Improvement in Mechanical and Thermal Properties of Graphite Flake/Cu Composites by Introducing TiC Coating on Graphite Flake Surface

In this work, TiC coating was successfully deposited on a graphite flake surface via molten salt technique, for the purpose of promoting the interfacial connection between Cu and graphite flake. Vacuum hot pressing was then employed to prepare TiC-coated graphite flake/Cu composite. The results indi...

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Main Authors: Ren Zhang, Xinbo He, Qian Liu, Xuanhui Qu
Format: Article
Language:English
Published: MDPI AG 2019-05-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/9/5/519
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author Ren Zhang
Xinbo He
Qian Liu
Xuanhui Qu
author_facet Ren Zhang
Xinbo He
Qian Liu
Xuanhui Qu
author_sort Ren Zhang
collection DOAJ
description In this work, TiC coating was successfully deposited on a graphite flake surface via molten salt technique, for the purpose of promoting the interfacial connection between Cu and graphite flake. Vacuum hot pressing was then employed to prepare TiC-coated graphite flake/Cu composite. The results indicate that introducing TiC coating on graphite flake surface can evidently reduce the pores and gaps at the interface, resulting in a significant improvement on the bending strength. When the TiC-coated graphite flake content is 60 vol%, the bending strength is increased by 58% compared with the uncoated one. The coefficient of thermal expansion dropped from 6.0 ppm&#183;K<sup>&#8722;1</sup> to 4.4 ppm&#183;K<sup>&#8722;1</sup>, with the corresponding thermal conductivity as high as 571 W&#183;m<sup>&#8722;1</sup>&#183;K<sup>&#8722;1</sup>. The outstanding thermal conductivity, apposite coefficient of thermal expansion, as well as superior processability, make TiC-coated graphite flake/Cu composite a satisfactory electronic packaging material with vast prospect utilized in microelectronic industry.
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spelling doaj.art-4a33da9257514fcb8c824c0f6ddd8d1b2022-12-21T17:45:14ZengMDPI AGMetals2075-47012019-05-019551910.3390/met9050519met9050519Improvement in Mechanical and Thermal Properties of Graphite Flake/Cu Composites by Introducing TiC Coating on Graphite Flake SurfaceRen Zhang0Xinbo He1Qian Liu2Xuanhui Qu3Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, ChinaInstitute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, ChinaHunan Provincial Key Laboratory of Health Maintenance for Mechanical Equipment, Hunan University of Science and Technology, Xiangtan 411201, ChinaInstitute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, ChinaIn this work, TiC coating was successfully deposited on a graphite flake surface via molten salt technique, for the purpose of promoting the interfacial connection between Cu and graphite flake. Vacuum hot pressing was then employed to prepare TiC-coated graphite flake/Cu composite. The results indicate that introducing TiC coating on graphite flake surface can evidently reduce the pores and gaps at the interface, resulting in a significant improvement on the bending strength. When the TiC-coated graphite flake content is 60 vol%, the bending strength is increased by 58% compared with the uncoated one. The coefficient of thermal expansion dropped from 6.0 ppm&#183;K<sup>&#8722;1</sup> to 4.4 ppm&#183;K<sup>&#8722;1</sup>, with the corresponding thermal conductivity as high as 571 W&#183;m<sup>&#8722;1</sup>&#183;K<sup>&#8722;1</sup>. The outstanding thermal conductivity, apposite coefficient of thermal expansion, as well as superior processability, make TiC-coated graphite flake/Cu composite a satisfactory electronic packaging material with vast prospect utilized in microelectronic industry.https://www.mdpi.com/2075-4701/9/5/519graphite flakecompositesinterfacethermal properties
spellingShingle Ren Zhang
Xinbo He
Qian Liu
Xuanhui Qu
Improvement in Mechanical and Thermal Properties of Graphite Flake/Cu Composites by Introducing TiC Coating on Graphite Flake Surface
Metals
graphite flake
composites
interface
thermal properties
title Improvement in Mechanical and Thermal Properties of Graphite Flake/Cu Composites by Introducing TiC Coating on Graphite Flake Surface
title_full Improvement in Mechanical and Thermal Properties of Graphite Flake/Cu Composites by Introducing TiC Coating on Graphite Flake Surface
title_fullStr Improvement in Mechanical and Thermal Properties of Graphite Flake/Cu Composites by Introducing TiC Coating on Graphite Flake Surface
title_full_unstemmed Improvement in Mechanical and Thermal Properties of Graphite Flake/Cu Composites by Introducing TiC Coating on Graphite Flake Surface
title_short Improvement in Mechanical and Thermal Properties of Graphite Flake/Cu Composites by Introducing TiC Coating on Graphite Flake Surface
title_sort improvement in mechanical and thermal properties of graphite flake cu composites by introducing tic coating on graphite flake surface
topic graphite flake
composites
interface
thermal properties
url https://www.mdpi.com/2075-4701/9/5/519
work_keys_str_mv AT renzhang improvementinmechanicalandthermalpropertiesofgraphiteflakecucompositesbyintroducingticcoatingongraphiteflakesurface
AT xinbohe improvementinmechanicalandthermalpropertiesofgraphiteflakecucompositesbyintroducingticcoatingongraphiteflakesurface
AT qianliu improvementinmechanicalandthermalpropertiesofgraphiteflakecucompositesbyintroducingticcoatingongraphiteflakesurface
AT xuanhuiqu improvementinmechanicalandthermalpropertiesofgraphiteflakecucompositesbyintroducingticcoatingongraphiteflakesurface