Infrared Spectroscopic Analysis of the Inorganic Deposits from Water in Domestic and Technical Heat Exchangers

The deposition of insoluble inorganic substances on heat exchanger surfaces has a strong negative influence on the heat transfer and thus on the performance of the apparatus and the process. The analysis of the deposits is a crucial step towards the development of suitable technologies for scaling m...

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Main Authors: Johannes Kiefer, Alexander Stärk, Agnita Lynda Kiefer, Heike Glade
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/11/4/798
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author Johannes Kiefer
Alexander Stärk
Agnita Lynda Kiefer
Heike Glade
author_facet Johannes Kiefer
Alexander Stärk
Agnita Lynda Kiefer
Heike Glade
author_sort Johannes Kiefer
collection DOAJ
description The deposition of insoluble inorganic substances on heat exchanger surfaces has a strong negative influence on the heat transfer and thus on the performance of the apparatus and the process. The analysis of the deposits is a crucial step towards the development of suitable technologies for scaling mitigation and prevention. Such analysis, however, is challenging and often requires advanced instrumentation and sample preparation. To overcome this problem, we present a straightforward analytical approach based on Fourier-transform infrared (FTIR) spectroscopy. We demonstrate that FTIR spectroscopy is a powerful tool for the chemical analysis of inorganic deposits. For example, it can identify the common anions in scales such as sulfates and carbonates. It can even distinguish between salts with the same anion but different cations such as calcium and sodium. Test measurements are performed on the deposits from a domestic water cooker and from the evaporator of a seawater desalination pilot plant.
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spelling doaj.art-4a42b6d164c048678d261a334e2631c02022-12-22T04:03:57ZengMDPI AGEnergies1996-10732018-03-0111479810.3390/en11040798en11040798Infrared Spectroscopic Analysis of the Inorganic Deposits from Water in Domestic and Technical Heat ExchangersJohannes Kiefer0Alexander Stärk1Agnita Lynda Kiefer2Heike Glade3Technische Thermodynamik, Universität Bremen, Badgasteiner Str. 1, 28359 Bremen, GermanyTechnische Thermodynamik, Universität Bremen, Badgasteiner Str. 1, 28359 Bremen, GermanyTechnische Thermodynamik, Universität Bremen, Badgasteiner Str. 1, 28359 Bremen, GermanyTechnische Thermodynamik, Universität Bremen, Badgasteiner Str. 1, 28359 Bremen, GermanyThe deposition of insoluble inorganic substances on heat exchanger surfaces has a strong negative influence on the heat transfer and thus on the performance of the apparatus and the process. The analysis of the deposits is a crucial step towards the development of suitable technologies for scaling mitigation and prevention. Such analysis, however, is challenging and often requires advanced instrumentation and sample preparation. To overcome this problem, we present a straightforward analytical approach based on Fourier-transform infrared (FTIR) spectroscopy. We demonstrate that FTIR spectroscopy is a powerful tool for the chemical analysis of inorganic deposits. For example, it can identify the common anions in scales such as sulfates and carbonates. It can even distinguish between salts with the same anion but different cations such as calcium and sodium. Test measurements are performed on the deposits from a domestic water cooker and from the evaporator of a seawater desalination pilot plant.http://www.mdpi.com/1996-1073/11/4/798Fourier-transform infrared spectroscopychemical analysisscaledebrisheat exchangerboilercarbonatesulfate
spellingShingle Johannes Kiefer
Alexander Stärk
Agnita Lynda Kiefer
Heike Glade
Infrared Spectroscopic Analysis of the Inorganic Deposits from Water in Domestic and Technical Heat Exchangers
Energies
Fourier-transform infrared spectroscopy
chemical analysis
scale
debris
heat exchanger
boiler
carbonate
sulfate
title Infrared Spectroscopic Analysis of the Inorganic Deposits from Water in Domestic and Technical Heat Exchangers
title_full Infrared Spectroscopic Analysis of the Inorganic Deposits from Water in Domestic and Technical Heat Exchangers
title_fullStr Infrared Spectroscopic Analysis of the Inorganic Deposits from Water in Domestic and Technical Heat Exchangers
title_full_unstemmed Infrared Spectroscopic Analysis of the Inorganic Deposits from Water in Domestic and Technical Heat Exchangers
title_short Infrared Spectroscopic Analysis of the Inorganic Deposits from Water in Domestic and Technical Heat Exchangers
title_sort infrared spectroscopic analysis of the inorganic deposits from water in domestic and technical heat exchangers
topic Fourier-transform infrared spectroscopy
chemical analysis
scale
debris
heat exchanger
boiler
carbonate
sulfate
url http://www.mdpi.com/1996-1073/11/4/798
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AT alexanderstark infraredspectroscopicanalysisoftheinorganicdepositsfromwaterindomesticandtechnicalheatexchangers
AT agnitalyndakiefer infraredspectroscopicanalysisoftheinorganicdepositsfromwaterindomesticandtechnicalheatexchangers
AT heikeglade infraredspectroscopicanalysisoftheinorganicdepositsfromwaterindomesticandtechnicalheatexchangers