Hydrophilic and Conductive Carbon Nanotube Fibers for High-Performance Lithium-Ion Batteries

Carbon nanotube fiber (CNTF) is a highly conductive and porous platform to grow active materials of lithium-ion batteries (LIB). Here, we prepared SnO<sub>2</sub>@CNTF based on sulfonic acid-functionalized CNTF to be used in LIB anodes without binder, conductive agent, and current collec...

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Main Authors: Nayoung Ku, Jaeyeong Cheon, Kyunbae Lee, Yeonsu Jung, Seog-Young Yoon, Taehoon Kim
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/24/7822
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author Nayoung Ku
Jaeyeong Cheon
Kyunbae Lee
Yeonsu Jung
Seog-Young Yoon
Taehoon Kim
author_facet Nayoung Ku
Jaeyeong Cheon
Kyunbae Lee
Yeonsu Jung
Seog-Young Yoon
Taehoon Kim
author_sort Nayoung Ku
collection DOAJ
description Carbon nanotube fiber (CNTF) is a highly conductive and porous platform to grow active materials of lithium-ion batteries (LIB). Here, we prepared SnO<sub>2</sub>@CNTF based on sulfonic acid-functionalized CNTF to be used in LIB anodes without binder, conductive agent, and current collector. The SnO<sub>2</sub> nanoparticles were grown on the CNTF in an aqueous system without a hydrothermal method. The functionalized CNTF exhibited higher conductivity and effective water infiltration compared to the raw CNTF. Due to the enhanced water infiltration, the functionalized CNTF became SnO<sub>2</sub>@CNTF with an ideal core–shell structure coated with a thin SnO<sub>2</sub> layer. The specific capacity and rate capability of SnO<sub>2</sub>@-functionalized CNTF were superior to those of SnO<sub>2</sub>@raw CNTF. Since the SnO<sub>2</sub>@CNTF-based anode was free of a binder, conductive agent, and current collector, the specific capacity of the anode studied in this work was higher than that of conventional anodes.
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spelling doaj.art-4a517135db4145a5ac43d00654c029152023-11-23T09:23:33ZengMDPI AGMaterials1996-19442021-12-011424782210.3390/ma14247822Hydrophilic and Conductive Carbon Nanotube Fibers for High-Performance Lithium-Ion BatteriesNayoung Ku0Jaeyeong Cheon1Kyunbae Lee2Yeonsu Jung3Seog-Young Yoon4Taehoon Kim5Composites Research Division, Korea Institute of Materials Science, Changwon 51508, KoreaComposites Research Division, Korea Institute of Materials Science, Changwon 51508, KoreaComposites Research Division, Korea Institute of Materials Science, Changwon 51508, KoreaComposites Research Division, Korea Institute of Materials Science, Changwon 51508, KoreaSchool of Materials Science and Engineering, Pusan National University, Busan 46241, KoreaComposites Research Division, Korea Institute of Materials Science, Changwon 51508, KoreaCarbon nanotube fiber (CNTF) is a highly conductive and porous platform to grow active materials of lithium-ion batteries (LIB). Here, we prepared SnO<sub>2</sub>@CNTF based on sulfonic acid-functionalized CNTF to be used in LIB anodes without binder, conductive agent, and current collector. The SnO<sub>2</sub> nanoparticles were grown on the CNTF in an aqueous system without a hydrothermal method. The functionalized CNTF exhibited higher conductivity and effective water infiltration compared to the raw CNTF. Due to the enhanced water infiltration, the functionalized CNTF became SnO<sub>2</sub>@CNTF with an ideal core–shell structure coated with a thin SnO<sub>2</sub> layer. The specific capacity and rate capability of SnO<sub>2</sub>@-functionalized CNTF were superior to those of SnO<sub>2</sub>@raw CNTF. Since the SnO<sub>2</sub>@CNTF-based anode was free of a binder, conductive agent, and current collector, the specific capacity of the anode studied in this work was higher than that of conventional anodes.https://www.mdpi.com/1996-1944/14/24/7822CNT fiberyarnlithium-ion batteryanodetin oxide
spellingShingle Nayoung Ku
Jaeyeong Cheon
Kyunbae Lee
Yeonsu Jung
Seog-Young Yoon
Taehoon Kim
Hydrophilic and Conductive Carbon Nanotube Fibers for High-Performance Lithium-Ion Batteries
Materials
CNT fiber
yarn
lithium-ion battery
anode
tin oxide
title Hydrophilic and Conductive Carbon Nanotube Fibers for High-Performance Lithium-Ion Batteries
title_full Hydrophilic and Conductive Carbon Nanotube Fibers for High-Performance Lithium-Ion Batteries
title_fullStr Hydrophilic and Conductive Carbon Nanotube Fibers for High-Performance Lithium-Ion Batteries
title_full_unstemmed Hydrophilic and Conductive Carbon Nanotube Fibers for High-Performance Lithium-Ion Batteries
title_short Hydrophilic and Conductive Carbon Nanotube Fibers for High-Performance Lithium-Ion Batteries
title_sort hydrophilic and conductive carbon nanotube fibers for high performance lithium ion batteries
topic CNT fiber
yarn
lithium-ion battery
anode
tin oxide
url https://www.mdpi.com/1996-1944/14/24/7822
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