Eco-friendly conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones with potassium hexacyanoferrate(II)
Conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones employing potassium hexacyanoferrate(II) as an eco-friendly cyanide source, benzoyl chloride as a promoter and potassium hydroxide as a catalyst by a one-pot two-step procedure is described. The advantages of this protocol are no use of str...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2014-12-01
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| Series: | Green Processing and Synthesis |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/gps-2014-0054 |
| _version_ | 1818938626093875200 |
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| author | Li Zheng Zheng Huanhuan |
| author_facet | Li Zheng Zheng Huanhuan |
| author_sort | Li Zheng |
| collection | DOAJ |
| description | Conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones employing potassium hexacyanoferrate(II) as an eco-friendly cyanide source, benzoyl chloride as a promoter and potassium hydroxide as a catalyst by a one-pot two-step procedure is described. The advantages of this protocol are no use of strong toxic cyanating agents, the high yield of the products and a simple work-up procedure. |
| first_indexed | 2024-12-20T06:10:50Z |
| format | Article |
| id | doaj.art-4a7b3d20e2af48499dfafeedcbc00f3c |
| institution | Directory Open Access Journal |
| issn | 2191-9542 2191-9550 |
| language | English |
| last_indexed | 2024-12-20T06:10:50Z |
| publishDate | 2014-12-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Green Processing and Synthesis |
| spelling | doaj.art-4a7b3d20e2af48499dfafeedcbc00f3c2022-12-21T19:50:42ZengDe GruyterGreen Processing and Synthesis2191-95422191-95502014-12-013644745610.1515/gps-2014-0054Eco-friendly conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones with potassium hexacyanoferrate(II)Li Zheng0Zheng Huanhuan1College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, People’s Republic of ChinaCollege of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, People’s Republic of ChinaConjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones employing potassium hexacyanoferrate(II) as an eco-friendly cyanide source, benzoyl chloride as a promoter and potassium hydroxide as a catalyst by a one-pot two-step procedure is described. The advantages of this protocol are no use of strong toxic cyanating agents, the high yield of the products and a simple work-up procedure.https://doi.org/10.1515/gps-2014-00542-aroyl α,β-unsaturated ketoneconjugate hydrocyanationgreen chemistrypotassium hexacyanoferrate(ii) |
| spellingShingle | Li Zheng Zheng Huanhuan Eco-friendly conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones with potassium hexacyanoferrate(II) Green Processing and Synthesis 2-aroyl α,β-unsaturated ketone conjugate hydrocyanation green chemistry potassium hexacyanoferrate(ii) |
| title | Eco-friendly conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones with potassium hexacyanoferrate(II) |
| title_full | Eco-friendly conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones with potassium hexacyanoferrate(II) |
| title_fullStr | Eco-friendly conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones with potassium hexacyanoferrate(II) |
| title_full_unstemmed | Eco-friendly conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones with potassium hexacyanoferrate(II) |
| title_short | Eco-friendly conjugate hydrocyanation of 2-aroyl α,β-unsaturated ketones with potassium hexacyanoferrate(II) |
| title_sort | eco friendly conjugate hydrocyanation of 2 aroyl α β unsaturated ketones with potassium hexacyanoferrate ii |
| topic | 2-aroyl α,β-unsaturated ketone conjugate hydrocyanation green chemistry potassium hexacyanoferrate(ii) |
| url | https://doi.org/10.1515/gps-2014-0054 |
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