Influence of Chemical Composition on Heating Value of Biomass: A Review and Bibliometric Analysis

Biomass has become an increasingly important resource for energy generation. The influence of the chemical composition on the heating value of biomass has not been a thoroughly studied subject, as shown by a bibliometric analysis. It is well known that the heating value of lignin is significantly hi...

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Main Authors: Bruno Esteves, Umut Sen, Helena Pereira
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/16/10/4226
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author Bruno Esteves
Umut Sen
Helena Pereira
author_facet Bruno Esteves
Umut Sen
Helena Pereira
author_sort Bruno Esteves
collection DOAJ
description Biomass has become an increasingly important resource for energy generation. The influence of the chemical composition on the heating value of biomass has not been a thoroughly studied subject, as shown by a bibliometric analysis. It is well known that the heating value of lignin is significantly higher (23.26–25.58 MJ/kg) than that of polysaccharides (18.6 MJ/kg), while extractives often have HHVs over 30 MJ/kg, depending on their oxidation levels. Therefore, the proportions of the chemical components in biomass determine its HHV. Softwoods generally have higher HHVs than hardwoods due to their higher contents of lignin and lipophilic resin. Ashes are incombustible, and a high ash content leads to a lower HHV in biomass. Several models have been proposed to correlate the heating values and chemical compounds of biomass, but the most accurate models are based on the lignin from extracted samples, while good correlations between lignin and extractives have also been reported. No good correlations have been obtained with polysaccharide compounds.
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spelling doaj.art-4a98d179f04044aa81a4f9499ac8510f2023-11-18T01:14:40ZengMDPI AGEnergies1996-10732023-05-011610422610.3390/en16104226Influence of Chemical Composition on Heating Value of Biomass: A Review and Bibliometric AnalysisBruno Esteves0Umut Sen1Helena Pereira2Department of Wood Engineering, Polytechnic Institute of Viseu, Av. Cor. José Maria Vale de Andrade, 3504-510 Viseu, PortugalForest Research Centre (CEF), School of Agriculture, University of Lisbon Tapada da Ajuda, 1349-017 Lisbon, PortugalForest Research Centre (CEF), School of Agriculture, University of Lisbon Tapada da Ajuda, 1349-017 Lisbon, PortugalBiomass has become an increasingly important resource for energy generation. The influence of the chemical composition on the heating value of biomass has not been a thoroughly studied subject, as shown by a bibliometric analysis. It is well known that the heating value of lignin is significantly higher (23.26–25.58 MJ/kg) than that of polysaccharides (18.6 MJ/kg), while extractives often have HHVs over 30 MJ/kg, depending on their oxidation levels. Therefore, the proportions of the chemical components in biomass determine its HHV. Softwoods generally have higher HHVs than hardwoods due to their higher contents of lignin and lipophilic resin. Ashes are incombustible, and a high ash content leads to a lower HHV in biomass. Several models have been proposed to correlate the heating values and chemical compounds of biomass, but the most accurate models are based on the lignin from extracted samples, while good correlations between lignin and extractives have also been reported. No good correlations have been obtained with polysaccharide compounds.https://www.mdpi.com/1996-1073/16/10/4226heating valuelignincelluloseextractive models
spellingShingle Bruno Esteves
Umut Sen
Helena Pereira
Influence of Chemical Composition on Heating Value of Biomass: A Review and Bibliometric Analysis
Energies
heating value
lignin
cellulose
extractive models
title Influence of Chemical Composition on Heating Value of Biomass: A Review and Bibliometric Analysis
title_full Influence of Chemical Composition on Heating Value of Biomass: A Review and Bibliometric Analysis
title_fullStr Influence of Chemical Composition on Heating Value of Biomass: A Review and Bibliometric Analysis
title_full_unstemmed Influence of Chemical Composition on Heating Value of Biomass: A Review and Bibliometric Analysis
title_short Influence of Chemical Composition on Heating Value of Biomass: A Review and Bibliometric Analysis
title_sort influence of chemical composition on heating value of biomass a review and bibliometric analysis
topic heating value
lignin
cellulose
extractive models
url https://www.mdpi.com/1996-1073/16/10/4226
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