
| id | doaj.art-4a1240d9b3c841428def4756dd2c681b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:23:11Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4a1240d9b3c841428def4756dd2c681b2022-12-22T00:04:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667o1817o181710.1107/S1600536810024165(E)-2,3-Dimethyl-N-(2-nitrobenzylidene)anilineM. Nawaz TahirMuhammad Ilyas TariqShahbaz AhmadMuhammad SarfrazAbdul Qayyum AtherIn the title compound, C15H14N2O2, the 2,3-dimethylanilinic and benzaldehyde groups are planar, with r.m.s. deviations of 0.0101 and 0.0241 Å, respectively, and are oriented at a dihedral angle of 11.69 (3)°. The nitro group is inclined to the benzaldehyde group by 34.02 (9)°. The molecule adopts an E configuration about the C=N bond. In the crystal, molecules are linked via C—H...O interactions, giving rise to the formation of zigzag polymeric chains extending along [010]. They are also linked by C—H...π, and π–π interactions [centroid–centroid distance of 3.7185 (11) Å] involving symmetry-related aniline and benzene rings. The H atoms of the ortho-methyl group are disordered over two sites with a refined occupancy ratio of 0.69 (2):0.31 (2).http://scripts.iucr.org/cgi-bin/paper?S1600536810024165 |
| spellingShingle | M. Nawaz Tahir Muhammad Ilyas Tariq Shahbaz Ahmad Muhammad Sarfraz Abdul Qayyum Ather (E)-2,3-Dimethyl-N-(2-nitrobenzylidene)aniline Acta Crystallographica Section E |
| title | (E)-2,3-Dimethyl-N-(2-nitrobenzylidene)aniline |
| title_full | (E)-2,3-Dimethyl-N-(2-nitrobenzylidene)aniline |
| title_fullStr | (E)-2,3-Dimethyl-N-(2-nitrobenzylidene)aniline |
| title_full_unstemmed | (E)-2,3-Dimethyl-N-(2-nitrobenzylidene)aniline |
| title_short | (E)-2,3-Dimethyl-N-(2-nitrobenzylidene)aniline |
| title_sort | e 2 3 dimethyl n 2 nitrobenzylidene aniline |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810024165 |
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